全文获取类型
收费全文 | 629篇 |
免费 | 16篇 |
国内免费 | 3篇 |
专业分类
化学 | 377篇 |
晶体学 | 17篇 |
力学 | 16篇 |
数学 | 85篇 |
物理学 | 153篇 |
出版年
2023年 | 5篇 |
2022年 | 18篇 |
2021年 | 11篇 |
2020年 | 5篇 |
2019年 | 14篇 |
2018年 | 15篇 |
2017年 | 16篇 |
2016年 | 41篇 |
2015年 | 15篇 |
2014年 | 18篇 |
2013年 | 35篇 |
2012年 | 35篇 |
2011年 | 33篇 |
2010年 | 20篇 |
2009年 | 22篇 |
2008年 | 21篇 |
2007年 | 22篇 |
2006年 | 23篇 |
2005年 | 28篇 |
2004年 | 12篇 |
2003年 | 8篇 |
2002年 | 13篇 |
2001年 | 9篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 8篇 |
1994年 | 6篇 |
1993年 | 11篇 |
1992年 | 13篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 5篇 |
1985年 | 7篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1972年 | 6篇 |
1971年 | 6篇 |
1969年 | 4篇 |
1967年 | 4篇 |
1939年 | 4篇 |
排序方式: 共有648条查询结果,搜索用时 0 毫秒
1.
Chetan Bhadaliya Bala Krishna Panigrahy Dipanjan Goswami Sovan Maiti Sanjay Jagannath Gurule Arshad H. Khuroo 《Biomedical chromatography : BMC》2022,36(4):e5337
A selective, highly sensitive, precise, and novel bioanalytical method has been developed and validated to quantify sinococuline, an active constituent present in the phytopharmaceutical drug product containing Cocculus hirsutus plant extract, in vivo. Chromatographic separation was achieved on a Luna Omega Polar-C18 bonded analytical column maintained at 45°C. The isocratic mobile phase consisted of methanol and ammonium formate buffer (60:40, v/v) at acidic pH with a low flow rate of 0.250 mL/min. Detection was performed on an API 4000 mass spectrometer using electrospray ionization in positive polarity and multiple reaction monitoring mode to achieve a lower limit of quantification of 1.50 ng/mL. Excellent accuracy and precision were obtained after extracting the analyte from plasma samples using a chemical analogue as an internal standard in the absence of an isotope-labeled compound. The extraction efficacy was evidenced from recovery study, and the analyte was found to be stable in plasma. Validation study demonstrated linearity with coefficient of correlation, r ≥ 0.99, and minimal matrix effect. This bioanalytical method was successfully applied to evaluate pharmacokinetic parameters of sinococuline from a phase I clinical trial of an aqueous extract of C. hirsutus in healthy human volunteers. 相似文献
2.
3.
Pradeep Mathur Bala Manimaran Md. Munkir Hossain Arnold L. Rheingold Louise M. Liable-Sands Glenn P.A. Yap 《Journal of organometallic chemistry》1997,540(1-2):165-168
The tris-methylene bridged compound (NO)4Fe2Se(μ-CH2)3 has been isolated. It has been characterised by IR and 1H, 13C, and 77Se NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods. The structure consists of a heavy atom triangle consisting of one Se and two Fe atoms. The Fe-Fe and the two Fe-Se edges are bridged by methylene groups. 相似文献
4.
The cyclic voltammetric behaviour of Eu3+/Eu2+ couple at hanging mercury drop electrode (HMDE) has been studied in chloride, bromide, iodide, thiocyanate and EDTA supporting
electrolytes. The apparent rate constant and transfer coefficient for these systems have been calculated at various voltage
scan rates, without using the data for standard or formal potential. The values have been compared with those obtained by
earlier workers through other electrochemical methods. 相似文献
5.
Kailash C. Malhotra Brij Bala Neeraj Sharma Subhash C. Chaudhry 《Transition Metal Chemistry》1995,20(4):388-390
Summary Complexes of composition [VOCl2(OC6H4Bu-t-4)] (1) and [VOCl(OC6H4Bu-t-4)2] (2) have been synthesized by the reaction of VOCl3 with equimolar and bimolar amounts, respectively, of 4-t-BuC6H4OSiMe3 in CCl4 and characterized by physio-chemical techniques. The complexes react with -hydroxyaldehydes and ketones such as 2-hydroxybenzaldehyde (salicylaldehyde, salH), and 2-hydroxy-2-phenylacetophenone (benzoin, benzH), 2-hydroxyacetophenone (hapH) and also with the potassium salt of p-chlorobenzohydroxamic acid (KBHACl) in 11 and 12 molar ratios, to yield five- and six-coordinate complexes. 相似文献
6.
Paul-Henri Ducrot Albert Kollmann Adil E. Bala Amel Majira Lucien Kerhoas Robert Delorme Jacques Einhorn 《Tetrahedron letters》1998,39(52):7282-9658
Two new antifungal resveratrol dimers, cyphostemmins A-B (1–2), have isolated from the roots of Cyphostemma crotalarioides planch (Vitaceae) together with resveratrol 3 and previously known reseveratrol dimers (4–7). Structures of these new compounds have been established on the basis of their MS and 1H and 13C NMR spectroscopic data. 相似文献
7.
8.
9.
10.