半参数回归模型估计的平均相合性

在误差序列为Lqmixingale情形下，给出了半参数回归模型中β和g(t)估计，研究了估计量的q阶平均相合性在较一般的条件下，得到了理想的结果     

Mg改性对Co/γ-Al2O3-TiO2催化燃烧丙烷性能影响

采用分步浸渍法制备了系列Mg改性的Co/γ-Al_2O_3-TiO_2催化剂,通过X射线衍射(XRD)、紫外可见漫反射光谱(DR-UV-vis)、N_2吸附-脱附(BET)、X射线光电子能谱(XPS)和H_2程序升温还原(H_2-TPR)等技术对催化剂进行表征,并考察了其对丙烷燃烧的催化性能。结果表明,Co在原始γ-Al_2O_3-TiO_2载体和Mg改性MgO/γ-Al_2O_3-TiO_2载体上均以Co_3O_4的形式存在;Mg掺入后与Al_2O_3作用形成MgAl_2O_4尖晶石,改善了载体的织构性质,提升了Co_3O_4在催化剂载体表面的暴露数量和分散程度。此外,MgAl_2O_4与Co_3O_4相互作用提升了Co_3O_4颗粒表面Co~(3+)/Co~(2+)和O_(ads)/O_(latt)的比例,并削弱了Co-O键键能,从而提升了其对丙烷的催化燃烧活性。当Mg负载量为15%(质量分数)时,在Co/MgO(15%)/γ-Al_2O_3-TiO_2催化剂上进行丙烷燃烧,丙烷90%转化率的温度比无Mg掺杂的Co/γ-Al_2O_3-TiO_2催化剂的降低了45℃,并且连续反应40 h其活性保持稳定。     

970 nm超辐射发光二极管弯曲脊形波导数值分析

本文基于光束传播法(beam propagation method, BPM)和时域有限差分法(finite difference time domain method, FDTD)建立了分析模型,模拟并分析了弯曲脊形波导超辐射发光二极管(superluminescent light emitting diode, SLD)不同结构参数(刻蚀深度、曲率半径、脊形宽度)对波导损耗的影响和倾斜脊形波导不同结构参数(刻蚀深度、脊形宽度、倾斜角度、发射波长)对模式反射率的影响。计算表明,弯曲脊形波导的刻蚀深度和曲率半径是影响波导损耗的重要因素。刻蚀深度较浅使波导对光场的限制作用较弱,过小的曲率半径会使模式传输泄露严重,损耗大大增加。脊形宽度越大,波导损耗越小,其对波导损耗影响较小。脊形波导的端面倾斜角度是抑制模式反射率的重要因素,脊形宽度增加,模式反射率逐渐减小,并在特定的几个角度形成的奇点达到最小值。刻蚀深度对于模式反射率的影响作用较小,但随着刻蚀深度的增加,奇点发生的角度产生了向小角度偏移。在特定的倾斜角度范围内,随着波长减小,奇点的数目会逐渐增加。研究结果可对设计具有优越性能的SLD器件...     

Solution-Mediated Hybrid FAPbI3 Perovskite Quantum Dots for Over 15% Efficient Solar Cell

Organic–inorganic formamidinium lead triiodide (FAPbI₃) hybrid perovskite quantum dot (QD) is of great interest to photovoltaic (PV) community due to its narrow band gap, higher ambient stability, and long carrier lifetime. However, the surface ligand management of FAPbI₃ QD is still a key hurdle that impedes the design of high-efficiency solar cells. Herein, this study first develops a solution-mediated ligand exchange (SMLE) for preparing FAPbI₃ QD film with enhanced electronic coupling. By dissolving optimal methylammonium iodide (MAI) into antisolvent to treat the FAPbI₃ QD solution, the SMLE can not only effectively replace the long-chain ligands, but also passivate the A- and X-site vacancies. By combining experimental and theoretical results, this study demonstrates that the SMLE engineered FAPbI₃ QD exhibits lower defect density, which is beneficial for fabricating high-quality QD arrays with desired morphology and carrier transport. Consequently, the SMLE FAPbI₃ QD based solar cell outputs a champion efficiency of 15.10% together with improved long-term ambient storage stability, which is currently the highest reported value for hybrid perovskite QD solar cells. These results would provide new design principle of hybrid perovskite QDs toward high-performance optoelectronic application.     

三维电大物体四面体剖分公共面快速查找算法

提出了一种查找四面体公共面的快速算法,用于矩量法为基础的体积分方程通用求解算法.该算法可用图的邻接矩阵和关联矩阵概念及其原理导出,并可通过稀疏矩阵的转置与乘法实现,其计算与存储复杂度均为O(N).数值例算结果验证了该算法的有效性,结果比较表明所提算法计算量更少,可用于电大尺寸介质体电磁场分析的前处理中,用以构成通用的分析软件或算法测试平台.     

用于液体激光介质的Nd~(3+)离子掺杂氟化镧纳米颗粒的制备与性能表征

设计并合成了掺杂不同Nd3+离子浓度的氟化镧纳米颗粒,并用油酸进行了表面修饰,使得这类纳米颗粒可分散于常见的有机溶剂中形成透明、均一、稳定的溶液。对纳米颗粒的结构、晶相以及发光性能进行了表征。固体和溶液材料在1 060 nm都有强的发射峰,说明纳米晶格可有效地保护Nd3+离子免受外界环境对发光的猝灭影响。纳米颗粒有机溶液的吸收损耗和散射损耗测试结果表明,其总损耗系数能够满足激光介质材料的损耗要求,为该材料的实用化打下了基础。     

Rationally Investigating the Influence of T1 Location on Electroluminescence Performance of Aryl Amine Modified Phosphine Oxide Materials

The correspondence between triplet location effect and host‐localized triplet–triplet annihilation and triplet–polaron quenching effects was performed on the basis of a series of naphthyldiphenylamine (DPNA)‐modified phosphine oxide hosts. The number and ratio of DPNA and diphenylphosphine oxide was adjusted to afford symmetrical and unsymmetrical molecular structures and different electronic environments. As designed, the first triplet (T₁) states were successfully localized on the specific DPNA chromophores. Owing to the meso‐ and multi‐insulating linkages, identical optical properties and comparable electrical performance was observed, including the same first singlet (S₁) and T₁ energy levels to support the similar singlet and triplet energy transfer and the close frontier molecular orbital energy levels. This established the basis of rational investigation on T₁ location effect without interference from other optoelectronic factors.     

CAXA实体设计解决单晶炉复杂钣金件展开曲线

利用CAXA实体设计软件,在单晶炉设计中解决与炉盖椭球封头相贯的钣金件展开曲线的画法。     

高效率激光二极管泵浦100 Hz 3.5 J Nd∶YAG MOPA激光器

研制了结构简单、高效率激光二极管泵浦Nd∶YAGM0PA激光器.振荡级输出单脉冲能量1.13 J,重复频率为100HZ.MOPA系统输出最大单脉冲能量2.35 J,光-光转换效率为39%.实验结果和理论计算符合较好.     

基于虚拟现实的光电对抗仿真系统的研究

将虚拟现实技术应用于光电对抗仿真领域,采用虚拟现实建模软件Multigen Creator进行视景建模,用视景管理软件OpenGVS来实现场景驱动,构建了一个载机光电对抗仿真系统,并介绍了用OpenGVS来开发光电对抗软件所需要解决的几个关键问题,包括目标的建模、视点的选取,碰撞的检测,以及爆炸效果的产生等。最后根据开发的仿真平台,对红外干扰弹的干扰策略进行了研究。