全文获取类型
收费全文 | 18967篇 |
免费 | 2885篇 |
国内免费 | 2469篇 |
专业分类
化学 | 10875篇 |
晶体学 | 181篇 |
力学 | 820篇 |
综合类 | 140篇 |
数学 | 1849篇 |
物理学 | 5177篇 |
无线电 | 5279篇 |
出版年
2024年 | 76篇 |
2023年 | 482篇 |
2022年 | 594篇 |
2021年 | 705篇 |
2020年 | 745篇 |
2019年 | 705篇 |
2018年 | 580篇 |
2017年 | 510篇 |
2016年 | 832篇 |
2015年 | 825篇 |
2014年 | 1072篇 |
2013年 | 1376篇 |
2012年 | 1544篇 |
2011年 | 1544篇 |
2010年 | 1141篇 |
2009年 | 1043篇 |
2008年 | 1196篇 |
2007年 | 1090篇 |
2006年 | 1024篇 |
2005年 | 915篇 |
2004年 | 692篇 |
2003年 | 671篇 |
2002年 | 699篇 |
2001年 | 606篇 |
2000年 | 453篇 |
1999年 | 432篇 |
1998年 | 385篇 |
1997年 | 329篇 |
1996年 | 353篇 |
1995年 | 283篇 |
1994年 | 263篇 |
1993年 | 220篇 |
1992年 | 184篇 |
1991年 | 155篇 |
1990年 | 116篇 |
1989年 | 106篇 |
1988年 | 78篇 |
1987年 | 56篇 |
1986年 | 45篇 |
1985年 | 55篇 |
1984年 | 48篇 |
1983年 | 24篇 |
1982年 | 22篇 |
1981年 | 14篇 |
1980年 | 14篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 7 毫秒
1.
2.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation. 相似文献
3.
Polypyrrole Shell@3D‐Ni Metal Core Structured Electrodes for High‐Performance Supercapacitors 下载免费PDF全文
Gao‐Feng Chen Yu‐Zhi Su Pan‐Yong Kuang Zhao‐Qing Liu Dao‐Yi Chen Xu Wu Nan Li Prof. Shi‐Zhang Qiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4614-4621
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). 相似文献
4.
Xiaopo Wu Yangming Shi Weibo Meng Xiaofei Ma Nian Fang 《International Journal of Satellite Communications and Networking》2019,37(3):283-291
Electromagnetic signal emitted by satellite communication (satcom) transmitters are used to identify specific individual uplink satcom terminals sharing the common transponder in real environment, which is known as specific emitter identification (SEI) that allows for early indications and warning (I&W) of the targets carrying satcom furnishment and furthermore the real time electromagnetic situation awareness in military operations. In this paper, the authors are the first to propose the identification of specific transmitters of satcom by using probabilistic neural networks (PNN) to reach the goal of target recognition. We have been devoted to the examination by exploring the feasibility of utilizing the Hilbert transform to signal preprocessing, applying the discrete wavelet transform to feature extraction, and employing the PNN to perform the classification of stationary signals. There are a total of 1000 sampling time series with binary phase shift keying (BPSK) modulation originated by five types of satcom transmitters in the test. The established PNNs classifier implements the data testing and finally yields satisfactory accuracy at 8 dB(±1 dB) carrier to noise ratio, which indicates the feasibility of our method, and even the keen insight of its application in military. 相似文献
5.
Two new homosecoiridoids, named loniaceticiridoside (1) and lonimalondialiridoside (2), were isolated from an aqueous extract of the flower buds of Lonicera japonica. Their structures including the absolute configuration were determined by extensive spectroscopic studies, especially by 2D NMR and CD data analysis. A proposed biosynthetic pathway and preliminary investigations of the biological activity of compounds 1 and 2 are also discussed. 相似文献
6.
Yaping Chen Dr. Kun Rui Prof. Jixin Zhu Prof. Shi Xue Dou Dr. Wenping Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):703-713
Developing clean and sustainable energies as alternatives to fossil fuels is in strong demand within modern society. The oxygen evolution reaction (OER) is the efficiency-limiting process in plenty of key renewable energy systems, such as electrochemical water splitting and rechargeable metal–air batteries. In this regard, ongoing efforts have been devoted to seeking high-performance electrocatalysts for enhanced energy conversion efficiency. Apart from traditional precious-metal-based catalysts, nickel-based compounds are the most promising earth-abundant OER catalysts, attracting ever-increasing interest due to high activity and stability. In this review, the recent progress on nickel-based oxide and (oxy)hydroxide composites for water oxidation catalysis in terms of materials design/synthesis and electrochemical performance is summarized. Some underlying mechanisms to profoundly understand the catalytic active sites are also highlighted. In addition, the future research trends and perspectives on the development of Ni-based OER electrocatalysts are discussed. 相似文献
7.
Studies on metabolism of total glucosides of paeony from Paeoniae Radix Alba in rats by UPLC‐Q‐TOF‐MS/MS 下载免费PDF全文
Wenli Cao Xinguo Wang Haojie Li Xuliang Shi Wencheng Fan Shaohua Zhao Minyan Liu Liying Niu 《Biomedical chromatography : BMC》2015,29(11):1769-1779
Total glucosides of paeony are the active constituents of Paeoniae Radix Alba. In this study, a novel strategy was proposed to find more metabolites and the differences between paeoniflorin, albiflorin and total glucosides of paeony (TGP). This strategy was characterized as follows: firstly, the animals were divided into three groups (paeoniflorin, albiflorin and TGP) to identify the source of TGP metabolites from paeoniflorin or albiflorin; secondly, a generic information‐dependent acquisition scan for the low‐level metabolites was triggered by the multiple mass defect filter and dynamic background subtraction; thirdly, the metabolites were identified with a combination of data‐processing methods including mass defect filtering, neutral loss filtering and product ion filtering; finally, a comparative study was used in the metabolism of paeoniflorin, albiflorin and TGP. Based on the strategy, 18 metabolites of TGP, 10 metabolites of paeoniflorin and 13 metabolites of albiflorin were identified respectively. The results indicated that the hydrolysis, conjugation reaction and oxidization were the major metabolic pathways, and the metabolic sites were the glycosidic linkage, the ester bond and the benzene ring. This study is first to explore the metabolism of TGP, and these findings enhance our understanding of the metabolism and the interactions of paeoniflrin and albiflorin in TGP. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
8.
9.
SOPHO-S系列数字程控交换机是由飞利蒲公司生产的。本文分析了该系列交换机的总体结构,并了它的线路传输技术。 相似文献
10.
Optical bistability in reflective fiber gratings 总被引:3,自引:0,他引:3
Chao-Xiang Shi 《Quantum Electronics, IEEE Journal of》1995,31(11):2037-2043
Optical bistability in a nonlinearly reflective fiber grating through the mode coupling between the LP01 and counter propagation LP02 modes (i,e., the reflective LP01&rlhar2;LP02 mode converter) is investigated by using the coupled-mode theory. Both the transmissive and the reflective properties of this nonlinear device are analyzed, which show that the output-versus-input relation exhibits the optical bistability. The switching power and the bistable hysteresis performances are also discussed. In addition, the comparison between the nonlinearly reflective mode converter (LP01&rlhar2;LP02) and the nonlinear fiber Bragg grating reflector (i,e., the LP01 and counter-propagation LP01 modes) is also presented. It is shown that the former has much lower switching power than the latter 相似文献