全文获取类型
收费全文 | 3225篇 |
免费 | 519篇 |
国内免费 | 366篇 |
专业分类
化学 | 1520篇 |
晶体学 | 50篇 |
力学 | 185篇 |
综合类 | 20篇 |
数学 | 308篇 |
物理学 | 884篇 |
无线电 | 1143篇 |
出版年
2024年 | 10篇 |
2023年 | 82篇 |
2022年 | 123篇 |
2021年 | 155篇 |
2020年 | 167篇 |
2019年 | 143篇 |
2018年 | 135篇 |
2017年 | 127篇 |
2016年 | 147篇 |
2015年 | 165篇 |
2014年 | 200篇 |
2013年 | 199篇 |
2012年 | 281篇 |
2011年 | 280篇 |
2010年 | 199篇 |
2009年 | 210篇 |
2008年 | 189篇 |
2007年 | 153篇 |
2006年 | 188篇 |
2005年 | 127篇 |
2004年 | 94篇 |
2003年 | 88篇 |
2002年 | 102篇 |
2001年 | 82篇 |
2000年 | 43篇 |
1999年 | 56篇 |
1998年 | 52篇 |
1997年 | 52篇 |
1996年 | 39篇 |
1995年 | 32篇 |
1994年 | 37篇 |
1993年 | 23篇 |
1992年 | 16篇 |
1991年 | 21篇 |
1990年 | 12篇 |
1989年 | 18篇 |
1988年 | 11篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 16篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1981年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 5篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有4110条查询结果,搜索用时 390 毫秒
1.
2.
3.
Yin-Feng Wang Meng Li Jin-Ming Teng He-Ye Zhou Chuan-Feng Chen 《Advanced functional materials》2021,31(49):2106418
Recently, circularly polarized organic light-emitting diodes (CP-OLEDs) fabricated with thermally activated delayed fluorescence (TADF) emitters are developed rapidly. However, most devices are fabricated by vacuum deposition technology, and developing efficient solution-processed CP-OLEDs, especially nondoped devices, is still a challenge. Herein, a pair of triptycene-based enantiomers, (S,S)-/(R,R)-TpAc-TRZ, are synthesized. The novel chiral triptycene scaffold of enantiomers avoids their intermolecular π–π stacking, which is conducive to their aggregation-induced emission characteristics and high photoluminescence quantum yield of 85% in the solid state. Moreover, the triptycene-based enantiomers exhibit efficient TADF activities with a small singlet-triplet energy gap (ΔEST) of 0.03 eV and delayed fluorescence lifetime of 1.1 µs, as well as intense circularly polarized luminescence with dissymmetry factors (|gPL|) of about 1.9 × 10−3. The solution-processed nondoped CP-OLEDs based on (S,S)-/(R,R)-TpAc-TRZ not only display obvious circularly polarized electroluminescence signals with gEL values of +1.5 × 10−3 and −2.0 × 10−3, respectively, but also achieve high efficiencies with external quantum, current, and power efficiency up to 25.5%, 88.6 cd A−1, and 95.9 lm W−1, respectively. 相似文献
4.
Meihua Shen Dr. Xinpeng Zhao Dr. Lu Han Nanxi Jin Prof. Song Liu Prof. Tao Jia Prof. Zhijun Chen Prof. Xiuhua Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(20):e202104137
Solar-driven interfacial vaporization by localizing solar-thermal energy conversion to the air−water interface has attracted tremendous attention. In the process of converting solar energy into heat energy, photothermal materials play an essential role. Herein, a flexible solar-thermal material di-cyan substituted 5,12-dibutylquinacridone (DCN−4CQA)@Paper was developed by coating photothermal quinacridone derivatives on the cellulose paper. The DCN−4CQA@Paper combines desired chemical and physical properties, broadband light-absorbing, and shape-conforming abilities that render efficient photothermic vaporization. Notably, synergetic coupling of solar-steam and solar-electricity technologies by integrating DCN−4CQA@Paper and the thermoelectric devices is realized without trade-offs, highlighting the practical consideration toward more impactful solar heat exploitation. Such solar distillation and low-grade heat-to-electricity generation functions can provide potential opportunities for fresh water and electricity supply in off-grid or remote areas. 相似文献
5.
