A pulsed ion-ion recombination laser

A new mechanism of pulsed laser oscillation based on ion-ion recombination is proposed. The advantages of utilizing this mechanism in a pulsed mode are considered, and the expected characteristics of the proposed lasers are estimated.     

Temporal and radial evolution of the populations of CuI levels inthe CuBr vapor laser

Populations of CuI ground state, resonance, and metastable levels have been measured in CuBr laser with and without hydrogen additives. Temporal evolution and spatial distribution populations have been studied during the excitation pulse and also during the interpulse period of time. Addition of hydrogen results in a smaller rate of resonance and metastable levels excitation and smaller depopulation of the ground state during the excitation pulse. Repopulation of the ground state after the excitation pulse with hydrogen is much faster. CuBr molecules have been detected only in the periphery of the active zone. The density of the CuBr molecules had no noticeable change either during the excitation pulse or in the interpulse period     

微乳液的热力学性质 I: 芳烃类的侧链链长对微乳液热力学函数影响

本文研究以非离子型表面活性剂-正辛醇-水-芳烃类所组成的微乳液, 探讨醇从油相转移到界面相时的自由能变化, 以及温度对自由能的影响。计算出熵和焓的变化, 发现在实验范围内, 上述热力学函数的对数值与芳烃侧链的碳原子数(n)呈线性关系。这些关系式对微乳液的构成和稳定性的讨论是重要的, 还对几种芳烃异构体所构成的微乳液的热力学函数进行了实验和讨论。     

抗坏血酸和尿酸在甘氨酸-壳聚糖修饰玻碳电极上的电化学行为及测定

制备了甘氨酸-壳聚糖复合膜修饰玻碳电极(Gly-CTS/GCE),研究了抗坏血酸(AA)和尿酸(UA)在该修饰电极上的电化学行为。结果表明在pH=5.59的磷酸盐缓冲溶液中,AA、UA在Gly-CTS/GCE上均产生灵敏的不可逆氧化峰,其峰电流与浓度在一定范围内呈良好的线性关系。对AA和UA混合溶液平行测定7次,相对标准偏差分别为4.6%、2.9%,表明该电极重现性和稳定性良好。AA、UA在Gly-CTS/GCE电极上的氧化峰峰电位相差340mV,据此可实现对二者的同时检测,并可应用于实际样品测定。     

Long-lived sealed-off CuBr laser

Investigations on the life-time of a whole-heated sealed-off CuBr laser are reported. Keeping the bromine concentration low enough not less than 500 h of laser operation is already realizable. The decrease of laser power is due mainly to output windows pollution.     

C70X2(X=H,F, Cl)的稳定性和电子光谱

用INDO方法研究C70H2四种异构体的稳定性, 表明其最稳定异构体为1, 9-C70H2和7, 8-C70H2, 两者能量差为16.3KJ.mol^-^1, 与实验值及ab initio计算值接近; 光谱计算表明, 其特征吸收峰与实验值一致。在此基础上预测C70F2和C70Cl2的稳定性和电子光谱, 表明C70F2四种异构体的稳定性顺序与C70H2一致, 而C70Cl2则以21, 42-异构体最为稳定。二者的电子光谱与C70H2极其相似只是在500nm以上有细微差别。     

氢原子在镍台阶面上吸附、振动和表面扩散行为的理论研究

本文用对势方法研究了氢原子在Ni(510)台阶面上的吸附和振动, 计算结果与实验符合得很好。并考察了氢原子在Ni(997)台阶面上的吸附和扩散, 结果表明,台阶对下台面上扩散的氢原子开成捕获势阱, 对上台面扩散的氢原子形成反射势,这也很好地支持了实验结果。     

Characteristics of pulsed discharges in copper bromide and copperHyBrID lasers

Comparative measurements of discharge electrical waveforms have been carried out with a Ne-H₂-CuBr laser, a Ne-CuBr laser, and a Cu HyBrID laser, each of the same size and geometry, and under the same conditions of excitation. From the general similarity of the electrical characteristics of the HyBrID laser and the Ne-H₂-CuBr laser, together with a reappraisal of the role of hydrogen, it is concluded that the main characteristics of these lasers (high efficiency, high average output power, and special features of their excitation pulse waveforms) can all be qualitatively explained if we assume that HBr and not hydrogen (molecular, atomic, or ionic) is the responsible agent which acts via the process of dissociative attachment of electrons to HBr during the interpulse period and during the early stages of the discharge current pulse