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1.
Yuwei Wang Jia-Jun Yan Shengnan Hu Prof. David James Young Prof. Hong-Xi Li Prof. Zhi-Gang Ren 《化学:亚洲杂志》2021,16(18):2681-2686
A photoluminescent bimetallic cluster [Ag10Cu6(bdppthi)2(C≡CPh)12(MeOH)2(H2O)](ClO4)4 ( 1 , bdppthi=N,N’-bis(diphenylphosphanylmethyl)-tetrahydroimidazole} was synthesized from the PNNP type ligand bdppthi generated in-situ. Upon excitation at 365 nm, 1 exhibited strong phosphorescent emission at 630 nm, which was selectively quenched by NH3 in air or water. The sensing of NH3 was rapid and recoverable, with detection limits of 53 ppm (v/v) in N2 and 21 μmol/L (0.36 ppm, w/w) for NH3 ⋅ H2O in water. Cluster 1 could potentially serve as a bifunctional chemical sensor for the efficient detection of ammonia in waste-gas and waste-water. 相似文献
2.
Peng-Yan Gui Xiao-Hui Yan Wen-Juan Yuan Yuan-Liang Ma Xiao Ding Shuai Liu 《Natural product research》2019,33(19):2830-2836
A new A, D-seco limonoid, named 12-acetyloxyperforatin (1), along with three known ones, were isolated from the leaves of Harrisonia perforata. Their structures were elucidated on the basis of spectroscopic analysis, including extensive NMR techniques and computational modelling. These compounds showed no inhibitory activity against the 11β-HSD1 enzyme. 相似文献
3.
Ji-Dong Lou Chun-Ling Gao Li Li Zhi-Gang Fang 《Monatshefte für Chemie / Chemical Monthly》2006,41(10):1071-1074
A new procedure for the selective oxidation of alcohols to the corresponding aldehydes and ketones with potassium permanganate
supported on aluminum silicate at room temperature under solvent-free conditions and shaking is reported. 相似文献
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模糊关系矩阵传递闭包的Warshall算法 总被引:8,自引:2,他引:6
通过对照关系的传递闭包和模糊关系的传递闭包,把求关系矩阵的传递闭包的算法完整地推广到模糊关系矩阵上。 相似文献
8.
为了在亚临界到临界点这个大范围内保证制冷剂物性计算的快速、稳定、可逆,提出将整个数据区间划分成若干个子区间分别进行隐式拟合,并且保证相邻子区间连接点处的连续与光滑,以及通过求分析解从隐式方程中得到显式物性计算式的方法.以美国国家标准局开发的程序REFPROP6.01的计算结果作为数据源,以R410A为例对该方法做了验证.得出快速物性计算公式的应用范围为饱和温度-60℃至临界温度,与NIST REFPROP 6.01的计算结果进行比较表明,计算速度快1500倍,平均相对偏差小于0.01%. 相似文献
9.
We investigate the two methods of defining the surface gravity ,κ on the horizon, which are the metric definition and the definition given by the spacetime conformal method. It is found that the latter is of greater generality. By this method, we find that ,κ of η- ξ spacetime is equal to the exponent factor α in the coordinate transformation, which confirms the argument that η- ξ spacetime can be considered as the background spacetime for finitetemperature field theories. The reasons why the metric definition of ,κ can not be applied in η- ξ spacetime are presented. 相似文献
10.
Xin‐Gui Li Run‐Feng Chen Mei‐Rong Huang Mei‐Fang Zhu Qun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2073-2092
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004 相似文献