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1.
A technique for the analysis and design of noniterative algorithms for discrete-time, band-limited signal extrapolation is described. The approach involves modeling the extrapolation process as a linear, time-varying (LTV) system, or filter. Together with a previously developed Fourier theory for LTV systems, this model provides a frequency-domain transfer function representation for the extrapolation system. This representation serves as a powerful tool for characterizing and comparing the reconstruction properties of several well-known least squares optimal algorithms for band-limited extrapolation. Moreover, the frequency-domain setting provides a conceptually attractive means for understanding the process of extrapolation itself. Additionally, a least squares approximation methodology for designing LTV filters for band-limited extrapolation is developed. The design technique is shown to unify a broad class of algorithms for extrapolating discrete-time data and, further, to provide a means for designing new and improved extrapolation algorithms 相似文献
2.
This note presents a variation of the well-known Silver–Meal heuristic to deal with lot sizing under a combination of a known, but time-varying, demand pattern along with an incremental quantity discount structure. The heuristic is shown to perform very well on a set of experiments presented in a recent paper in this journal. Additional experiments are performed to further explore the time horizon effects on the relative performance of the newly proposed heuristic compared to the two best performing ones from the previous paper. 相似文献
3.
Benzophenone oxime and substituted benzophenone oximes can be pyroiyzed to the imines to a small extent in the heated transfer line from the gas chromatograph to the mass spectrometer source and to a large extent in the hot injection port of a gas chromatograph at high temperatures using the splitless mode of sample injection. The pyrolysis of the oximes to the imines appears to be largely a surface reaction and does not form the benzophenones as pyrolysis products. Decomposition of benzophenone oxime to benzophenone was produced by another reaction at the front of the chromatographic column. Thermal isomerizaton of benzophenone oxime to benzanilide was not observed under these conditions. 相似文献
4.
Suppression of non-specific adsorption using sheath flow 总被引:1,自引:0,他引:1
The use of a confining sheath fluid within a microfluidic channel in order prevent non-specific adsorption of analytes to the walls of microchannels is demonstrated. A sheath-flow channel fabricated using laser cutting of Mylar films is developed. Numerical simulations of convective and diffusive mass transport within the channel are presented. The device is characterized experimentally using epifluorescence microscopy. It is demonstrated that the device is capable of preventing the adsorption of Rhodamine B to the walls of the channel for a period that would allow for adsorption-free T-sensor measurements to be made within the core of the flow channel. Generalized scaling rules based on the diffusion coefficient, sheath thickness and affinity of the potential adsorbant for the surface material are discussed. The controlled adsorption of the protein bovine serum albumin (BSA) to a gold surface is also demonstrated using SPR microscopy. 相似文献
5.
6.
Burnaby Munson Ta-Min Feng Harry D. Ward Roger K. Murray 《Journal of mass spectrometry : JMS》1987,22(9):606-609
Analysis of the isobutane chemical ionization mass spectra of hexenols, cyclohexenols and various syn/anti pairs of bicyclic and tricyclic homoallylic alcohols shows that: (i) the spectra of the allylic alcohols are dominated by [M + H – H2O]+ and [M + C4H9–H2O]+ ions and contain traces of [M + H]+ ions; (ii) [M + H]+ ions are prominent in the spectra of acyclic and certain cyclic homoallylic alcohols; and (iii) [M + H]+ ions dominate the spectra of other acyclic unsaturated alcohols. The [M + H]+ ions may result from either: (a) protonation of the hydroxyl group, followed by a very rapid intramolecular proton transfer from the protonated hydroxyl group to the carbon–carbon double bond or internal solvation of the protonated hydroxyl group by the carbon–carbon double bond; and/or (b) direct protonation of the carbon–carbon double bond with significant internal solvation of the resulting carbocation by the hydroxyl group, which may lead to carbon–oxygen bond formation to give a protonated cyclic ether. The consequences of placing various geometric constraints on the possible intramolecular interactions between the hydroxyl group and the carbon–carbon double bond in unsaturated alcohols are explored. 相似文献
7.
Charles Allgood Yi Lin Yee-Chung Ma Burnaby Munson 《Journal of mass spectrometry : JMS》1990,25(10):497-502
Dilute mixtures of C6H6 or C6D6 in He provide abundant [C6H6]+· or [C6D6]+· ions and small amounts of [C6H7]+ or [C6D7]+ ions as chemical ionization (CI) reagent ions. The C6H6 or C6D6 CI spectra of alkylbenzenes and alkylanilines contain predominantly M+· ions from reactions of [C6H6]+· or [C6D6]+· and small amounts of MH+ or MD+ ions from reactions of [C6H7]+ or [C6D7]+. Benzene CI spectra of aliphatic amines contain M+·, fragment ions and sample-size-dependent MH+ ions from sample ion-sample molecules reactions. The C6D6 CI spectra of substituted pyridines contain M+· and MD+ ions in different ratios depending on the substituent (which alters the ionization energy of the substituted pyridine), as well as sample-size-dependent MH+ ions from sample ion-sample molecule reactions. Two mechanisms are observed for the formation of MD+ ions: proton transfer from [C6D6]+· or charge transfer from [C6D6]+· to give M+·, followed by deuteron transfer from C6D6 to M+·. The mechanisms of reactions were established by ion cyclotron resonance (ICR) experiments. Proton transfer from [C6H6]+· or [C6D6]+· is rapid only for compounds for which proton transfer is exothermic and charge transfer is endothermic. For compounds for which both charge transfer and proton transfer are exothermic, charge transfer is the almost exclusive reaction. 相似文献
8.
9.
Proton affinities of a series of triphenyl Group Va compounds have been determined by bracketing using reactant ion monitoring: (C6H5)3N = 904 ± 8 kJ mol?1, (C6H5)3P = 968 ± 5 kJ mol?1, (C6H5)3As = 904 ± 8 kJ mol?1 and (C6H5)3Sb = 846 ± 8 kJ mol?1. The large difference in substituent effect of phenyl for hydrogen between As or P and N may result from overlap of the 2p orbitals of N with the sp2 orbitals on the ring carbons and lack of overlap for P or As. Proton affinities of phenylalkylphosphine oxides are essentially the same, 904 ± 8 kJ mol?1, independent of alkyl group. 相似文献
10.
Frank C. De Lucia Jr. Jennifer L. Gottfried Chase A. Munson Andrzej W. Miziolek 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007,62(12):1399-1404
Detecting trace explosive residues at standoff distances in real-time is a difficult problem. One method ideally suited for real-time standoff detection is laser-induced breakdown spectroscopy (LIBS). However, atmospheric oxygen and nitrogen contributes to the LIBS signal from the oxygen- and nitrogen-containing explosive compounds, complicating the discrimination of explosives from other organic materials. While bathing the sample in an inert gas will remove atmospheric oxygen and nitrogen interference, it cannot practically be applied for standoff LIBS. Alternatively, we have investigated the potential of double pulse LIBS to improve the discrimination of explosives by diminishing the contribution of atmospheric oxygen and nitrogen to the LIBS signal. These initial studies compare the close-contact (< 1 m) LIBS spectra of explosives using single pulse LIBS in argon with double pulse LIBS in atmosphere. We have demonstrated improved discrimination of an explosive and an organic interferent using double pulse LIBS to reduce the air entrained in the analytical plasma. 相似文献