超宽带大功率合成器设计北大核心CSCD

在80 MHz~1 GHz频段,单个功率管输出功率能达到100 W以上,为研制输出功率400 W的功率放大器,文中设计了四路功率合成器。该合成器需要实现功率容量大、工作频带宽、体积小的设计目标。在功率容量方面,文中采用悬置带状线结构,其功率容量远远大于微带线结构;在工作频带方面,采用切比雪夫九节阻抗变换器,将工作带宽拓宽为80 MHz~1 GHz;在体积方面,文中合成器的功率合成部分采用Y型节级联实现四路功率合成,阻抗变换部分采用切比雪夫阻抗变换器进行阻抗变换,该结构相较于磁环巴伦功率合成器,不但具有损耗小、平坦度高的优点,而且通过将阻抗变换器设计成曲折的形状,进一步缩小了合成器体积。仿真与实测结果显示该合成器在80 MHz~1 GHz范围内还具有较高的平坦度,合成效率可达90%以上。     

微波单片集成电路的成品率优化

采用建立管芯等效电路模型、灵敏度分析以及统计勘探法对微波单片集成电路进行成品率优化，并编制了软件，加入到ＧａＡｓＩＣＣＡＤ系统中。应用该软件对Ｘ波段低噪声ＭＭＩＣ、超宽带ＭＭＩＣ放大器进行了设计，成品率有较大的提高，电路性能有所改善。     

大型稀疏无约束最优化问题的行列修正算法

本文提出了一类适用于大型稀疏最优化问题的简单易行的行列修正算法，获得了新算法的局部超一性收敛性，大量的数值试验表明这是一个较为理想的修正算不。新算法同样可以用来求解大型对称性非线性方程组。     

激光等离子实验中的低能X射线时间谱解谱方法

利用快速Fourier变换(FFT)算法和反卷积原理对Dante谱议测量波形进行了回推获得了激光等离子体源区低能X射线辐射时间波形。解谱方法采用了W.N.Mcelroy等人提出的SANDⅡ解谱方法并与文献[6]中介绍的限幅迭代和周期性光滑技术相配合计算出了能谱时间关系的16分区结果,给出了1989年6月LF-12强激光装置实验的双束靶、漏靶诊断口,入射口的X射线时间谱以及辐射温度时间关系T_R(i)。     

互贯型螯合树脂的研究．Ⅱ．IPN型含偕胺肟基螯合树脂的合成与性能研究

以交联聚苯乙烯－聚丙烯腈树脂为骨架，经功能基化反应制备出含偕胺肟基团的互贯型螯合树脂。对功能基化反应条件和螯合树脂对金的吸着性能，吸着选择性和吸着机理进行了研究。互贯型螯合树脂的吸着性能与互贯树脂的结构有关，而螯合树脂的选择吸着性则与互贯网络无关．     

Determination of trace-level haloacetic acids in drinking water by ion chromatography-inductively coupled plasma mass spectrometry

A new method for the determination of nine haloacetic acids (HAAs) with ion chromatography (IC) coupled to inductively coupled plasma mass spectrometry (ICP-MS) was developed. With the very hydrophilic anion-exchange column and steep gradient of sodium hydroxide, the nine HAAs could be well separated in 15 min. After suppression with an ASRS suppressor that was introduced in between IC and ICP-MS, the background was much decreased, the interference caused by sodium ion present in eluent was removed, and the sensitivities of HAAs were greatly improved. The chlorinated and brominated HAAs could be detected as 35ClO and 79Br without interference of the matrix due to the elemental selective ICP-MS. The detection limits for mono-, di-, trichloroacetic acids were between 15.6 and 23.6 microg/l. For the other six bromine-containing HAAs, the detection limits were between 0.34 and 0.99 microg/l. With the pretreatment of OnGuard Ag cartridge to remove high concentration of chloride in sample, the developed method could be applied to the determination of HAAs in many drinking water matrices.     

