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2.
Bassam Abu Thaher Jalal A. Zahra Mustafa M. El-Abadelah Hans-Hartwig Otto 《Monatshefte für Chemie / Chemical Monthly》2004,40(9):435-439
Nitrilimines were prepared from N-arylhydrazono chlorides and reacted with -alanine yielding the corresponding amidrazones, which were treated with 1,1-carbonyldiimidazole in THF affording the hitherto unknown 3-acetyl-1-aryl-1,4,5,6-tetrahydro-1,2,4-triazepin-7-ones. 相似文献
3.
In the presence of triethylamine, 2-mercaptobenzoic acid readily adds onto acylhydrazonoyl chlorides (1a-c) (precursors of the reactive nitrile imine 1,3-dipolar species) to afford good yields of the corresponding 2-[(2-oxo-1-arylhydrazonopropan-1-yl)mercapto]benzoic acids (2a-c). The latter acyclic adducts, in THF in the presence of 1,1'-carbonyldiimidazole, undergo intramolecular cyclization involving the activated carboxy and the enol functionality to deliver the respective 2-(N-arylhydrazono)-3-oxobenzothiophenes (3a-c). In the solid state, the latter compounds adopt the (Z)-geometry around the C=N double bond as evidenced by single crystal X-ray structure determination for 3b. 相似文献
4.
Summary. N′-Arylacetonitrilimines were generated from acetohydrazonyl chlorides and reacted with mercaptoalkanoic acids forming 4-aryl-5-oxo-3-thiahexanoic
acids. These were cyclized by reaction with dicyclohexyl carbodiimide yielding 2-acetyl-4-aryl-6H-1,3,4-thiadiazin-5-ones.
Received November 13, 2001. Accepted January 9, 2002 相似文献
5.
Jalal A.?Zahra Bassam Abu?Thaher Mustafa M.?El-Abadelah Hans-Hartwig?OttoEmail author 《Monatshefte für Chemie / Chemical Monthly》2005,136(4):567-570
Summary. Nitrilimines prepared from N-arylhydrazono chlorides reacted with 2-mercaptonicotinic acid yielding the corresponding addition products, 2-[(2-oxo-1-arylhydrazonopropan-1-yl)mercapto] nicotinic acids, which were treated with 1,1-carbonyldiimidazole in THF affording by cyclocondensation the corresponding hitherto unknown 2-arylhydrazono-3-oxothieno[2,3-b]pyridines. 相似文献
6.
Till?R?hrich Bassam?Abu Thaher Nico?Manicone Hans-Hartwig?OttoEmail author 《Monatshefte für Chemie / Chemical Monthly》2004,135(8):979-999
Summary. (RS)-2-tert-Butyldimethylsilyl-1,2-thiazetidine-3-acetic acid 1,1-dioxide prepared from (RS)-S-benzyl--homocysteine was condensed via DCC/NHS with various L-amino acid esters or dipeptide esters yielding N-silylated -sultam peptides. A -sultam active ester was isolated as an intermediate. Desilylation with TBAF in THF yielded stable N-unsubstituted products, and deprotection of the benzyl esters was achieved by catalytic hydrogenation. (S)-S-Benzyl--homocysteine was obtained by fractional crystallization of the brucine salt of the racemate and transformed into benzyl (S)-1,2-thiazetidine-3-acetate, which was on the other hand synthesized by an enantiospecific route from -benzyl Boc-L-aspartate. Some -sultam peptides were prepared from the (S)-enantiomer, and finally some -sultam peptides containing D-Ala units were obtained. 相似文献
7.
Zinc sulfide (ZnS) thin films have been deposited on Si (1 0 0) substrate using ultrasonic spray pyrolysis. X-ray diffraction (XRD) analysis revealed that the films are (0 0 2) preferentially oriented with c-axis-oriented wurtzite structure. The crystallinity has been found to improve with film thickness in the 180–6000 nm range. Film structure has been analyzed by XRD, scanning electron microscope, FTIR, and Raman spectroscopies, while the stoichiometry has been verified by energy-dispersive spectroscopy and particle-induced X-ray emission techniques. Electrical properties of the grown films were characterized by current–voltage and capacitance–voltage measurements where, the films show better conducting behavior at higher thickness. 相似文献
8.
Bassam Jamil Mohd Sa’ed Abed Bassam Na’ami Thaier Hayajneh 《Signal, Image and Video Processing》2013,7(6):1029-1040
Security and imperceptibility are fundamental issues for steganography. This paper presents a multi-level steganography system based on concealing and deception. Basically, the secret image is embedded in a cover image, which in turn is embedded in another higher-level cover image. Each steganography level provides additional security, with lower levels implemented using stronger steganography methods. Furthermore, in the event that the higher level steganography is compromised, it would include misleading information to deceive the attacker that he/she is successfully eavesdropping. One challenge of hierarchical system is retaining hidden data in lower level in a higher level stenographic technique. To mitigate this issue, we designed a novel technique which combines discrete cosine transform and least significant bit (LSB). The technique objective is to maximize the capacity and invisibility of the secret image with minimal modification to the cover image (at most k-bits per block). The performance (capacity and peak signal-to-noise ratio) of the proposed method has superior performance compared with LSB since it combines the benefits of 1-bit and 3-bit LSBs. Furthermore, the paper demonstrates that the secret message is successfully embedded and extracted in two-level steganography system with peak signal-to-nose ratio greater than 20 dB. 相似文献
9.
Mostefa Sayhi Nasreddine Haine Belkacem Belaabed Valérie Vigneras 《Journal of Macromolecular Science: Physics》2015,54(10):1183-1195
Conducting polymer blends were prepared using polyaniline doped with para- toluene sulfonic acid (PTSA-PANI) and a polyester polyol-based polyurethane (PU). The morphological, thermal and dielectric properties of the PTSA-PANI/PU blends in the frequency range of 1–5 GHz (S band) were investigated. It was found that the morphology of the samples was affected by the PTSA-PANI loading, resulting in the formation of agglomerates and pathways when above 10 wt%. The thermal stability of the composites was improved with increased PTSA-PANI loading. The electrical conductivity percolation threshold was obtained at 2.5% of PTSA-PANI loading and the electrical conductivity reached the value of 0.13 S/m at a PTSA-PANI loading of 30 wt%. The obtained results for the PTSA-PANI/PU blends prepared indicate a high potential for their successful use in electrical and electromagnetic applications. 相似文献
10.
F-alkyl oxiranes 1 and p-methylbenzene sulfonate ester intermediates 3 derived from 2-F-alkyl ethane -1,2-diols 2 are converted into F-alkyl β-amino alcohols 5 respectively by a two-step process. 相似文献