Fabricating blazing grating on NGD by photochemical etching

This paper tries to introduce the reader to the method of using photochemical re-action to copy holographic optical elements(HOEs)in relief.The holographic blazing gratingso copied is groove depth adjustable phase modulability enlarged through copying and 3.3times the diffraction efficiency(DE)of the original grating.It is expected that the newmethod will lead to the mass production of the light-weight HOEs at low cost.     

全硅MCM-41担载的加氢脱硫催化剂的TPR研究

用TRP技术研究了以全硅MCM-41(Si-MCM-41)和HNO3交换的全硅MCM-41(H-MCM-41)为载体制备的Ni-Mo、Co-Mo和Ni-W加氢脱硫(HDS)催化剂的还原性能，并以0．8(wt)％二苯并噻吩(DBT)的十氢萘溶液为模型化合物，在高压固定床反应器上考察了上述催化剂的加氢脱硫(HDS)反应性能。结果表明，Si-MCM-41经稀HNO3交换后，所担载的Ni-Mo和Ni-W催化剂还原性能、HDS活性和加氢活性有显著变化，但对Co-Mo催化剂影响不大。这说明在Ni-Mo／H-MCM-41和Ni-W／H-MCM-41中可能存在氢溢流现象，DBT的HDS活性与载体表面酸性和氢溢流有关。     

GMA熔融接枝EPDM的研究

以甲基丙烯酸缩水甘油酯（ＧＭＡ）为接枝单体，过氧化二异丙苯（ＤＣＰ）为引发剂，对三元乙丙胶（ＥＰＤＭ）进行了熔融接枝，在烃链上引入极性基团，以改善ＥＰＤＭ与极性聚合物的相容性。用差示扫描量热计（ＤＳＣ）研究了ＧＭＡ的聚合温度，用富里叶红外（ＦＴ－ＩＲ）、凝胶渗透色谱（ＧＰＣ）对接枝产物进行了表征。实验结果表明，产物的接枝率和凝胶量可以通过反应条件（温度、时间、反应物组成及加料方式）来控制。     

Effect of chemical composition and heat treatment condition on microstructure and magnetic properties of nanocrystalline BaDyxFe12−xO19 (x = 0.1, 0.2, 0.3, 0.4) microfibres

A series of BaDy_xFe_12?xO₁₉ ferrite microfibres have been synthesized from metal nitrates and citric acid by the sol–gel method. TG-DSC, XRD, FTIR, FESEM, TEM and VSM were employed to characterize the thermal decomposition process, crystallite sizes, structure and magnetic properties of ferrite microfibres. The effect of calcined temperature, holding time, ion substitution on structure, magnetic properties of barium ferrite microfibres was investigated. The nanoparticle growth mechanism of ferrite microfibres was discussed. The results indicated that the hexaferrite phase was formed at 750 °C and Dy³⁺ ions entered the magnetoplumbite lattice. However, the reflections shift to a lower angle and the characteristic peaks of ferrite microfibres in FTIR shift to the lower wavenumber with the Dy content increasing. The VSM results shown that saturation magnetization (M _s ) gradually increased with calcined temperature increasing and holding time prolonging, while coercive force (H _c ) revealed an increase at first and then decreases. With the Dy content increasing, the M _s achieved values of M _s  = 50 emu?g^?1 (297 K) and 70 emu?g^?1 (77 K) and the H _c value shown a continuous reduction from 515 kA??m^?1 (297 K) and 435 kA?m^?1 (77 K) (x = 0.0) to 242 and 215 kA?m^?1 (x = 0.4).     