A theoretical study of electronic excited states of photosynthetic reaction center in Rhodopseudomonas viridis

The electronic singlet vertical excited states of photosynthetic reaction center (PSRC) in Rhodopseudomonas (Rps.) viridis were investigated by ZINDO and INDO/S methods. The effects of the interactions of pigment-pigment and pigment-protein on the electronic excitations were examined. The calculation results showed that the interactions of pigment-pigment and pigment-protein play an important role in reasonably assigning the experimental absorption and circular dichroism (CD) spectra of PSRC in Rps. virids. By comparing the theoretically computed excited states with the experimental absorption and CD spectra, satisfactory assignments of the experimental spectroscopic peaks were achieved.     

基于氮化碳复合材料磁性固相萃取结合高效液相色谱法测定尿液中3种羟基多环芳烃

建立了测定尿液中3种羟基多环芳烃的氮化碳复合材料磁性固相萃取结合高效液相色谱-荧光检测法。所构筑的磁性氮化碳材料，经扫描电子显微镜、X射线衍射仪、振动样品磁强计和比表面积分析仪表征后，用于尿液中3种羟基多环芳烃的富集净化。考察了吸附剂用量、吸附时间、洗脱溶液和洗脱体积（单次洗脱体积×洗脱次数）对萃取效率的影响。结合高效液相色谱-荧光分析，在0.25~250 μg/L范围内线性关系良好（相关系数r=0.999），3种羟基多环芳烃的检出限和定量限分别为0.08和0.25 μg/L，回收率为90.1%~102%，日内和日间精密度分别为1.5%~7.7%和2.2%~8.7%。该本方法简单、快速、高效，可用于尿液中羟基多环芳烃的分析。     

Magnetic Large-Mesoporous Nanoreactors Enable Enzymatically Regulated Background-Free and Persistently Signalling Diseases Diagnosis

Diverse diseases and increasing prevalence pose a serious threat to public health. Point-of-care testing (POCT) techniques have imposed superior requirements over sensitivity, selectivity, robustness, affordability, and high-throughput. However, transient signal, complex sample pretreatment, and low signal-to-noise ratio make POCT severely limited in detection accuracy, efficiency, and sensitivity. Here, an enzyme-assisted magnetic large-mesoporous nanoreactor (FS) is constructed for achieving persistent-chemiluminescence signal output and eliminating matrix interference in disease diagnosis. The core-shell structured FS synthesized via an interface coassembly method exhibits uniform size, large and open mesopores (≈22 nm), and intrinsic magnetic separability. Such unique FS acts as efficient nanoreactor for confined cascade reactions enable efficient persistent-chemiluminescence (pCL) signal transduction and high-SNR chromogenic analysis of diverse biomarkers. The developed pCL assays facilitate high-sensitive determination of chronic disease biomarkers glucose and uric acid with detection limits (DL) of 5.4 mg L⁻¹ and 151.2 ng L⁻¹, respectively. The proposed chromogenic immunoassay enables an ultrasensitive and visual determination of alpha-fetoprotein with a DL of 1.2 ng L⁻¹, which is superior to previously published immunoassays. The feasibility of the developed methods for real-world applications are demonstrated in 159 clinical serum samples, and the determination results agree well with the clinical data. The proposed technique is expected to promote highly sensitive disease diagnosis in primary medical institutions and resource-limited areas since not relying on expensive automatic sampling and testing instruments. The good flexibility of the customizable nanoreactor makes it a powerful tool for developing various POCT techniques for rapid, sensitive, and accurate diseases diagnosis.     

基于历史梯度平均方差缩减的协同参数更新方法

随机梯度下降算法(SGD)随机使用一个样本估计梯度,造成较大的方差,使机器学习模型收敛减慢且训练不稳定。该文提出一种基于方差缩减的分布式SGD,命名为DisSAGD。该方法采用历史梯度平均方差缩减来更新机器学习模型中的参数,不需要完全梯度计算或额外存储,而是通过使用异步通信协议来共享跨节点的参数。为了解决全局参数分发存在的“更新滞后”问题,该文采用具有加速因子的学习速率和自适应采样策略：一方面当参数偏离最优值时,增大加速因子,加快收敛速度;另一方面,当一个工作节点比其他工作节点快时,为下一次迭代采样更多样本,使工作节点有更多时间来计算局部梯度。实验表明：DisSAGD显著减少了循环迭代的等待时间,加速了算法的收敛,其收敛速度比对照方法更快,在分布式集群中可以获得近似线性的加速。