PHOTOELECTRIC EFFECTS IN DYE-SENSITIZED ARTIFICIAL LIPID MEMBRANES

Using dyes of known redox potentials the specific mechanisms of dark and light potential generation is analyzed in pigmented lipid membranes. The role of the ionic and electronic conductance, as well as the redox potential gradient is specifically related to the observed open circuit voltage developed across the membrane. The results can be most easily explained by the redox electrode model.     

包覆型纳米铜-银双金属粉研究

目前,导电胶或者电磁波屏蔽涂料用的导电性填料主要有三类,一是铜粉,二是银粉,三是铜-银双金属粉。铜粉具有来源广、价格低廉、导电性好等优点,但其抗氧化性能弱;银粉导电性与抗氧化性好,但其资源日益匮乏。大量的研究试图通过对铜粉进行表面改性来提高其性能。表面改性有两种方法,一是包膜处理,用SiO2溶胶处理铜粉,铜粉抗氧化性能提高,但其表面导电性能大大降低犤1犦;另一类方法是在铜粉表面覆盖一层导电性能与抗氧化性能均佳的银或金而制成双金属粉末犤2～5犦。制取高性能的铜-银双金属粉是该领域的研究重点。目前获得铜-银双金属粉的方…     

Are the pyrazolines formed from the reaction of [60]fullerene with alkyl diazoacetates unstable?

[60]Fullerene-fused pyrazolines 1 were prepared by the reaction of C₆₀ with alky diazoacetates under the solid-state high-speed vibration milling conditions as well as in toluene solution. Pyrazolines 1 were stable in refluxing toluene and its thermolysis process in 1,2-dichlorobenzene was investigated, the decomposition rates and activation energies of pyrazolines 1 were obtained. The current work demonstrated that the liquid-phase reaction of C₆₀ with alkyl diazoacetates undergoes via 1,3-dipolar cycloaddition pathway at room temperature, or proceeds via carbene mechanism at a temperature of refluxing toluene, thus clarifies the previous ambiguity of its reaction mechanism.     

1，1'-二羟基-5，5'-联四唑的镧系金属配合物的合成、表征及热行为

以1,1′-二羟基-5,5′-联四唑(H_2BTO)为配体,镧系金属离子作为金属中心,采用溶剂热法制备了5种金属配合物:[La_2(BTO)_3(H_2O)_8]·2H_2O (1)、[Ce_2(BTO)_3(H_2O)_8]·2H_2O (2)、[Pr_2(BTO)_3(H_2O)_8]·2H_2O (3)、[Sm_2(BTO)_3(H_2O)_8]·2H_2O (4)和[Nd_2(BTO)_3(DMF)_4]·6H_2O (5)。通过单晶X射线衍射和元素分析对5种配合物的结构进行了表征。结果表明,5种配合物均属于单斜晶系,P2_1/n空间群。利用差示扫描量热法研究了配合物1～4的热稳定性,采用Kissinger法和Ozawa法分别计算了其热分解动力学参数。     

高分五号卫星偏振遥感陆地上空气溶胶光学厚度

针对多角度偏振成像仪(Directional Polarimetric Camera,DPC)数据,提出了基于多角度多光谱偏振信息的气溶胶光学厚度反演方法。该方法使用Nadal-Breon半经验模型计算地表偏振反射率,以扣除地表影响;采用倍加累加法矢量辐射传输模型构建气溶胶参数查找表,通过计算最小残差,动态确定最优气溶胶模型,从而实现陆地上空气溶胶光学厚度的反演。使用DPC的L1级条带数据,反演获得了中国东部地区气溶胶光学厚度的空间分布,并与MODIS产品和AERONET地基站点数据分别进行了对比,反演结果与MODIS气溶胶产品的整体分布具有很好的一致性;同时,与AERONET地基站点观测结果具有较高的相关性,670 nm和865 nm两个波段的相关系数都在0.8以上,说明该算法模型反演陆地上空的气溶胶光学厚度准确可靠,可为DPC遥感大气气溶胶提供技术支持。     

基于DPC的中国部分区域陆地气溶胶光学厚度反演

大气气溶胶是气候变化与遥感定量化等的重要影响因素,研究气溶胶光学特性具有重要意义.基于高分五号卫星搭载的大气气溶胶多角度偏振探测仪(Directional polarimetric camera,DPC)过境中国区域的数据,开展了气溶胶光学厚度的反演研究.基于矢量辐射传输模型6SV计算构建气溶胶光学特性查找表,采用Ro...     

MSP430F5xxx在高速公路不停车收费系统(ETC)中的应用

本文探讨了使用MSP430F5xxx实现ETC系统中实时HDLC编解码的方法.MSP430F5xxx是T1公司MSP430家族最新产品序列,采用先进的0.18工艺,1MIPS消耗的电流低到了惊人的160μA.同时,FSxxx产品都配备了高效灵活的DMA模块,对16bit数据进行搬移只需要2个时钟周期.     

高精度二维DCT的结构优化算法研究及FPGA实现

提出了一种基于5级流水线的高精度向量乘法器的二维DCT VLSI结构.采用一维DCT行处理,转置RAM存储器,一维DCT列处理的流水线结构代替复用一维DCT算法以提高速度,并且在一维DCT算法模块中,对于系数乘法,采用并行乘法的结构,可以进一步提高运算速度.在高精度方面,采用移位的方案,精度精确到小数点后5位,满足高精...     

HYDROGEN GENERATION FROM ARTIFICIAL SEA HATER IN A SEMICONDUCTOR SEPTUM ELECTROCHEMICAL PHOTOVOLTAIC CELL

Visible light of the solar spectrum is directly converted to stored chemical energy of hydrogen from artificial sea water in a novel electrochemical photovoltaic cell. The principal element of the cell, modeled after the photosynthetic thylakoid membrane, is a semiconductor septum made of polycrystalline n-CdSe thin film deposited on nickel foil, which separates two aqueous solutions. Under short-circuit conditions, vigorous hydrogen evolution was seen at the Ni surface and continued as long as the cell was operated. The novel cell, the concept of which was derived from pigmented bilayer lipid membrane studies, is easy to construct, simple to operate, and appears to be a practical approach to the photochemical conversion and storage of solar energy.     

基于多角度偏振信息反演海洋上空卷云云顶高度

采用偏振辐射信息反演云顶高度时,为了减小由云层及地表偏振辐射特性变化带来的反演结果不确定度,使用490 nm和865 nm通道多角度偏振信息反演卷云云顶高度.理论分析大气顶偏振特征,给出490 nm与865 nm通道偏振特性差异,说明使用此两通道偏振反射率差反演云顶高度的可行性.假设卷云为一般种类混合模型(General Habit Mixture,GHM),使用倍加累加矢量辐射传输模型计算和分析大气顶490 nm和865 nm通道偏振反射率差对卷云有效粒子半径、光学厚度和云顶压强的敏感性.分析表明,当卷云光学厚度大于3时,偏振反射率差对有效粒子半径和光学厚度的变化不敏感,对云顶压强变化敏感.根据敏感性分析结果选择适当的参数构建偏振反射率差查找表,使用查找表方法反演POLDER3数据的卷云云顶高度,并与POLDER3产品和MODIS产品进行比较.结果表明,与POLDER3的官方算法相比,使用偏振反射率差查找表方法有更宽的散射角适用范围,反演结果与MODIS产品有更好的一致性.