厚胶光刻非线性畸变的校正

利用厚胶光刻技术制作大深度微结构元件是一种有效的途径,但厚胶光刻过程中的非线性畸变对光刻面形质量的严重影响限制了该技术的应用,基于此,提出了一种对掩模透射率函数进行校正的方法。分析空间像形成及其在光刻胶内传递、曝光、显影等过程中非线性因素的影响,利用模拟退火算法对掩模透射率函数进行校正,以提高光刻面形质量,并以凹面柱透镜为例,给出了校正前后的显影轮廓模拟结果,其校正后浮雕面形的体积偏差仅为2.63%。该方法在有效改善面形质量的同时,并没有引起掩模的设计、制作难度及费用增加,这对于设计、制作高质量的微结构元件有重要意义。     

水热处理对纳米HZSM－5沸石酸性质及其降低汽油烯烃性能的影响

 采用水蒸气和碱性氨水蒸气在500℃下对纳米HZSM－5沸石催化剂进行了水热处理改性，并用XRD，IR，NH3－TPD和XRF对催化剂进行了表征．以降低FCC汽油（≤70℃馏分）烯烃含量为探针反应，考察了不同水热处理介质对催化剂酸性质和催化性能的影响．结果表明，经不同介质水热处理后，纳米HZSM－5沸石中约10％的Al2O3被脱除，总酸量降低，导致积炭失活的强酸中心明显减少；不同水热处理介质对催化剂的总酸量没有明显影响，而对酸中心类型分布的影响较大．水热处理改性使催化剂活性的稳定性明显改善，初始活性降低．同时，水热处理改性降低了催化剂对芳构化反应的催化活性，提高了对异构化反应的催化活性．采用氨水（0．5mol／L）蒸气处理的纳米HZSM－5催化剂其降烯烃催化活性更为稳定．在给定的反应条件下，FCC汽油的烯烃含量（φ）由65．9％降低到约26％，产物中烯烃、芳烃（主要是C7～C9芳烃）和烷烃含量分别保持在25％，19％和55％左右，辛烷值基本不变．     

CdS Reinforced with CoSX/NiCo-LDH Core-shell Co-catalyst Demonstrate High Photocatalytic Hydrogen Evolution and Durability in Anhydrous Ethanol

At present, inefficient charge separation of single photocatalyst impedes the development of photocatalytic hydrogen evolution. In this work, the CoS_X/NiCo-LDH core-shell co-catalyst was cleverly designed, which exhibit high activity and high stability of hydrogen evolution in anhydrous ethanol system when coupled with CdS. Under visible light (λ≥420 nm) irradiation, the 3 %Co/NiCo/CdS composite photocatalyst exhibits a surprisingly high photocatalytic hydrogen evolution rate of 20.67 mmol g⁻¹ h⁻¹, which is 59 times than that of the original CdS. Continuous light for 20 h still showed good cycle stability. In addition, the 3 %Co/NiCo/CdS composite catalyst also shows good hydrogen evolution performance under the Na₂S/Na₂SO₃ and lactic acid system. The fluorescence (PL), ultraviolet-visible diffuse reflectance (UV-vis) and photoelectrochemical tests show that the coupling of CdS and CoS_X/NiCo-LDH not only accelerates the effective transfer of charges, but also greatly increases the absorption range of CdS to visible light. Therefore, the hydrogen evolution activity of the composite photocatalyst has been significantly improved. This work will provide new insights for the construction of new co-catalysts and the development of composite catalysts for hydrogen evolution in multiple systems.     

衍射微透镜列阵在Shack-Hartmann波前传感器中的应用

菲涅耳衍射微透镜列阵是目前广泛应用的衍射光学元件之一,它是基于衍射原理,由计算机设计,并通过微细加工技术制作成的.本文介绍了8相位台阶菲涅耳衍射微透镜列阵的制作方法,并描述了一个用16×16微透镜列阵形成的小型 Shack-Hartmann 波前传感实验系统,用该系统可对入射波前进行测量和重建.     

深蚀刻二元光学元件

提出一种新颖的，蚀刻位相深度超过２π的深蚀刻二元光学技术，并从理论上分析深蚀刻二元光这元件与衍射效率的关系，然后用计算机进行模拟与分析，得到深蚀刻二元光学元件特性后一些初步研究结果。     

Numerical simulation and experiment of TA2 sheet forming under laser shock

The effects of laser energy and different shock spaces and shock times on the TA2 titanium sheet deformation are investigated experimentally and simulated numerically by ABAQUS software. The results indicate that the amount of TA2 sheet deformation increases with the increase of laser energy, varies with shock order and shock path, and is the greatest when the shocks are along the length of sheet and symmetrical.The numerically simulative results are consistent with the experimental data.