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Duygu İNCİ 《应用有机金属化学》2020,34(12):e6016
NOO-type tridentate Schiff base, N-salicylidene-2-aminobenzoic acid, (H2L), and its ternary Cu (II) complex containing H2L Schiff base and 4,7-dimethyl-1,10-phenanthroline (4,7-dmphen), [Cu(4,7-dmphen)(H2L)]27H2O, have been synthesized and characterized by CHN analysis, ESI-MS, FTIR, and single-crystal X-ray diffraction techniques. The interaction of alone H2L Schiff base ligand and ternary Cu (II) complex with biomacramolecules {calf thymus DNA (CT-DNA) and bovine serum albumin (BSA)} has been investigated by electronic absorption and fluorescence spectroscopy. The experimental results indicate that H2L Schiff base ligand and ternary Cu (II) complex bind to CT-DNA by means of a moderate intercalation mode. Furthermore, the fluorescence quenching mechanism between H2L Schiff base ligand and ternary Cu (II) complex with BSA possesses a static quenching process. Radical scavenging activity of H2L Schiff base ligand and ternary Cu (II) complex was measured in terms of EC50, using the DPPH and H2O2 methods. Biomacromolecule interactions and scavenging activity studies revealed that ternary Cu (II) complex yielded better results than H2L Schiff base ligand alone. 相似文献
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Barrette J Bellwied R Braun-Munzinger P Cleland WE Cormier T Dadusc G David G Dee J Diebold GE Dietzsch O Duek E Fatyga M Fox D Greene SV Germani JV Hall JR Hemmick TK Herrmann N Hogue RW Hong B Jayananda K Kraus D Kumar BS Lacasse R Lissauer D Llope WJ Ludlam TW Majka R Makowiecki D Mark SK Mitchell JT Muthuswamy M O'Brien E Pruneau C Rotondo FS Sandweiss J da Silva NC Simon-Gillo J Slaughter J Sonnadara U Stachel J Takai H Takagui EM Throwe TG Waters L Winter C Wolf K Wolfe D Woody CL Xu N 《Physical review letters》1993,70(12):1763-1766
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Lawrence H.Lazarus 《中国化学快报》2011,22(8):907-910
Analogues of endomorphin and tripeptidcs modified at positions 4 and 3,respectively,with various phenylalanine analogues were synthesized and their affinities for opioid receptors were evaluated.Most of the peptides exhibited potentμ-receptor affinity and selectivity,among them,compound 7(Dmt-Pro-Tmp-Tmp-NH_2) exhibited potent affinity for bothμ-andδ-receptors (K_iμ= 0.47 nmol/L,K_iδ= 1.63 nmol/L). 相似文献
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This paper outlines the path from developing broadband ISDN/ATM systems towards the European vision of the next generation mobile system — Universal Mobile Telecommunications System (UMTS).The capabilities of UMTS in terms of services and features compared to the second generation mobile system GSM, and the network technologies behind N-ISDN and B-ISDN, are discussed with proposals for technical developments to satisfy the UMTS requirements. The UMTS radio interface aspects are described and considerations on the network requirements to support these radio aspects are discussed.The requirements within the network for control, switching and transport to support the mobility, service and interconnecting network aspects of UMTS are outlined in conjunction with the technical solutions currently under discussion and some latest thoughts on a potential high-level architecture 相似文献
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