高温氨化合成GaN微晶

分别利用Ga2O3粉末和Ga2O3凝胶作为Ga源,采用NH3为N源,在950℃下,分别将两种反应物与流动的NH3反应20 min合成了GaN微晶。用X射线衍射(XRD)、扫描电子显微镜(SEM)、选择区电子衍射(SAED)对微晶进行结构、形貌的分析,特别是对两种不同途径合成GaN微晶的XRD进行了分析比较。结果表明,当Ga源温度为950℃时两种不同的合成途径均可得到六方纤锌矿结构的GaN单晶颗粒,在氮化温度为850℃和900℃时,利用Ga2O3粉末作为Ga源,仅有少量的Ga2O3转变为GaN;而采用Ga2O3凝胶作为Ga源,在相同的温度下,大部分凝胶经过高温氨化反应均可转化为GaN。     

量子阱层和垒层具有不同Al组分的270/290/330nm AlGaN基深紫外LED光电性能

为了研究AlGaN量子阱层和垒层中Al组分不同对AlGaN基深紫外发光二极管(LED)光电性能的影响,本文利用MOCVD生长、光刻和干法刻蚀工艺制备了AlGaN量子阱层和垒层具有不同Al组分的270/290/330nm深紫外LED,通过实验和数值模拟计算方法发现,量子阱层和垒层中具有低Al组分紫外LED的AlGaN材料具有较低的位错密度、较高的光输出功率和外量子效率。通过电流-电压(I-V)曲线拟合出的较大的理想因子(3.5)和能带结构图表明,AlGaN深紫外LED的电流产生是隧穿机制占据主导作用,这是因为高Al组分AlGaN量子阱中强极化场造成了有源层区域较大的能带弯曲和电势降。     

ZnO纳米管的制备及光学特性研究

ZnO nanotubes have been fabricated through a carbon thermal reduction deposition process. Structure characterization results show that the ZnO nanotubes have a single crystalline wurtzite hexagonal structure pref- erentially oriented in the c-axis. The diameters of ZnO nanotubes are in the range of 90-280 nm and the wall thickness is about 50-100 nm. Room-temperature photoluminescence measurements of the ZnO nanotubes exhibit an intensive ultraviolet peak at 377 nm and a broad peak centered at about 517 nm. The UV emission is caused by the near band edge emission while the green emission may be attributed to both oxygen vacancy and the surface state. Raman and cathodoluminescence spectra are also discussed. Finally, a possible growth mechanism of the ZnO nanotubes is proposed.     

一种抑制栅极正负向串扰的GaN HEMT无源驱动电路

GaN器件由于其更快的开关速度,比硅器件更容易发生严重的开关振荡,也更容易受到栅源电压振荡的影响。为了抑制GaN基半桥结构中的串扰,提出了一种抑制GaN高电子迁移率晶体管(HEMT)栅极正负向串扰的无源钳位驱动电路来抑制栅源电压振荡。采用基本无源元件建立自举驱动回路,并增加三极管以构成从驱动电路到GaN HEMT的低阻抗米勒电流路径,抑制正负向串扰。在LTspice软件下进行电路模拟仿真,并搭建实验平台进行实测验证,结果表明栅源电压的最大正向串扰可降至1.2 V,最大负向串扰可降至1.6 V,漏源电流的正向和负向串扰均降至2 A以下,证明该电路对栅源电压以及漏源电流的振荡均有良好的抑制效果。     

题目：电子泄露有关的氮化镓蓝光发射二极管低温发光效率行为

The typical light emission efficiency behaviors of InGaN/GaN multi-quantum well （MQW） blue light- emitting diodes （LEDs） grown on c-plane sapphire substrates are characterized by pulsed current operation mode in the temperature range 40 to 300 K. At temperatures lower than 80 K, the emission efficiency of the LEDs decreases approximately as an inverse square root relationship with drive current. We use an electron leakage model to explain such efficiency droop behavior; that is, the excess electron leakage into the p-side of the LEDs under high forward bias will significantly reduce the injection possibility of holes into the active layer, which in turn leads to a rapid reduction in the radiative recombination efficiency in the MQWs. Combining the electron leakage model and the quasi-neutrality principle in the p-type region, we can readily derive the inverse square root dependent function between the light emission efficiency and the drive current. It appears that the excess electron leakage into the p-type side of the LEDs is primarily responsible for the low-temperature efficiency droop behavior.     

氨化Ga2O3/Mg薄膜制备簇状GaN纳米线

通过在1050°C时氨化Ga2O3/Mg薄膜制备出簇状GaN纳米线。用X射线衍射(XRD),傅里叶红外吸收光谱(FTIR)扫描电子显微镜(SEM)和高分辨电子显微镜(HRTEM)对样品进行测试分析。结果表明,GaN纳米线为六万纤锌矿结构单晶相并且成族生长,直径在200～500nm米左右,其长度可达5～10μm。几乎所有纳米线的直径均有逐渐缩小的趋势。对Mg膜的作用进行了初步的分析。     

氮化镓粉末的溶胶凝胶法制备及其结构

报道了一种新颖而有效的二步制备氮化镓粉末的方法. 以乙氧基镓Ga(OC2H5)3作前驱体, 利用溶胶-凝胶法和高温氨化法相结合, 在950 ℃氨化温度下, 将凝胶与流动的NH3反应20 min, 合成了GaN粉末. XRD、FTIR、TEM及SAED的测量结果表明, GaN粉末是六方纤锌矿结构的单晶晶粒, 粉末粒度较均匀, FTIR吸收谱有明显的宽化现象.     

退火温度对硅基GaN薄膜质量的影响

采用电泳沉积法在Si(111)衬底上制备GaN薄膜,并研究退火温度对GaN薄膜晶体质量、表面形貌和发光特性的影响。傅立叶红外吸收谱(FTIR)、X射线衍射(XRD)和扫描电镜(SEM)的测试结果表明所得样品为六方纤锌矿结构的GaN多晶薄膜,随退火温度的升高,晶粒尺寸增大,结晶化程度提高。室温下光致发光谱的测试发现了位于367 nm处的强发光峰和437 nm处的弱发光峰,其发光强度随退火温度的升高而增强,但发光峰的位置并不发生移动。     

四角状氧化锌纳米结构的发光特性研究

The tetrapod ZnO nanostructures are synthesized on the Si （100） substrates using the chemical va- por deposition （CVD） method at 1000 ℃. Each nanostructure has four arms which are about 3-10 μm in length and 0.2-1.5 μm in diameter. Further analyses on structure demonstrate that the tetrapod ZnO nanostructures have single crystalline wurtzite hexagonal structure preferentially oriented in c-axis. The photoluminescence （PL） mea- surements of the tetrapod ZnO nanostructures revealed a UV peak at 382 nm corresponding to the free exciton emission, and a green peak at 523 nm arising from deep level emission. For comparative analysis, cathodolumines- cence （CL） spectra obtained from different regions of an individual tetrapod are investigated. Moreover, a possible growth mechanism of the tetrapod ZnO nanostructures is also discussed based on the experimental results.     

sol-gel法制备GaN纳米棒的研究

采用简单、有效的sol-gel法在1 000℃时通过氧化镓凝胶和氨气反应成功合成了GaN纳米棒。XRD和SAED的测试结果表明,GaN纳米棒为六方纤锌矿结构。用TEM观察发现,大部分GaN纳米棒平直而光滑,直径为200 nm~1.8μm,最长的纳米棒达几十微米。室温下光致发光谱的测试发现了较强的355.6 nm处的紫外发光峰和445.9 nm处的蓝色发光峰。