全文获取类型
收费全文 | 137360篇 |
免费 | 20667篇 |
国内免费 | 15614篇 |
专业分类
化学 | 72025篇 |
晶体学 | 1022篇 |
力学 | 6945篇 |
综合类 | 642篇 |
数学 | 12812篇 |
物理学 | 42402篇 |
无线电 | 37793篇 |
出版年
2024年 | 318篇 |
2023年 | 3208篇 |
2022年 | 3303篇 |
2021年 | 4705篇 |
2020年 | 5061篇 |
2019年 | 4444篇 |
2018年 | 3921篇 |
2017年 | 3772篇 |
2016年 | 5537篇 |
2015年 | 5777篇 |
2014年 | 6955篇 |
2013年 | 9050篇 |
2012年 | 10820篇 |
2011年 | 12409篇 |
2010年 | 8504篇 |
2009年 | 8415篇 |
2008年 | 8546篇 |
2007年 | 7605篇 |
2006年 | 7394篇 |
2005年 | 6533篇 |
2004年 | 5886篇 |
2003年 | 4561篇 |
2002年 | 4059篇 |
2001年 | 3397篇 |
2000年 | 2943篇 |
1999年 | 3350篇 |
1998年 | 2988篇 |
1997年 | 2660篇 |
1996年 | 2545篇 |
1995年 | 2219篇 |
1994年 | 1980篇 |
1993年 | 2001篇 |
1992年 | 1961篇 |
1991年 | 1533篇 |
1990年 | 1295篇 |
1989年 | 1021篇 |
1988年 | 670篇 |
1987年 | 477篇 |
1986年 | 467篇 |
1985年 | 378篇 |
1984年 | 254篇 |
1983年 | 180篇 |
1982年 | 155篇 |
1981年 | 98篇 |
1980年 | 71篇 |
1979年 | 34篇 |
1978年 | 19篇 |
1977年 | 16篇 |
1973年 | 15篇 |
1957年 | 32篇 |
排序方式: 共有10000条查询结果,搜索用时 491 毫秒
1.
Zhihong Zhao Bin Wang Rui Tan Wenjing Liu Minghui Zhang 《Magnetic resonance in chemistry : MRC》2022,60(4):427-433
In this study, the transverse relaxation time (T2) of activated carbon (AC) in different relative environment humidity was detected firstly by low-field nuclear magnetic resonance (LFNMR). The pore size (diameter) of AC distributions was calculated by the relationship between T2 and surface relaxation rate (ρ), where ρ was obtained by the detection of nine porous materials with known pore size. The results showed that the pore size distributions of AC calculated by ρ < 0.19 nm/ms were in good agreement with that obtained by nitrogen adsorption method and proved that LFNMR as a new detection method was feasible for characterizing AC pore size distribution. 相似文献
2.
3.
Zhang Bing Yang Jie-qin Liu Ying Hu Bin Yang Yang Zhao Li Lu Qiang 《Cellulose (London, England)》2022,29(12):6565-6578
Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and... 相似文献
4.
Qianqian Fan Zirui Liu Feng Qiu Prof. Yong Mao Prof. Qingju Liu Prof. Longzhou Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202202700
The artificially accurate design of nonmetal electrocatalysts’ active site has been a huge challenge because no pure active species with the specific structure could be strictly controlled by traditional synthetic methods. Species with a multiconfiguration in the catalyst hinder identification of the active site and the subsequent comprehension of the reaction mechanism. We have developed a novel electro-assisted molecular assembly strategy to obtain a pure pentagon ring on perfect graphene avoiding other reconstructed structures. More importantly, the active atom was confirmed by the subtle passivation process as the topmost carbon atom. Recognition of the carbon-defect electrocatalysis reaction mechanism was first downsized to the single-atom scale from the experimental perspective. It is expected that this innovative electro-assisted molecular assembly strategy could be extensively applied in the active structure-controlled synthesis of nonmetal electrocatalysts and verification of the exact active atom. 相似文献
5.
