天然绿帘石原位高压同步辐射X射线衍射研究

在金刚石压腔高压装置(DAC)上采用同步辐射角度色散X射线衍射技术,在室温、最高压力9.16GPa条件下,对天然绿帘石进行了状态方程研究。在实验压力范围内,未观察到绿帘石发生相变。通过Birch-Murnaghan状态方程,对所获得的实验数据进行了状态方程拟合,获得了天然绿帘石的体弹模量值为116(7)GPa,体弹模量的压力导数值为7.8(8),若将体弹模量的压力导数值固定为4,获得绿帘石的体弹模量值为132(4)GPa。另外,绿帘石存在较为明显的轴向压缩各向异性:c轴方向压缩系数最大,b轴方向压缩系数最小,说明天然绿帘石在c轴方向更易于压缩,而b轴方向最抗压。     

提高中压燃气锅炉热效率技术分析

采用锅炉正平衡计算方法,辅以反平衡计算法,对某自备电站75t／h中压三气混烧燃气锅炉进行了热力计算．根据燃气锅炉燃料特性,结合现场检测锅炉热工参数,分析了影响燃气锅炉热效率的因素,计算了排烟温度及散热量损失所占比例,通过分析,找出了最佳运行空气过剩系数,以提供合理的供风量,从而节约能源,减少排烟量,减少热损失,提高锅炉燃烧效率．     

Synchrotron X-ray diffraction study of phenacite at high pressure

We report the results of a natural phenacite from 0 to 30.9 GPa using in situ angle-dispersive X-ray diffraction and a diamond anvil cell at the National Synchrotron Light Source, Brookhaven National Laboratory. Over this pressure range, no phase change or disproportionation has been observed. The isothermal equation of state was determined. The values of V₀, K₀, and K₀′ refined with a third-order Birch-Murnaghan equation of state are V₀=1116.1±1.2 ų, K₀=223±9 GPa, and K₀′=5.5±0.8. Furthermore, we confirm that the linear compressibilities (β) along a and c directions of phenacite are elastically isotropic (β_a=1.50×10^-3 and β_c=1.34×10^-3 GPa^-1). Consequently, it can be concluded that the compressibility of phenacite under high pressures has been accurately constrained.     

Phase Relations and Pressure-Volume-Temperature Equation of State of Galena

The phase relations and pressure volume dependences of galena （PbS） under high pressure and high temperature are investigated by means of in situ observation using resistance heating in a diamond anvil cell and synchrotron radiation. The phase transition from NaCl type to TII type takes place at approximately 2.4 GPa. A fit to the high temperature third-order Bireh-Murnaghan equation of state yields an isothermal bulk modulus Ko = 37（3） GPa, and its pressure derivative K＇0 = 3.6（3）, the temperature derivative of the bulk modulus （ K/ T）p = -0.022（9） GPaK^-1, and the thermal expansion coeffeient α0 = 2.2（5） × 10^-5 K^-1 for TII-type galena. The linear compressibilities j3 along a, b and c directions of TII type is elastically anisotropic （βa = 3.4 × 10^-3 GPa^-1, βb = 1.4× 10^-4 GPa^-1 and βc = 1.6 × 10^-3 GPa^-1）. We obtain the temperature derivative of the bulk modulus （ K/ T）p and thermal expansion coefficient α0 for TlI-type galena for the first time.     

An in situ high-pressure X-ray diffraction experiment on hydroxyapophyllite

The compression behavior of a natural hydroxyapophyllite is investigated up to about 10.01 GPa at 300 K using in situ angle-dispersive X-ray diffraction and a diamond anvil cell at the High Pressure Experiment Station, Beijing Synchrotron Radiation Facility (BSRF). Over this pressure range, no phase change or disproportionation is observed. The isothermal equation of state is determined for the first time. The values of zero-pressure volume V0 , isothermal bulk modulus K0 , and K0 refined with a third-order Birch-Murnaghan equation of state are V0 = 1276.3±0.9  3 , K0 = 71±3 GPa, and K0 = 8±1. Furthermore, we confirm that the values of linear compressibility β along the a and c directions of hydroxyapophyllite are elastically anisotropic.     

Lanczos方法计算小尺寸Heisenberg链基态与低激发态能谱与Haldane提出的海森堡XXZ量子模型的比较研究

利用Lanczos方法的TITPACK程序,计算了1维量子海森堡模型基态和低激发态波函数,能量的本征值和算符两点关联函数值与系统哈密顿量参数的变化关系。然后,用Matlab软件进行有限尺寸修正,基态能量计算值与理论值误差为0．0000472,而基态能量的绝对值与链长成平方反比关系E～1／n^2。在XXZ模型中粒子间距d与Sx、Sz算符两点关联函数值之间呈幂级数下降S=Aexp（-d／B）的规律。计算结果和Haldane提出的1维量子海森堡XXZ模型中基态和低激发态能量相符合,只有在耦合常数J等于某些值时有能级交叠。