Tuning the Basicity of Cyano‐Containing Ionic Liquids to Improve SO2 Capture through Cyano–Sulfur Interactions

A new approach has been developed to improve SO₂ sorption by cyano‐containing ionic liquids (ILs) through tuning the basicity of ILs and cyano–sulfur interaction. Several kinds of cyano‐containing ILs with different basicity were designed, prepared, and used for SO₂ capture. The interaction between these cyano‐containing ILs and SO₂ was investigated by FTIR and NMR methods. Spectroscopic investigations and quantum chemical calculations showed that dramatic effects on SO₂ capacity originate from the basicity of the ILs and enhanced cyano–sulfur interaction. Furthermore, the captured SO₂ was easy to release by heating or bubbling N₂ through the ILs. This efficient and reversible process, achieved by tuning the basicity of ILs, is an excellent alternative to current technologies for SO₂ capture.     

Divergent Synthesis of Oxa-Cyclic Nitrones through Gold(I)-Catalyzed 1,3-Azaprotio Transfer of Propargylic α-Ketocarboxylate Oximes: Experimental and DFT Studies

1,3-Azaprotio transfer of propargylic α-ketocarboxylate oximes, a new type of alkynyl oximes featuring an ester tether, has been explored by taking advantage of gold catalysis. The incorporation of an oxygen atom to the chain of alkynyl oximes led to the formation of two different oxa-cyclic nitrones. It was found that internal alkynyl oximes with an E-configuration deliver five-membered nitrones, whereas terminal alkynyl oximes with an E-configuration afford six-membered nitrones. DFT calculations on four possible pathways supported a stepwise formation of C−N and C−H bonds, in which a 1,3-acyloxy-migration competes with the 1,3-azaprotio-transfer, especially in the case of internal alkynyl oximes. The relative nucleophilic properties of oxygen in the carbonyl group and the nitrogen in the oxime, the electronic effects of alkynes, and the influence of the ring system have been investigated computationally.     

8e6科技走校园路线--校园网行为管理解决方案最受青睐

8e6科技公司近日发布的一项校园网安全状况和网络行为管理调查报告显示:目前校园网关注的主要问题是安全威胁和网络带宽浪费。校园网络遇到的安全问题主要集中在防病毒和网络行为管理上,为此,网络行为管理解决方案成为改善校园网安全和应用状况的优选解决方案。大部分受访人表示,他们很愿意采用网络行为管理解决方案,用以解决目前遇到的网络行为管理问题。而选择网络行为管理解决方案时,他们比较关心的是设备的稳定性、安全性和性价比,通过网络行为管理解决方案来分析、记录网络行为以及阻断不当的上网行为,提高网络的安全性和网络带宽利用…     

SafeNet如何超越SSL VPN

对许多企业而言,不仅需要能够简单部署的安全远程访问解决方案,而且还需要能够紧密地与企业已投资的身份管理系统进行集成的解决方案。为了满足安全远程访问的实时需求,SafeNet最近推出了无边界安全企业级访问服务器(Borderless SecurityEnterprise Access Server)。该产品不仅具备SSL VPN功能,而且利用特殊配置及设定来满足大型企业的严苛要求(快速建立安全存取控制解决方案,并提供迅速的ROI)。该产品安装在稳固且高效能的1U装置中,将IPSec及SSL VPN、稳固的用户认证、多方授权、端点安全兼容检查以及广泛的认证功能整合在一起,…     

McAfee推进在华战略

全球入侵防护和安全风险管理解决方案领先供应商McAfee公司7月5日在华宣布,将正式启用中文名称“迈克菲”。同期还宣布在深圳成立的移动技术研究实验室已投入使用,为包括摩托罗拉在内的移动设备开发安全解决方案。此外迈克菲还与中国联通、百度、软通科技和华擎科技四家中国企业结盟,共同为中国的消费者提供安全产品。纵观McAfee的中国区战略,可以说是品牌加固、科研深化与结盟广泛全线推进。迈克菲寓意双重也许启用一个中文名称本身并不是一件值得大惊小怪的事,但从McAfee董事会主席兼CEO GeorgeSamenuk先生亲临北京别具匠心的新闻发…     

人的安全如何保证?

最近发生的某信息安全专业技术人员泄密事件引起了业界的广泛关注,人们惊诧于原本脆弱的信息系统,由于安全技术人员的泄密而将变得更加脆弱。其实人们关注的范围还不止这些,比如受到牵连的安全公司业务上将受到什么样的打击?被泄密单位的损失如何弥补?有关方面对此类事件如何处     

美讯智内容安全防御全面升级

针对日益突出的内容安全问题,SurfControl美讯智公司日前发布了一系列措施:—针对传统旗舰产品,RiskFilter实现全面大升级至5.0版。—推出全新架构的反间谍软件解决方案:企业安全盾(EnterpriseThreatShield,ETS)。—针对中小用户上网行为管理的需要,推出SurfControlWebFilterSm