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Margarita Valero Brígida Esteban Rafael Peläez Licesio J. Rodrïguez 《Journal of inclusion phenomena and macrocyclic chemistry》2004,48(3-4):157-163
The aim of the present study was to investigate the effect of the presence of thewater-soluble polymer polyvinylpyrrolidone (PVP) MW = 24000 g/mol, on thecomplexation of the phototoxic anti-inflammatory drug naproxen, in its sodiumsalt form, with hydroxypropil-β-cyclodextrin (HP-β-CD). The datashown that the polymer interacts with the free naproxen and with thenaproxen:HP-β-CD inclusion complex. The presence of different proportions of PVP, in the 0–1%(w/w) rangesystematically increased the Kapp of the naproxen:HP-β-CD inclusioncomplex formation. The cause of this increase is that the polymer interactswith the HP-β-CD with a binding constant of K2 = 29000 ± 53 M-1; and with the naproxen:HP-β-CD inclusion complex, to givea ternary complex naproxen:HP-β-CD:PVP. The binding constant of thisprocess was K3 = 5350 ± 1 M-1. NMR data revealed that in the ternary system, PVP is outside of the cyclodextrin, and therefore must be wholly or partially recovering the naproxen:HP-β-CD inclusion complex. 相似文献
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A new family of polyoxygenated stilbenophanes has been synthesized as conformationally restricted analogues of antimitotic combretastatins. By means of the McMurry olefination process, compounds derived from diethyleneglycol and 1,6-hexanediol were obtained, whereas Grubbs' catalyst failed in producing the ring-closing metathesis to this kind of macrocyclic products. 相似文献
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最小一乘稳健多元分析校正 总被引:1,自引:3,他引:1
本文论述最小一乘求解的多元分析校正算法,探讨了最小一乘较常规最小二乘法及其他隐健算法的优点。用计算机数值模拟及实际多组分光谱体系对方法进行了检验,展示了最小一乘法在分析化学计量学中实际应用的可行性。 相似文献
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Ohsuna T Slater B Gao F Yu J Sakamoto Y Zhu G Terasaki O Vaughan DE Qiu S Catlow CR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(20):5031-5040
High-resolution electron microscopy (HREM) has been used to image the surface structure of nano- and micrometer-sized synthetic crystals of zeolite-Linde-L (LTL). Columnar holes and rotational, nano-sized, wheel-like defects were observed within the crystals, where the hole has a minimum size equal to that of the rotational defect. Predictions of surface structure from atomistic computer simulation concur with the observations from HREM and provide insight into the crystal growth mechanism of perfect and defective LTL. Analysis of the energetics of the formation of rotational defect structures reveals that the driving force for defect creation is thermodynamic and furthermore, the rotational defects could be created in high concentrations. Formation of a columnar hole is found to be slightly energetically unfavourable and therefore we speculate that the incidence of both rotational and nano-sized vacancy defects is strongly dependent on kinetic factors and reaction conditions. The morphology of nano- and microcrystalline LTL is contradistinct and we use insights from simulation to propose an explanation of the disparity in crystal shape. 相似文献
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TypeNet是一种基于两层长短时记忆网(LSTM)分支结构的孪生网络模型,在自由文本击键事件序列分类任务上取得了很好的效果,但缺乏可解释性。为此,该文改进了TypeNet模型,提出一种基于单层LSTM分支结构的孪生网络模型TypeNet II。TypeNet II模型用多层感知机度量两个分支输出表征向量差的绝对值体现的特征序列的相似度。模型训练完毕后,用多元二项式回归模拟多层感知机部分,基于得到的多元二项式对模型进行解释。实验结果表明,TypeNet II模型的分类效果超出了已有的TypeNet模型,多元二项式回归的结果具有泛化性,表征向量差的绝对值与相似度量之间存在非线性关系。 相似文献
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The Sixth-Generation (6G) standard for wireless communications is expected to realize ubiquitous coverage for massive Internet of Things (IoT) networks by 2030. Satellite-based communications are recognized as a highly promising technical enabler to satisfy IoT service requirements in the 6G era. This study analyzes multiple access technologies, which are essential for the effective deployment of satellite-based IoT. First, we thoroughly investigate the existing research related to massive access, including information-theory considerations as well as Non-Orthogonal Multiple Access (NOMA) and Random Access (RA) technologies.Then, we explore the influence of the satellite transmission environment on multiple access technologies. Based on this study, a Non-orthogonal Massive Grant-Free Access (NoMaGFA) scheme, which reaps the joint benefits of RA and NOMA, is proposed for asynchronous transmissions in satellite-based IoT to achieve improved system throughput and enhance the system robustness under varying traffics. Finally, we identify some important and interesting future developments for satellite-based IoT, including waveform design, transceiver design, resource allocation, and artificial intelligence-enhanced design. 相似文献
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