全文获取类型
收费全文 | 406篇 |
免费 | 19篇 |
国内免费 | 1篇 |
专业分类
化学 | 276篇 |
晶体学 | 22篇 |
力学 | 1篇 |
数学 | 13篇 |
物理学 | 114篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 13篇 |
2015年 | 5篇 |
2014年 | 12篇 |
2013年 | 17篇 |
2012年 | 17篇 |
2011年 | 15篇 |
2010年 | 13篇 |
2009年 | 24篇 |
2008年 | 25篇 |
2007年 | 19篇 |
2006年 | 21篇 |
2005年 | 24篇 |
2004年 | 19篇 |
2003年 | 17篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 9篇 |
1998年 | 2篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 11篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 9篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 9篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1973年 | 4篇 |
1972年 | 2篇 |
排序方式: 共有426条查询结果,搜索用时 15 毫秒
1.
We demonstrate the potential of femtosecond two-color pulse interferometry for in vitro optical glucose monitoring, by dispersion of the group refractive index in a glucose solution sample with respect to a red-color
light and a blue-color light. By comparison with femtosecond one-color pulse interferometry, the basic performance of the
present system with regard to sensitivity, quantitativeness, and tolerance to surrounding disturbances, is evaluated. The
resulting accuracy and precision of glucose determination are 77 and 118mg/dl for 10-mm-sample-thickness, respectively. This
near-common-path configuration of the two-color pulse light provides good stability to fluctuations of sample temperature,
which is important in clinical applications. Considering the performance of femtosecond two-color pulse interferometry as
an optical glucose sensor, a suitable measurement site for in vivo optical glucose monitoring is discussed. 相似文献
2.
3.
A wetting/dewetting process was utilized to prepare self-organized organic dye particles of micrometer and submicrometer size.
Near-field scanning optical microscopy successfully identified near-field excited near-field fluorescence from single particles.
The majority of the small particles with diameters around 2 mm or less, however, did not show fluorescence under near-field
observation. In contrast, far-field fluorescence, when excited by a polarized evanescent field, was observed, with the intensity
depending on the excitation polarization, indicating that molecules' transition moment within dye particles was oriented parallel
to the substrate surface. Single particle fluorescence spectrum consistently showed an identical sharp peak with a large redshift,
indicating that the particles were composed of identical dye aggregates similar to J-aggregates. These observations suggest
that the near-field at the probe tip was polarized parallel to the probe axis. Another observation, that molecules were oriented
in a similar direction among adjacent particles, suggests that the dewetting process contributed to the alignment of the molecular
direction among adjacent particles, which further proves that the present specimen was formed by a self-organizing mechanism. 相似文献
4.
Shindo M Yoshikawa T Itou Y Mori S Nishii T Shishido K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,12(2):524-536
Ynolates were found to react with alpha-alkoxy-, alpha-siloxy-, and alpha-aryloxyketones at room temperature to afford tetrasubstituted olefins with high Z selectivity. Since the geometrical selectivity was determined in the ring opening of the beta-lactone enolate intermediates, the torquoselectivity was controlled by the ethereal oxygen atoms. From experimental and theoretical studies, the high Z selectivity is induced by orbital and steric interactions rather than by chelation. In a similar manner, alpha-dialkylamino ketones provided olefins with excellent Z selectivity. These products can be easily converted into multisubstituted butenolides and gamma-butyrolactams in good yield. 相似文献
5.
F. de Corte K. Masumoto A. De Wispelaere F. Bellemans 《Journal of Radioanalytical and Nuclear Chemistry》1995,192(1):91-96
A dedicated NAA calibration method was developed for the determination of the neutron spectrum monitor elements Co, Au and Lu in alloyed wires and foils, with an accuracy of better than 1%. The method does not require quantitative micropipetting for preparing the standards, and leads to vanishing errors caused by flux inhomogeneities and by differences in counting geometry and gamma attenuation. Its performance was tested by analysing various NIST, IRMM and RX aluminium-based materials with certified or specified Co, Au or Lu content. 相似文献
6.
Charged particle activation analysis of phosphorus in biological materials using the31P (α,n)34mCl reaction has been studied. Since34mCl is also produced by the32S (α,pn) and the35Cl (α, α′ n) reactions, the thick-target yield curves on phosphorus, sulfur and chlorine were determined in order to choose
the optimum irradiation conditions. As a result, it was found that the activation analysis for phosphorus without interferences
from surfur and chlorine is possible by bombarding with less than 17 MeV alphas. The applicability of this method to biological
samples was then examined by irradiating several standard reference materals. It was confirmed that phosphorus can readily
be determined at the detection limit of 1 μg free from interferences due to the matrix elements. 相似文献
7.
8.
9.
10.