胶乳对油井水泥水化产物和硬化浆体微结构的影响

利用XRD和SEM?EDS对胶乳油井水泥水化产物及硬化浆体微结构进行了研究。结果表明胶乳并没有改变油井水泥水化产物的种类;微观形貌显示,胶乳的掺入使得水化产物表面形成一层绒状的物质结构,堆积紧密的六方叠片状的Ca（ OH）2晶体形貌变得松散薄片状分布。     

钢渣在强碱性条件下的早期水化性能

本文选用浓度为1.2 mol/L和1.6 mol/L的NaOH溶液为激发剂,研究强碱性环境对钢渣水化1 d和7 d的水化产物、微观形貌及水化结合水的影响,并与钢渣在60℃时的水化性能进行了比较。结果表明:强碱性环境和高温能够促进钢渣活性组分(C2S、C3S和C12A7)的早期水化,但钢渣中的非活性组分(RO和Fe3O4)的水化程度很低;强碱环境和高温对钢渣水化的水化产物种类的影响差异很小;钢渣水化产物的化学结合水量随着碱度的增加而增大,相比于高温,强碱环境对钢渣早期水化的促进作用较大。     

大掺量粉煤灰混凝土长龄期的微观结构

对深圳平安金融中心2年龄期大掺量粉煤灰混凝土基础底板钻芯取样试件进行了强度、渗透性、碳化深度测试,并通过扫描电镜观察了试件中硬化浆体的微观结构。结果显示:大掺量粉煤灰混凝土长龄期力学性能和耐久性能优异;复合胶凝材料硬化浆体密实,骨料与浆体之间结合紧密;粉煤灰反应程度较高,体系中Ca(OH)2含量较低,硬化浆体中生成大量低Ca/Si的C-S-H凝胶。     

Effects of Pt diffusion barrier layer on the interface reaction and electric properties of PZT film/Si (111) sample

The effects of the Pt diffusion barrier layer on the interface diffusion and reaction, crystallization, dielectric and ferroelectric properties of the PZT/Si(111) sample have been studied using XPS, AES and XRD techniques. Hie results indicate that the Pt diffusion barrier layer between the PZT layer and the Si substrate prohibits the formation of TiCx TiSix and SiO2 species in the PZT layer. The Pt barrier layer also completely interrupts the diffusion of Si from the Si substrate into the PZT layer and impedes the diffusion of oxygen from air to the Si substrate greatly. Although the Pt layer can not prevent completely the diffusion and reaction between oxygen and silicon, it can prevent the formation of a stable SiO2 interface layer on the interface of PZT/Si. The Pt layer reacts with silicon to form PtSix species on the interface of Pt/Si, which can intensify the chemical binding strength between the Pt layer and the Si substrate. To play a good role as a diffusion barrier layer, the Pt barrier layer     

Interface diffusion and chemical reaction of PZT layer/Si (111) sample during the annealing treatment in air

The interface diffusion and chemical reaction between a PZT (PbZrxTi1-xO3) layer and a Si(111) substrate during the annealing treatment in air have been studied by using XPS (X-Ray Photoelectron Spectroscopy) and AES (Auger Electron Spectroscopy). The results indicate that the Ti element in the PZT precursor reacted with residual carbon and silicon, diffused from the Si substrate, to form TiCx, TiSix species in the PZT layer during the thermal treatment. A great interface diffusion and chemical reaction took place on the interface of PZT Si also. The silicon atoms diffused from silicon substrate onto the surface of PZT layer. The oxygen atoms, which came from air, diffused into silicon substrate also and reacted with Si atoms to form a SiO2 interlayer between the PZT layer and the Si (111) substrate. The thickness of SiO2 interlayer was proportional to the square root of treatment time. The formation of the SiO2 interlayer was governed by the diffusion of oxygen in the PZT layer at low annealing tempera     

聚合物对油井水泥石微观结构和抗腐蚀性能的影响

将不同组成的油井水泥石放在高温高压的酸性环境中腐蚀1～4个月,观察其腐蚀深度和微观结构变化。结果表明,在同一腐蚀时间内,苯丙胶乳水泥石和环氧树脂水泥石的腐蚀深度小于空白水泥石,腐蚀部分的水化产物受到溶蚀,硫含量增加;但水化产物组成没有变化,也未生成硫化物或碳酸盐。水泥石被腐蚀的原因可能是S2－和CO2－3酸性离子被吸附于CSH内部,导致水化产物溶蚀。     

养护高温对复合胶凝材料水化性能的影响

养护温度对胶凝材料的水化速度和硬化浆体结构有重大影响。本文重点对比研究在常温（20℃）以及高温（65℃）下养护的不同组成的胶凝材料水化性能和硬化浆体的显微结构。原材料采用北京兴发水泥有限公司生产的混凝土外加剂性能检测用基准水泥与内蒙古元宝山一级粉煤灰。试验组C为纯水泥净浆试样，F1为粉煤灰掺量为25％的净浆试样，水胶比（w／b）均采用0.4。     

复合胶凝材料水化过程的ESEM观察

利用环境扫描电镜(ESEM)和X射线衍射分析(XRD)研究了由硅酸盐水泥、粉煤灰和膨胀剂组成的复合胶凝材料的水化产物形貌和硬化浆体结构。复合胶凝材料水化初期有过渡产物钾石膏片状晶体生成,CSH凝胶为约1μm长的晶须,而钙矾石则以六方片状晶核形式存在。在粉煤灰颗粒表面有通过溶解-结晶机制生成的水化产物。在水化后期,CSH成为无特征形貌的致密浆体,其中分布有充分发育的棒状钙矾石晶体。粉煤灰颗粒由表面生成的水化产物与周围的浆体紧密结合成为一个整体。