High-performance nonfused ring electron acceptor with a steric hindrance induced planar molecular backbone

Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs.     

LDPC-based space-time coded OFDM systems over correlated fadingchannels: Performance analysis and receiver design

We consider a space-time coded (STC) orthogonal frequency-division multiplexing (OFDM) system with multiple transmitter and receiver antennas over correlated frequency- and time-selective fading channels. It is shown that the product of the time-selectivity order and the frequency-selectivity order is a key parameter to characterize the outage capacity of the correlated fading channel. It is also observed that STCs with large effective lengths and ideal built-in interleavers are more effective in exploiting the natural diversity in multiple-antenna correlated fading channels. We then propose a low-density parity-check (LDPC)-code-based STC-OFDM system. Compared with the conventional space-time trellis code (STTC), the LDPC-based STC can significantly improve the system performance by exploiting both the spatial diversity and the selective-fading diversity in wireless channels. Compared with the previously proposed turbo-code-based STC scheme, LDPC-based STC exhibits lower receiver complexity and more flexible scalability. We also consider receiver design for LDPC-based STC-OFDM systems in unknown fast fading channels and propose a novel turbo receiver employing a maximum a posteriori expectation-maximization (MAP-EM) demodulator and a soft LDPC decoder, which can significantly reduce the error floor in fast fading channels with a modest computational complexity. With such a turbo receiver, the proposed LDPC-based STC-OFDM system is a promising solution to highly efficient data transmission over selective-fading mobile wireless channels     

On the stability of Riemannian manifold with parallel spinors

Inspired by the recent work [HHM03], we prove two stability results for compact Riemannian manifolds with nonzero parallel spinors. Our first result says that Ricci flat metrics which also admit nonzero parallel spinors are stable (in the direction of changes in conformal structures) as the critical points of the total scalar curvature functional. Our second result, which is a local version of the first one, shows that any metric of positive scalar curvature cannot lie too close to a metric with nonzero parallel spinor. We also prove a rigidity result for special holonomy metrics. In the case of SU(m) holonomy, the rigidity result implies that scalar flat deformations of Calabi-Yau metric must be Calabi-Yau. Finally we explore the connection with a positive mass theorem of [D03], which presents another approach to proving these stability and rigidity results. Dedicated to Jeff Cheeger for his sixtieth birthday     

Optimal resource allocation for wireless video over CDMA networks

We present a multiple-channel video transmission scheme in wireless CDMA networks over multipath fading channels. We map an embedded video bitstream, which is encoded into multiple independently decodable layers by 3D-ESCOT video coding technique, to multiple CDMA channels. One video source layer is transmitted over one CDMA channel. Each video source layer is protected by a product channel code structure. A product channel code is obtained by the combination of a row code based on rate compatible punctured convolutional code (RCPC) with cyclic redundancy check (CRC) error detection and a source-channel column code, i.e., systematic rate-compatible Reed-Solomon (RS) style erasure code. For a given budget on the available bandwidth and total transmit power, the transmitter determines the optimal power allocations and the optimal transmission rates among multiple CDMA channels, as well as the optimal product channel code rate allocation, i.e., the optimal unequal Reed-Solomon code source/parity rate allocations and the optimal RCPC rate protection for each channel. In formulating such an optimization problem, we make use of results on the large-system CDMA performance for various multiuser receivers in multipath fading channels. The channel is modeled as the concatenation of wireless BER channel and a wireline packet erasure channel with a fixed packet loss probability. By solving the optimization problem, we obtain the optimal power level allocation and the optimal transmission rate allocation over multiple CDMA channels. For each CDMA channel, we also employ a fast joint source-channel coding algorithm to obtain the optimal product channel code structure. Simulation results show that the proposed framework allows the video quality to degrade gracefully as the fading worsens or the bandwidth decreases, and it offers improved video quality at the receiver.     

Enantiomeric separation of basic drugs with partially filled serum albumin as chiral selector in capillary electrophoresis.

A reliable method is presented for the chiral separation of three basic drugs (mexiletine, chlorpheniramine and propranolol) with serum albumins (human and porcine, HSA and PSA) as chiral selectors by capillary electrophoresis in combination with the partial filling technique. Based on the systematic optimization of operation variables, the chiral separation of mexiletine, chlorpheniramine and propranolol was achieved in the pH 7.4 phosphate buffer by using HSA, PSA and PSA as selectors, respectively. The chiral recognition ability of HSA and PSA was compared. HSA and PSA show a different chiral recognition ability for each of the three drugs. In addition, the association constants between enantiomeric drugs and proteins were determined to be 2.00 and 3.80 x 10(2) M(-1) for mexiletine and HSA, 0.59 and 1.12 x 10(3) M(-1) for chlorpheniramine and PSA, and 0.87 and 1.42 x 10(3) M(-1) for propranolol and PSA. The method for the chiral separation and determination of association constants possesses the advantages of simple performance, effective avoiding of the interference of the UV detection from protein, and lowering of the reagent consumption.     

