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Inoue S Wang W Präsang C Asay M Irran E Driess M 《Journal of the American Chemical Society》2011,133(9):2868-2871
The first N-donor-stabilized phosphasilene LSi(SiMe(3))═PSiMe(3) (L = PhC(NtBu)(2)) has been synthesized in 87% yield through 1,2-silyl migration of the (Me(3)Si)(2)P-substituted, N-heterocyclic silylene [LSi-P(SiMe(3))(2)]. Remarkably, the latter reacts with dichlorotriphenylphosphorane Ph(3)PCl(2) to give the unprecedented 4π-electron Si(2)P(2)-cycloheterobutadiene [(LSi)(2)P(2)] with two-coordinate phosphorus atoms. The striking molecular structures as well as the (29)Si and (31)P NMR spectroscopic features of both products indicate the presence of zwitterionic Si═P bonds which is also in accordance with results by DFT calculations. 相似文献
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Metrangolo P Präsang C Resnati G Liantonio R Whitwood AC Bruce DW 《Chemical communications (Cambridge, England)》2006,(31):3290-3292
New, halogen-bonded fluorinated mesogens are reported; the expected microphase separation associated with perfluoroalkyl chains is surprisingly absent in the mesophase. 相似文献
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