6.
Tianyu Gong Longhai Guo Jun Ye Lifan He Teng Qiu Xiaoyu Li 《Journal of polymer science. Part A, Polymer chemistry》2021,59(16):1807-1820
The implementation of covalent adaptable networks (CANs) in general resin system is becoming attractive. In this work, we propose a simple post-curing strategy based on the core-shell structured acrylate latex for the achievement on both the improved general performance and the CANs characteristics in latex films. The building to the CANs was relied on the introduction of 4,4′-diaminophenyl disulfide as the curing agent, which cured the acetoacetoxy decorated shell polymer through the ketoamine reaction. The metathesis reaction of aromatic disulfides in the crosslinking segments enabled the thermally induced dynamic behavior of the network as revealed in the stress relaxation tests by comparison with other diamine crosslinking agents without the incorporation of disulfide. The synergism of the dynamic crosslinking of the shell polymer and static crosslinking in the core polymer contributed to the improved mechanical strength (15 MPa, strain% = 250%) and the suppressed water adsorption (~1% in 24 h of soaking) of the latex film, which exhibited above 90% of recovery in both strength and strain from a cut-off film damage within 1 h at 80°C. Moreover, the cured latex film could be recycled, and 75% of the mechanical performance was regained after three fragmentation-hot-pressing cycles. These, in addition with the feasible and environmental friendly characteristics, suggest a sustainable paradigm toward the smart thermosetting latex polymers. 相似文献
7.
8.
Development of an LC‐MS/MS method for determining the pharmacokinetics of clonidine following oral administration of Zhenju antihypertensive compound
下载免费PDF全文
![点击此处可从《Biomedical chromatography : BMC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jing Qin Limin Wang Lihong Wu Jun Chen Teng Shen Yongji Li Limei Han Jianxin Wang 《Biomedical chromatography : BMC》2015,29(7):1068-1075
Zhenju antihypertensive compound (ZJAHC) is a combined Chinese–Western medicine formula including clonidine (CLO), hydrochlorothiazide (HCT), rutin, Chrysanthemum indicum extract and pearl powder. Compared with CLO preparations, ZJAHC shows improved activities and decreased adverse effects. It is believed that the side effects of CLO are caused by its high peak plasma concentration. Hence, study of the influence of ZJAHC on the pharmacokinetic behaviors of clonidine seems essential. In present study, the plasma concentrations of CLO were determined with a liquid chromatography–tandem mass spectrometry (LC‐MS/MS) method. The MS/MS transitions monitored for clonidine and internal standard were 230.2 → 213.1 and 152.2 → 110.2, respectively. The analyte was quantified in a single run within 3 min. The pharmacokinetic study showed that the area under the plasma concentration–time curve of CLO in ZJAHC (60 µg/kg CLO) was similar to that of CLO‐HCT‐high (120 µg/kg CLO) but the peak concentration was much lower than that in CLO‐HCT‐high. ZJAHC could enhance the bioavailability without greatly increasing peak concentration of clonidine. This comprehensive effect of enhancing the bioavailability and avoiding the high peak plasma concentration for CLO might mainly result from the co‐contribution of Western medicine and traditional Chinese medicine (TCM), while the effect of TCM was stronger than that of Western medicine. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
9.
10.
对铌酸锂晶体进行γ射线辐照处理,吸收光谱显示基础吸收边紫移,480nm波长附近出现一明显吸收峰,这是由空位色心V0和Nb^4+缺陷引起的,Nb^4+的存在进一步被EPR实验所证实。本文对上述辐照缺陷的产生机理进行了讨论。 相似文献