A Fluorescent and Colorimetric Sensor for Nanomolar Detection of Co2+ in Water

A new disulfide‐based, imine‐linked fluorescent receptor 1 was processed into organic nanoparticles (ONPs) with an average particle size of 79 nm. The photophysical properties of the ONPs were evaluated by UV/Vis absorption spectroscopy. Receptor 1 selectively recognized Co²⁺ ions in water with a detection limit down to 88 nm.     

New high power DC-DC converter with loss limited switching and lossless secondary clamp

A new isolated high frequency high power DC-DC converter full bridge topology employing one resonant "soft" switching pole that is zero voltage switched and one phase-shifted hard switching pole with loss limited switching for primary switching is presented. The devices in the loss limited pole do not have resonant capacitors across them, but exhibit significantly lower losses than conventional hard switching as the energy dissipation is limited by the finite energy stored in the leakage inductance. This unique combination of zero voltage switching and loss limited switching reduces the switching loss in all primary devices to lower levels. Isolation is achieved by a coaxially wound high frequency transformer with ultra low leakage which increases throughput and efficiency. A novel nondissipative secondary rectifier clamp allows excellent control of reverse recovery energy. Converters that produce 128 kW at 25 kHz have been developed and are commercially available. As this topology exhibits complete control of all parasitic loss mechanisms, it can be easily scaled to higher power levels.     

Reciprocity-transposition-based sinusoidal pulsewidth modulation for diode-clamped multilevel converters

Modulation strategies for multilevel inverters have typically focused on synthesizing a desired set of three phase sinusoidal voltage waveforms using a fixed number of DC voltage levels. This results in the average current injection and hence the net power drawn from the multiple DC bus terminals to be unmatched and time varying. Subsequently, the DC-bus voltages are unregulated, requiring corrective control action to incorporated. In this paper, the principle of reciprocity transposition in introduced as a means for modeling the DC-bus current injection simultaneously as the modulation strategy is formulated. Furthermore, a new sinusoidal pulsewidth-modulation strategy that features constant and controllable current injection at the DC-bus terminals while maintaining output voltage waveform quality is introduced. The proposed strategy is general enough to be applied to converters with an even number of levels and an odd number of levels. Analytical results comparing the performance of the proposed modulator with a conventional multiple carrier modulator are presented for example multilevel converters with four and five levels. Computer simulation results verifying the analytical results are presented for a four-level converter.     

A current source PWM inverter with actively commutated SCRs

Conventional SCR based current source inverters suffer from poor waveform quality due to six step switching. Pulse width modulated current source inverters typically require gate turn off devices with reverse voltage blocking capability which have limited their application. In this paper, a new pulse width modulated current source inverter topology using one gate turn off switch and six SCRs is presented. The converter uses active commutation to realize pulse width modulation in a conventional SCR based current source inverter. Modulation techniques for the proposed inverter, simulation and experimental results are described in the paper. This topology is suitable for high performance, high power applications     

Insect growth regulatory activity of carvacrol-based 1,3,4-thiadiazoles and 1,3,4-oxadiazoles

Abstract 

In designing of novel insect growth regulators (IGRs), biologically occurring carvacrol has been structurally modified to thiadiazole and oxadiazole moieties. Two series of carvacrol analogs containing 1,3,4-thiadiazole (VIIIa–e) and 1,3,4-oxadiazole (IXa–e) derivatives are designed and synthesized. Their structures are confirmed by FT-IR, \(^{1}\text {H}\) NMR, \(^{13}\)C NMR and LC-MS. IGR activity is tested against Spodoptera litura. Several analogs displayed IGR activity against this insect pest. Compounds VIIIe and IXe displayed relatively good IGR activity with \(\text {GI}_{50 }\)values 117.43 and 108.83 ppm against Spodoptera litura, respectively.

Graphical Abstract

Synthesis, characterization and evaluation of carvacrol-based 1,3,4-thiadiazole and 1,3,4-oxadiazole derivatives as potent insect growth regulators (IGRs).

Open image in new window

     

Ion-implantation-induced structural modifications in Y1Ba2Cu3O7−δ superconductor

Ion-implantation-induced structural modifications in Y₁Ba₂Cu₃O_7−δ superconductor are examined by a grazing angle X- ray diffraction technique. By employing a range of grazing angles from 0.3° to 10° it is shown that 100 KeV Ar⁺ inplantation of the superconductor leads to amorphization as well as modification of grain size and orientation at dose values lower than 10¹⁶ ions/ cm². At the dose of 5 × 10¹⁶ ions/ cm² the X-ray diffraction intensity is a factor of 6 less as compared to the original pellet, though the lines themselves are sharp. This shows coexistence of perovskite grains and amorphous matrix.     

General relations and identities for order statistics from non-independent non-identical variables

Some recurrence relations and identities for order statistics are extended to the most general case where the random variables are assumed to be non-independent non-identically distributed. In addition, some new identities are given. The results can be used to reduce the computations considerably and also to establish some interesting combinatorial identities.     

Thermal neutron effect on YBa2Cu3O7

High-Tc superconductor YBa₂Cu₃O₇ was irradiated by thermal neutrons. Significant effects on the critical temperature were found. The changes were also investigated by X-ray diffraction technique.⁶⁵Cu (n, )⁶⁶Cu was the only reason for the degradation in superconducting properties. The existence of an isotope effect is argued.     

An efficient synthesis of rearranged new biologically active benzimidazoles derived from 2-formyl carvacrol

Research on Chemical Intermediates - A new series of benzimidazole derivatives was synthesized by one-pot two-step reaction as a result of unexpected rearrangement during reaction of 2-formyl...