[U(CO3)3(H2O)2]·2H2O配合物的合成及晶体结构

A uranylcontaining compound [U(CO₃)₃(H₂O)₂]·2H₂O has been synthesized under hydrothermal condition and characterized by X-ray single-crystal analysis. Crystal structural analysis indicates that this compound consists of three CO₃^2- molecules, one U⁶⁺. The results reveal that the title compound presents a 3D frame work built up by O-H…O week hydrogen bonds interactions. The central uranium atom is eight-coordinated through three CO₃^2- molecules and two H₂O. The compound shows a coplanar hexagonal network structure, each hexagon containing a hexagonal hole with a water moleculet. CCDC: 737313.     

[U(CO_3)_3(H_2O)_2]·2H_2O配合物的合成及晶体结构

A uranylcontaining compound [U(CO_3)_3(H_2O)_2]·2H_2O has been synthesized under hydrothermal condition and characterized by X-ray single-crystal analysis. Crystal structural analysis indicates that this compound consists of three CO_3~(2-) molecules, one U~(6+). The results reveal that the title compound presents a 3D frame work built up by O-H……O week hydrogen bonds interactions. The central uranium atom is eight-coordinated through three CO_3~(2-) molecules and two H_2O. The compound shows a coplanar hexagonal network structure, each hexagon containing a hexagonal hole with a water moleculet.     

铁尾矿物相分析及加气混凝土制备

 研究区域的铁矿尾矿SiO₂质量分数达55.88%, 其成矿地质环境独特而复杂。尾矿的组成以石英、闪石和斜长石为主, 是一种富含硅酸铁的低硅磁铁尾矿。将铁尾矿和硅砂分别粉磨25 和30 min, 在最大限度使用尾矿的条件下, 得出生产铁尾矿加气混凝土的优化方案, 成功制备出干密度为588 kg/m³, 抗压强度为3.99 MPa 的加气混凝土制品。通过XRD 和反应机理的分析结果表明, 成品中主要的物相为水化产物是0.9 nm 托贝莫来石、1.1 nm 托贝莫来石、1.4 nm 托贝莫来石和C-S-H 凝胶, 此外还有铁钙闪石、硬石膏、方解石和水化反应中残留的石英, C-S-H 凝胶作为“黏结剂”和托贝莫来石相互胶结成一个整体, 使制品得到较好的强度。     

液相色谱-电化学法检测食品中甲醛合次硫酸氢钠

根据离子特性及电化学活性的研究,提出了离子色谱-电化学法定性检测甲醛合次硫酸氢钠(CH2O·HSO<'->2·Na<'+>).对温度及酸度对分析物稳定性的影响作了试验并进行讨论.在定量检验时,回收率达到90%～96%之间,测定结果的相对标准偏差(n=5)均小于4%.     

花岗岩型铀矿床中矿前期蚀变对铀活化溶解的实验研究及其找矿意义

产铀花岗岩岩体多为二云母花岗岩,其中黑云母遭受白云母化,进而改变晶体结构和铀的赋存状态,产生铀的活化溶解。大量实验结果表明,黑云母转变为白云母易发生于含钾、铝的氯化物酸性溶液中,形成温度多在350～500℃,压力(PH2O)20～100MPa。实验结果证实,酸性初始溶液对形成造岩矿物的白云母化和伊利石化更有利,并往往稳定于pH=3～4的范围,白云母化时转入溶液的铀含量最高可达30%。黑云母的绿泥石化易发生于400℃,50MPa含镁、钠,pH=6～8的弱碱溶液中。黑云母转变为绿泥石比其转变为白云母时释放出的铀要少得多,一般低于检测限。实验结果还表明,晶质铀矿在黑云母的白云母化条件下转入溶液的铀为104～130μg/L,比晶质铀矿在黑云母绿泥石化条件下转入溶液的铀(12.2μg/L)高近一个数量级。这种"矿前期蚀变"在"退色蚀变"过程中铀的丢失现象对于找矿具有普遍重要意义。     

Generation of minimally persistent circle formation for a multi-agent system

In this paper, two methods of generating minimally persistent circle formation are presented. The proposed methods adopt a leader-follower strategy and all followers are firstly motivated to move into the leader＇s interaction range. Based on the information about relative angle and relative distance, two numbering schemes are proposed to generate minimally persistent circle formation. Distributed control laws are also designed to maintain the desired relative distance between agents. The distinctive features of the proposed methods are as follows. First, only 2n - 3 unilateral communication links for n agents are needed during the circle formation process and thus the communication complexity can be reduced. In addition, the formation topology is kept fixed for the whole motion and achieves a self-stability property. Finally, each follower keeps a regualr interval with its neighbors and the formation converges to a uniform circle formation. Simulation results are also provided to demonstrate the effectiveness of the proposed methods.     

基于经验模态分解的自混合干涉相位提取方法研究

为实现光反馈机理下激光自混合干涉信号相位的精确提取, 本文提出了一种基于经验模态分析(EMD)的方法.首先, 采用EMD算法对含噪的自混合干涉信号进行了降噪预处理, 提取有效的干涉信号.然后在对含有外腔物体运动信息的光反馈相位求解的过程中, 利用希尔伯特黄变换(HHT)原理实时提取每一时刻的瞬时相位, 将其去包裹处理后得到真实相位. 在弱、适度、强光反馈条件下, 分别对基于EMD的相位提取算法进行了仿真研究.最后, 搭建了基于自混合干涉效应的微位移测量实验平台, 进行实验研究.实验结果表明, 利用该方法可以实现对自混合干涉信号的相位提取, 最大误差小于1.6 rad.仿真和实验结果的一致性, 说明了EMD方法的有效性.     

高效液相色谱法检测食品中姜黄素类化合物

建立了食品中姜黄素类化合物的液相色谱分析方法。采用甲醇提取试样中姜黄素及其同系物去甲氧基姜黄素和双去甲氧基姜黄素,以YMCTMCarotenoid色谱柱(250 mm×4.6 mm,5μm)分离,甲醇水溶液(A)-甲基叔丁基醚(B)梯度洗脱。对所分析化合物的稳定性、前处理条件及色谱条件进行考察。3种分析物在0.5~100μg/mL范围内线性关系良好,相关系数为0.997 7~0.999 8。在10~100 mg/kg加标浓度范围内,平均回收率为72.2%~102%,相对标准偏差为3.4%~13.8%。对姜黄素、去甲氧基姜黄素和双去甲氧基姜黄素的检出限分别为6、5、5 mg/kg。方法稳定、可靠,已应用于实际样品的检测。     

不确定关联时滞大系统的分散鲁棒控制

研究不确定关联时滞大系统的分散鲁棒控制问题,其中不确定性满足范数有界条件.应用线性矩阵不等式(LMI)的方法,得到了系统存在分散鲁棒控制器的充分条件.同时研究了当系统状态不可测时,基于观测器的使系统鲁棒镇定的充分条件.