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1.
Danilov Felix I. Bogdanov Dmytro A. Smyrnova Olena V. Korniy Sergiy A. Protsenko Vyacheslav S. 《Journal of Solid State Electrochemistry》2022,26(4):939-957
Journal of Solid State Electrochemistry - The electrochemical deposition of a nickel–iron alloy from a plating solution based on a deep eutectic solvent (a eutectic mixture of ethylene glycol... 相似文献
2.
3.
Herein, we report an addition to the toolbox for the monitoring and quantification of the hydrolytic decay of pentose-1-phosphates, which are known to be elusive and difficult to quantify. This communication describes how apparent equilibrium shifts of a nucleoside phosphorolysis reaction can be employed to calculate hydrolytic loss of pentose-1-phosphates based on the measurement of post-hydrolysis equilibrium concentrations of a nucleoside and a nucleobase. To demonstrate this approach, we assessed the stability of the relatively stable ribose-1-phosphate at 98 °C and found half-lives of 1.8–11.7 h depending on the medium pH. This approach can be extended to other sugar phosphates and related reaction systems to quantify the stability of UV-inactive and hard-to-detect reaction products and intermediates. 相似文献
4.
5.
Pan Huang Dawen Xu Robert M. Reich Felix Kaiser Boping Liu Fritz E. Kühn 《Tetrahedron letters》2019,60(24):1574-1577
A first example of an Et2Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis. 相似文献
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8.
P. David J. Hartfiel H. Janszen R. von Mutius J. Arvieux L. Farvacque B. Berthier B. Bonin J. C. Lugol 《Zeitschrift für Physik A Hadrons and Nuclei》1987,326(4):367-372
The excitation function of the fission probability P E E x) for238U has been measured in the reaction238U(α, α′ f) at 480 MeV bombarding energy. The reaction mechanism of this reaction is discussed for excitation energies belowB nf , the threshold for second chance fission, and aboveB nf up toE x =37 MeV. In comparing with results from fission induced by photons and by particle transfer reactions the (α, α′f) reaction gives too low values for the fission probabilityP f at excitation energies well aboveB nE . The role of the quasi-elastic knock-out process in this reaction is discussed. 相似文献
9.
M. Brando N. Büttgen V. Fritsch J. Hemberger H. Kaps H.-A. Krug von Nidda M. Nicklas K. Pucher W. Trinkl A. Loidl E.W. Scheidt M. Klemm S. Horn 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(3):289-298
We present susceptibility, microwave resistivity, NMR and heat-capacity results for Li1-xZnx(V1-yTiy)2O4 with 0 ?
x
? 0.3 and 0 ?
y
? 0.3. For all doping levels the susceptibility curves can be fitted with a Curie-Weiss law. The paramagnetic Curie-Weiss temperatures
remain negative with an average value close to that of the pure compound Θ≈ - 36 K. Spin-glass anomalies are observed in the susceptibility, heat-capacity and NMR measurements for both type of dopants.
From the temperature dependence of the spin-lattice relaxation rate we found critical-dynamic behavior in the Zn doped compounds
at the freezing temperatures. For the Ti-doped samples two successive freezing transitions into disordered low-temperature
states can be detected. The temperature dependence of the heat capacity for Zn-doped compounds does not resemble that of canonical
spin glasses and only a small fraction of the total vanadium entropy is frozen at the spin-glass transitions. For pure LiV2O4 the spin-glass transition is completely suppressed. The temperature dependence of the heat capacity for LiV2O4 can be described using a nuclear Schottky contribution and the non-Fermi liquid model, appropriate for a system close to
a spin-glass quantum critical point. Finally an (
x
/
y
,
T
)-phase diagram for the low-doping regime is presented.
Received 16 March 2001 and Received in final form 30 October 2001 相似文献
10.
H. G. Bohlen W. von Oertzen R. Kalpakchieva B. Gebauer S. M. Grimes A. Lenz T. N. Massey M. Milin Ch. Schulz Tz. Kokalova S. Torilov S. Thummerer 《Physics of Atomic Nuclei》2003,66(8):1494-1500
The structure of neutron-rich beryllium isotopes has been investigated using different heavy-ion-induced transfer reactions. In neutron transfer reactions, the population of final states shows a strong sensitivity to the chosen core nucleus, i.e., the target nuclei 9Be or 10Be, respectively. Molecular rotational bands up to high excitation energies are observed with 9Be as the core due to its pronounced 2α-cluster structure, whereas only a few states at low excitation energies are populated with 10Be as the core. For 11Be, a detailed investigation has been performed for the three states at 3.41, 3.89, and 3.96 MeV, which resulted in the most probable spin-parity assignments 3/2+, 5/2?, and 3/2?, respectively. Furthermore, we have studied particle-hole states of 16C using the 13C(12C, 9C)16C reaction and found 14 previously unknown states. Using the 12C(12C, 9C)15C reaction, five new states were observed for 15C. 相似文献