首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   126667篇
  免费   33699篇
  国内免费   29582篇
化学   63433篇
晶体学   1573篇
力学   6744篇
综合类   690篇
数学   12372篇
物理学   62059篇
无线电   43077篇
  2024年   948篇
  2023年   2134篇
  2022年   2569篇
  2021年   2645篇
  2020年   2941篇
  2019年   3895篇
  2018年   3670篇
  2017年   4593篇
  2016年   5295篇
  2015年   6254篇
  2014年   6391篇
  2013年   8559篇
  2012年   9379篇
  2011年   10099篇
  2010年   12649篇
  2009年   12585篇
  2008年   6702篇
  2007年   6033篇
  2006年   5778篇
  2005年   5366篇
  2004年   5928篇
  2003年   4662篇
  2002年   4504篇
  2001年   4517篇
  2000年   3739篇
  1999年   3470篇
  1998年   2847篇
  1997年   2595篇
  1996年   2974篇
  1995年   3293篇
  1994年   3297篇
  1993年   3333篇
  1992年   2918篇
  1991年   2513篇
  1990年   2047篇
  1989年   2112篇
  1988年   2006篇
  1987年   1218篇
  1986年   1261篇
  1985年   904篇
  1984年   1006篇
  1982年   906篇
  1981年   752篇
  1980年   788篇
  1979年   537篇
  1978年   535篇
  1977年   633篇
  1976年   1042篇
  1972年   539篇
  1971年   446篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Mobile Networks and Applications - Inverse kinematics is an important basic theory in walking control of biped robot. This study focuses on the parameter setting using the improved algorithm in...  相似文献   
2.
3.
At present, the reactivity of cyclic alkanes is estimated by comparison with acyclic hydrocarbons. Due to the difference in the structure of cycloalkanes and acycloalkanes, the thermodynamic data obtained by analogy are not applicable. In this study, a molecular beam sampling vacuum ultraviolet photoionization time-of-flight mass spectrometer (MB-VUV-PI-TOFMS) was applied to study the low-temperature oxidation of cyclopentane (CPT) at a total pressure range from 1–3 atm and low-temperature range between 500 and 800 K. Low-temperature reaction products including cyclic olefins, cyclic ethers, and highly oxygenated intermediates (e. g., ketohydroperoxide KHP, keto-dihydroperoxide KDHP, olefinic hydroperoxides OHP and ketone structure products) were observed. Further investigation of the oxidation of CPT – electronic structure calculations – were carried out at the UCCSD(T)-F12a/aug-cc-pVDZ//B3LYP/6-31+ G(d,p) level to explore the reactivity of O2 molecules adding sequentially to cyclopentyl radicals. Experimental and theoretical observations showed that the dominant product channel in the reaction of CPT radicals with O2 is HO2 elimination yielding cyclopentene. The pathways of second and third O2 addition – the dissociation of hydroperoxide – were further confirmed. The results of this study will develop the low-temperature oxidation mechanism of CPT, which can be used for future research on accurately simulating the combustion process of CPT.  相似文献   
4.
Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature...  相似文献   
5.
6.
Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs.  相似文献   
7.
根据新时代新工科人才需求特点和电工学课程特点,分析非电专业学生的电类实践需求,提出构建电工学课程为核心的电工电子实践创新能力培养新体系。通过优化教学内容、开展教学模式和考核模式改革、构建教学资源体系和进行教师队伍建设,使我校电工学课程教学质量提升、学生工程实践和创新能力提高、学生满意度增加、一流课程建设成效显著。  相似文献   
8.
Synthetic active matters are perfect model systems for non-equilibrium thermodynamics and of great potential for novel biomedical and environmental applications. However, most applications are limited by the complicated and low-yield preparation, while a scalable synthesis for highly functional microswimmers is highly desired. In this paper, an all-solution synthesis method is developed where the gold-loaded titania-silica nanotree can be produced as a multi-functional self-propulsion microswimmer. By applying light, heat, and electric field, the Janus nanotree demonstrated multi-mode self-propulsion, including photochemical self-electrophoresis by UV and visible light radiation, thermophoresis by near-infrared light radiation, and induced-charge electrophoresis under AC electric field. Due to the scalable synthesis, the Janus nanotree is further demonstrated as a high-efficiency, low-cost, active adsorbent for water decontamination, where the toxic mercury ions can be reclaimed with enhanced efficiency.  相似文献   
9.
Wang  Xuebin  Xu  Can  Zheng  Zhigang 《Nonlinear dynamics》2021,103(3):2721-2732
Nonlinear Dynamics - The classical Kuramoto model serves as a useful tool for studying synchronization transitions in coupled oscillators that is limited to the sinusoidal and pairwise...  相似文献   
10.
Journal of Optimization Theory and Applications - We distinguish two kinds of piecewise linear functions and provide an interesting representation for a piecewise linear function between two normed...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号