纳米银对铕配合物荧光性质的影响(英文)

研究了纳米银对稀土铕-吡啶-2,6-二羧酸配合物(Eu(Ⅲ)C7H5NO4,Eu(Ⅲ)DPA)的荧光性质的影响。随着纳米银浓度增加,荧光强度先增强而后逐渐下降。较大粒径的纳米银使Eu(Ⅲ)DPA荧光增强效率较大,且达到最大荧光增强效率所需的纳米银浓度较低。在高浓度Eu(Ⅲ)DPA溶液体系中,纳米银导致荧光猝灭。电偶极子跃迁发射荧光增强效率大于磁偶极子跃迁发射荧光增强效率。分析认为,纳米银对Eu(Ⅲ)DPA荧光性质的影响与表面等离子体共振与激发态荧光中心强烈耦合以及表面等离子体再吸收有关。同时,纳米银对铕配合物的不对称率有影响,其影响因素与局域电磁场增强,折射率以及配位场有关。     

Quantum Thermalization and Vanishing Thermal Entanglement in the Open Jaynes–Cummings Model

The quantum thermalization of the Jaynes–Cummings (JC) model in both equilibrium and non-equilibrium open-system cases is studied, in which the two subsystems, a two-level system and a single-mode bosonic field, are in contact with either two individual heat baths or a common heat bath. It is found that in the individual heat-bath case, the JC model can only be thermalized when either the two heat baths have the same temperature or the coupling of the JC system to one of the two baths is turned off. In the common heat-bath case, the JC system can be thermalized irrespective of the bath temperature and the system–bath coupling strengths. The thermal entanglement in this system is also studied. A counterintuitive phenomenon of vanishing thermal entanglement in the JC system is found and proved.     

Power dissipation characteristics of great power and super high speed semiconductor switch

The power dissipation characteristics of pulsed power switch reversely switched dynistors （RSDs） are investigated in this paper. According to the expressions of voltage on RSD, derived from the plasma bipolar drift model and the RLC circuit equations of RSD main loop, the simulation waveforms of current and voltage on RSD are acquired through iterative calculation by using the fourth order Runge-Kutta method, then the curve of transient power on RSD versus time is obtained. The result shows that the total dissipation on RSD is trivial compared with the pulse discharge energy and the commutation dissipation can be nearly ignored compared with the quasi-static dissipation. These characteristics can make the repetitive frequency of RSD increase largely. The experimental results prove the validity of simulation calculations. The influence factors on power dissipation are discussed. The power dissipation increases with the increase of the peak current and the n-base width and with the decrease of n-base doping concentration. In order to keep a low power dissipation, it is suggested that the n-base width should be smaller than 320μm when doping concentration is 1.0×10^14cm^-3 while the doping concentration should be higher than 5.8×10^13cm^-3 when n-base width is 270μm.     

Comparison of Three SVPWM Strategies

Three space vector pulse width modulation （SVPWM） schemes, called 7-segment space vector modulation （SVM）, 5-segment SVM and 3-segment SVM are studied in this paper. The basic principle of SVPWM is presented. The switching sequence of different scheme is described. The modulation signals, DC bus voltage utilization, and output line voltage harmonic of these schemes are analyzed by the MATLAB software with different modulation index M and frequency modulation index N. The simulation results are analyzed and show that discontinuous modulating functions lead a reduction of switching actions. The DC bus voltage utilization of three schemes is almost the same. For all three SVM, the frequency modulation index N will affect the harmonic characteristic, and the modulation index M will affect DC bus voltage utilization and the harmonic content. The experiment is implemented by the DSP of TMS320F2812. The results validate three algorithms and the simulation.     

Further Study of A-Related Quantum Interference of П-State Diatomic on Collision-Induced Rotational Energy Transfer

In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Lett. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A1П, v = 3) with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.     

Yb3+/Er3+共掺锗碲酸盐玻璃上转换发光增强机理的研究

玻璃的最大声子能量决定稀土离子的上转换发光强度，但本研究发现：Yb^3 ／Er^3 共掺锗碲酸盐玻璃在980nm LD抽运下，上转换荧光强度随着Bi2O3对PbO的取代和碱金属离子半径的增大而明显增强．而Raman光谱显示基质玻璃的最大声子能量并不随Bi2O3对PbO的取代和碱金属离子半径的增大而变化，但玻璃的最大声子密度随着Bi2O3对PbO取代和碱金属离子半径的增大而降低．从玻璃无辐射跃迁概率的角度，通过分析表明，最大声子密度的降低是玻璃上转换发光强度增强的主要原因．     

基于非线性预测效果的癫痫脑电信号的特征提取方法

在非线性时间序列预测研究的基础上,提出了基于非线性预测效果的癫痫脑电信号特征提取方法,从脑电信号中自动检测出癫痫脑电信号.采用基于可预测性的选取嵌入维数的方法确定脑电信号序列的嵌入维数,进行相空间重构.实验结果表明:基于非线性预测效果的特征提取方法提取的特征能明显地区分癫痫脑电信号与正常脑电信号,该非线性特征提取方法适合小数据量的情况且对噪声的稳定性好.     

Skin Effect of Reversely Switched Dynistor in Short Pulse Discharge Application

The skin effect in the reversely switched dynistor （RSD） devices is investigated in this paper. Based on the plasma bipolar drift model of the RSD, the current density distributions on the chip are simulated with considering the skin effect. The results indicate that the current density on the border can be several hundred to a thousand A/cm2 higher than that in the center of the chip. The skin effect becomes more prominent as the voltage increases and the inductance decreases in the main circuit. The phenomenon that most of a certain group of chips break over on the border has proved the existence of the skin effect.     

基于局域相关向量机回归模型的小尺度网络流量的非线性预测

基于非线性时间序列局域预测法与相关向量机回归模型, 本文提出了局域相关向量机预测方法, 并应用于预测实际的小尺度网路流量序列. 应用基于信息准则的局域预测法邻近点的选取方法来选取局域相关向量机回归模型的邻近点个数. 对比分析了局域相关向量机预测法、前馈神经网络模型与局域线性预测法对网络流量序列的预测性能, 其中前馈神经网络模型的参数采用粒子群优化算法来优化. 实验结果表明: 邻近点优化后的局域相关向量机回归模型能够有效地预测小尺度网络流量序列, 归一化均方误差很小; 局域相关向量机回归模型生成的时间序列具有与原网络流量时间序列相一致的概率分布; 局域相关向量机回归模型的预测精度好于前馈神经网络模型的与局域线性预测法的. 关键词： 小尺度网络流量 非线性时间序列预测方法 局域预测法 相关向量机回归模型     

Spectral Characterization of Couplings in a Mixed Optomechanical Model *

Abstract:We study the spectrum of single-photon emission and scattering in a mixed optomechanical model which consists of both linear and quadratic optomechanical interactions. The spectra are calculated based on the exact long-time solutions of the single-photon emission and scattering processes in this system. We find that there exist some phonon sideband peaks in the spectra and there are some sub peaks around the phonon sideband peaks under proper parameter conditions. The correspondence between the spectral features and the optomechanical interactions is confirmed, and the optomechanical coupling strengths can be inferred by analyzing the resonance peaks and dips in the spectra.