An overall study of convergence conditions for algorithms in nonlinear programming

Since the point-to-set maps were introduced by Zangwill^[1] in the study of conceptual algorithms, various sufficient conditions for the algorithms to be of global convergence have been established. In this paper, the relations among all these conditions are illustrated by a unified approach; still more, unlike the sufficient conditions previously given in the literature, a new necessary condition is put forward at the end of the paper, so that it implies more applications.     

激光除锈过程的实时监测技术研究

对激光除锈过程中的实时监测技术进行了实验研究,结果表明:除锈过程中产生的声波强度会随着表面清洁度的变化而发生明显的变化,声波信号包含了除锈过程中的大量信息,可作为激光除锈实时监测的基本信号.     

自相似结构壳模型

为了扩展以简谐振子为基矢的常规壳模型（ＳＭ）计算到晕核，提出了自相似结构壳模型（ＳＳＭ）．通过对简谐振子动能项和势能项的重度规以及单粒子平均场模拟，可以得到ＳＳＭ中的单粒子轨道有态相关的圆频率，在ＳＳＭ中，晕核大的均方根半径、厚的中子皮以及Ｂｏｒｒｏｍｅａｎ晕核和的束缚态性质能够再现出来。     

平面交叉玻璃波导型微透镜阵列光学性能研究

介绍了平面交叉玻璃光波导型半球形微透镜阵列的制作方法.利用积分形式的光线方程式讨论了半球形微透镜的光学特性,得到了半球形微透镜的光线轨迹方程式和焦距表示式,理论结果与实验数据是一致的.     

Analysis and Optimization of the Energy Efficiency in the 802.11 DCF

This paper introduces an analytical model to investigate the energy efficiency of the IEEE 802.11 distributed coordinated function (DCF). This model not only accounts for the number of contending nodes, the contention window, but also the packet size, and the channel condition. Based on this model, we identify the tradeoff in choosing optimum parameters to optimize the energy efficiency of DCF in the error-prone environment. The effects of contention window and packet size on the energy efficiency are examined and compared for both DCF basic scheme and DCF with four-way handshaking. The maximum energy efficiency can be obtained by combining both the optimal packet size and optimal contention window. To validate our analysis, we have done extensive simulations in ns-2, and simulation results seem to match well with the presented analytical results. The Ohio Board of Regents Doctoral Enhancements Funds and the National Science Foundation under Grant CCR 0113361 have supported this work. Xiaodong Wang received his B.S. degree in communication engineering from Beijing Information Technical Institute of China in 1995, and his M.S. degree in electric engineering from Beijing University of Aeronautics and Astronautics of China in 1998. He joined China Telecom in 1998 where he worked on communication protocols for telecommunication. From June 2000 to July 2002, he worked on GSM base station software development at Bell-labs China, Beijing, China. Currently he is a Ph.D. student in Computer Engineering at University of Cincinnati. His research activities include wireless MAC protocols, energy saving for wireless sensor networks. He is a student member of the IEEE. Jun Yin received the BS degree in automatic control from Dalian Railway Institute of China in 1997, and the MS degree in flight control from Beijing University of Aeronautics and Astronautics of China in 2001. Since 2001 she has been a Ph.D. student in the OBR Research Center for Distributed and Mobile Computing at the University of Cincinnati. Her research interests include performance evaluation of 802.11 MAC protocol, wireless ad hoc networks and sensor networks. She is a student member of the IEEE. Dharma P.Agrawal IEEE Fellow, 1987; ACM Fellow, 1998; AAAS Fellow, 2003 Dr. Agrawal is the Ohio Board of Regents Distinguished Professor of Computer Science and Computer Engineering in the department of Electrical and Computer Engineering and Computer Science, University of Cincinnati, OH. He has been a faculty member at Wayne State University, (1977–1982) and North Carolina State University (1982–1998). He has been a consultant to the General Dynamics Land Systems Division, Battelle, Inc., and the U. S. Army. He has held visiting appointment at AIRMICS, Atlanta, GA, and the AT&T Advanced Communications Laboratory, Whippany, NJ. He has published a number of papers in the areas of Parallel System Architecture, Multi computer Networks, Routing Techniques, Parallelism Detection and Scheduling Techniques, Reliability of Real-Time Distributed Systems, Modeling of C-MOS Circuits, and Computer Arithmetic. His recent research interest includes energy efficient routing, information retrieval, and secured communication in ad hoc and sensor networks, effective handoff handling and multicasting in integrated wireless networks, interference analysis in piconets and routing in scatternet, use of smart directional antennas (multibeam) for enhanced QoS, Scheduling of periodic real-time applications and automatic load balancing in heterogeneous workstation environment. He has four approved patents and three patent filings in the area of wireless cellular networks.