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ZEN Jyh-Myng 《高等学校化学研究》2001,17(3)
We report here the development of chemical sensors based on screen-printed technology in our research group to solve major analytical problems in environmental and clinical aspects. The purpose of the research is aimed at the enhancement of selectivity and sensitivity for analysis and monitoring of pollutants and analytes using novel chenically modified screen-printed electrodes. For example, an enzyme reactor coupled with a copper-plated screen-printed carbon electrode (CuSPE) was developed for glucose sensing. The electrocatalytic reduction of enzymatically produced H2O2 at the CuSPE was determined by flow injection analysis (FIA) in pH 7.4 PBS. The proposed method was applied to determine glucose content in fruit juice and clinical sample and satisfactory results with good recoveries were obtained. A thoroughly kinetics and mechanism study was also done for those systems that are verified in analytical applications. 相似文献
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ZHANG Zhi-qian 《应用数学和力学(英文版)》2005,26(8):1064-1071
IntroductionAs one of the meshfree methods, multiple scale reproducing kernel particle method(RKPM)[1,2]bears, besides the common features of all meshfree methods, a uniqueinherent feature of multiresolution analysis by which the structural response can b… 相似文献
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基于多尺度再生核质点法(RKPM)的多分辨分析特性,给出了适于求解二维问题的h型自适应分析方法,讨论了不同高梯度指标对检测高梯度区的影响,同时还提出了基于邻节点搜索(SNN)及局部Delaunay三角分解(LDT)技术的适于任意节点分布的无网格自适应分析节点加密技术.通过对二维线弹性平面应力及平板弯曲问题的h型自适应分析,说明了不合适的高梯度指标将对自适应分析的收敛造成不良影响,且LDT节点加密技术较SNN技术的效率更高.数值算例的结果说明自适应分析的有效性、稳定性及良好的收敛特性. 相似文献
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快速溶剂萃取一气相色谱法测定土壤中多氯联苯Aroclor系列 总被引:1,自引:0,他引:1
建立了快速溶剂萃取、浓硫酸净化、气相色谱法测定土壤中多氯联苯Aroclor系列的方法.方法线性良好、灵敏度高、回收率在70%~110%之间、相对标准偏差RSD小于17%,并用于有证的标准土壤样品及环境实样的分析,结果满意. 相似文献
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为考察缢蛏育苗过程中光强的控制幅度, 研究了不同光照强度对缢蛏稚贝生长的影响. 试验分别选择1mm和5mm不同附着基厚度和4组不同光照强度试验, 时间为10d, 平均光强分别为A: (12244±5290)lx、B: (3792±2105)lx、C: (380±145)lx、D: (14±11)lx(光暗比12h:12h). 当附着基厚度为1mm时, 初始大小(0.26±0.02)mm缢蛏稚贝在A、B、C、D组的生长大小和成活率分别为(1.17±0.11)mm和(72.2±3.9)%、(1.25±0.12)mm和(84.6±4.1)%、(1.55±0.13)mm和(89.7± 4.5)%, (1.32±0.11)mm和(82.1±3.6)%. C组缢蛏稚贝生长大小和成活率都最大, 各组差异显著. 当附着基厚度为5mm时, 缢蛏稚贝在A、B、C、D组的生长大小和成活率分别为(1.48±0.12)mm和(86.3±3.7)%、(1.52±0.13)mm和(89.6±3.9)%、(1.62±0.14)mm和(88.4±4.0)%, (1.41±0.11)mm和(84.3±3.9)%. C组缢蛏稚贝生长大小和成活率都最大, 但是各组没有显著差异. 当实验对象换成较大(1.45±0.16)mm缢蛏稚贝, 光照强度对于薄附着基内稚贝的生长的影响更为明显. 结果表明: 光照强度对缢蛏稚贝生长有明显影响, 稚贝生长过程中最适的光照强度为(380±145)lx, 高于或低于此光照范围, 稚贝的生长率都会受到不同程度的抑制; 适当增加附着基厚度有利于高光强下大规格稚贝的发育生长. 相似文献
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基于磁/惯性传感器旋转弹体定姿的Kalman滤波器设计 总被引:1,自引:0,他引:1
微惯性传感器精度较低,其漂移会引起很大的姿态误差,不能提供长时间稳定姿态;磁传感器组合的姿态角误差不随时间累积但姿态角更新速度慢。针对这一问题提出了利用磁/惯性传感器构建低成本姿态探测系统的方案,设计了Kalman滤波器融合二者信息——以磁传感器解算的姿态角和等效旋转矢量法解算的姿态角之差作为观测量,以惯性传感器的漂移和姿态误差角作为状态变量,整个解算过程无需使用地磁场强度。仿真结果表明了该算法的有效性,二者组合定姿可实现高精度的姿态测量。 相似文献