Dan Chen Kaixin Du Xiaochen Niu Hongwei Zhang Xue Zhang Yu Tang Jianchun Zhao 《Biomedical chromatography : BMC》2022,36(3):e5288
Amlexanox, an anti-inflammatory and anti-allergic agent, has been widely used clinically for the treatment of canker sores, asthma, and allergic rhinitis. Recently, amlexanox has received considerable attention in curing nonalcoholic fatty liver diseases and hepatitis virus infection. Herein, we first established a sensitive high-performance liquid chromatography-tandem mass spectrum (LC–MS/MS) method for the determination of amlexanox in rat plasma. Propranolol was used as the internal standard (IS). Using a simple protein precipitation method, the amlexanox and IS were separated with Capcell Pak C18 column (2.0 × 50 mm, 5 μm) and eluted with water and acetonitrile each containing 0.1% formic acid using gradient elution condition at a flow rate of 0.4 mL·min−1. Amlexanox and IS were detected by a triple quadrupole mass in multiple reactive monitoring (MRM) under the transitions of m/z 299.2 → 281.2 and m/z 259.9 → 116.1 with positive electrospray ionization, respectively. The calibration curves of amlexanox were established with the range of 50 to 2000 ng·mL−1 (r2 > 0.99). The validation method consisted of selectivity, accuracy, precision, carryover effect, matrix effect, recovery, dilution effect, and stability. The fully validated method was successfully applied to the pharmacokinetic study of amlexanox in Wistar rats. 相似文献
6.
Song Zhang Luke A. Galuska Xiaodan Gu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(7):1108-1129
Thin films with a nanometer-scale thickness are of great interest to both scientific and industrial communities due to their numerous applications and unique behaviors different from the bulk. However, the understanding of thin-film mechanics is still greatly hampered due to their intrinsic fragility and the lack of commercially available experimental instruments. In this review, we first discuss the progression of thin-film mechanical testing methods based on the supporting substrate: film-on-solid substrate method, film-on-water tensile tests, and water-assisted free-standing tensile tests. By comparing past studies on a model polymer, polystyrene, the effect of different substrates and confinement effect on the thin-film mechanics is evaluated. These techniques have generated fruitful scientific knowledge in the field of organic semiconductors for the understanding of structure–mechanical property relationships. We end this review by providing our perspective for their bright prospects in much broader applications and materials of interest. 相似文献
7.
以“创新、协调、绿色、开放、共享”为内核的新发展理念,是对马克思主义发展理念的继承和发扬,极具时代精神,富含问题意识,为高校思想政治教育发展、教育教学改革实践提供了强大的理论支撑。本文以“通信原理”为例,阐述了新发展理念在课程改革中的思路和方法,实现了思想政治教育与专业基础课程有机融合,为深化高校教学改革、创新人才培养模式提供了思路。 相似文献
8.
以智能反射面(intelligent reflecting surface,IRS)辅助的无线携能通信(simultaneous wireless information and power transfer,SWIPT)系统为背景,研究了该系统中基于能效优先的多天线发送端有源波束成形与IRS无源波束成形联合设计与优化方法。以最大化接收端的最小能效为优化目标,构造在发送端功率、接收端能量阈值、IRS相移等多约束下的非线性优化问题,用交替方向乘子法(alternating direction method of multipliers,ADMM)求解。采用Dinkelbach算法转化目标函数,通过奇异值分解(singular value decomposition,SVD)和半定松弛(semi-definite relaxation,SDR)得到发送端有源波束成形向量。采用SDR得到IRS相移矩阵与反射波束成形向量。结果表明,该系统显著降低了系统能量收集(energy harvesting,EH)接收端的能量阈值。当系统总电路功耗为?15 dBm时,所提方案的用户能效为300 KB/J。当IRS反射阵源数与发送天线数均为最大值时,系统可达最大能效。 相似文献
9.
Tian Xiu-Zhi Yang Rui Ma Jia-Jia Ni Yong-Hao Deng Hai-Bo Dai Lei Tan Jiao-Jun Zhang Mei-Yun Jiang Xue 《高分子科学》2022,40(7):789-798
Chinese Journal of Polymer Science - Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein, polyurethane was... 相似文献
10.