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In this paper we have calculated the variations of the gap Δ'(0,d) and transition temperature T'c in small metallic grains as functions of grain size (or the level spacing d between discrete electronic states) for the cases of odd and even numbers of electrons by applying the random matrix theory to the mean field theory. We find the presence of enhancement of superconductivity and critical dc, where the superconductivity of small grains breaks down. This agrees with Anderson's prediction (1959 J. Phys. Chem. Solids 11 28). We find that in the grains, as the size is lowered, the transition temperature T'c decreases and Δ'(0,d)/kBT'c≤πe-γ in odd numbers of electrons, and for Gaussian orthogonal and unitary ensembles in some regimes Δ'(0,d)/kB T'c>πe-γ in even numbers of electrons. 相似文献
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Tahir SAVRAN Abdurrahman KARAG
Z ükriye Nihan KARUK ELMAS Duygu AYDIN Furkan
ZEN Kenan KORAN Fatma Nur ARSLAN Ahmet Orhan G
RGÜLÜ brahim YILMAZ 《Turkish Journal of Chemistry》2020,44(4):1148
A fluorogenic probe based on a coumarin-derivative for Cu2+ sensing in CH3CN/H2O media (v/v, 95/5, 5.0 μM) was developed and applied in real samples. 3-(4-chlorophenyl)-6,7-dihydroxy-coumarin (MCPC) probe was obtained by synthetic methodologies and identified by spectral techniques. The probe MCPC showed remarkable changes with a “turn-off” fluorogenic sensing approach for the monitoring of Cu2+ at 456 nm under an excitation wavelength of 366 nm. The response time of the probe MCPC was founded as only 1 min. The detection limit of the probe MCPC was recorded to be 1.47 nM. The binding constant and possible stoichiometric ratio (1:1) values were determined by Benesi-Hildebrand and Job’s plot systems, respectively. The mechanism of the probe MCPC with Cu2+ was further confirmed by ESI-MS and FT-IR analyses, as well as supported by theoretical calculations. Furthermore, the probe MCPC was successfully employed for the practical applications to sense Cu2+ in different herbal and black tea samples. The proposed sensing method was also verified by ICP-OES method. 相似文献
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Zhi-qian Zang Yu-fei Luo Dong Zhang Xin-hua Wan Qi-feng Zhou Department of Polymer Science & Engineering College of Chemistry Peking University Beijing China 《高分子科学》2000,(2):101-107
Novel side-chain liquid-crystalline poly(meth)acrylates were synthesized using 1-(3-hydroxyl-propyl)-3-[(4"-cyano-p-terphenyloxycarbonyl)alkyl]-1,1,3,3-tetramethyldisiloxane as the key intermediate. The polymers used a disiloxanemoiety as decoupling spacer with cyano-p-terphenyl as mesogenic unit. The products were characterized by NMR, GPC,DSC and polarizing optical microscopy. All the polymers with cyano-p-terphenyl mesogens formed a stable mesophase.However, if the mesogenic unit is replaced by cyano-p-biphenyl, the liquid crystalline character will be lost. The results alsoshowed that the decoupling is incomplete even if a complex and very flexible decoupling spacer is deliberately incorporatedto obtain the highest possible decoupling effect. 相似文献