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1.
Grindstone Chemistry--a greatly evolved version of Toda’s method of grinding solids together for solvent-free chemical reactions--has been described and its usefulness illustrated by the successful application of this technique to a simplified process for conducting the multi-component Biginelli reaction for the synthesis of physiologically active tetrahydropyrimidinones. 相似文献
2.
Ajay K. Bose Maghar S. Manhas Suhas Pednekar Subhendu N. Ganguly Hoang Dang William He Arun Mandadi 《Tetrahedron letters》2005,46(11):1901-1903
An important stage in process development is kilo scale preparation of the target compound. For this reason, a procedure involving water-based biphasic reaction media has been developed for conducting some exothermic reactions on a large scale. This protocol is illustrated by the energy-efficient and rapid preparation of dihydropyrimidinones by a solvent-free, green chemistry procedure applied to the Biginelli reaction using p-toluenesulfonic acid as catalyst. 相似文献
3.
Joseph P. Kennedy Tung-Ping Liao Suhas Guhaniyogi Victor S. C. Chang 《Journal of polymer science. Part A, Polymer chemistry》1982,20(11):3219-3227
β-Pinene was polymerized with H2O/BCl3 (protic) and p-dicumyl chloride and sym-tricumyl chloride (nonprotic) inifer systems in CH2Cl2 or CH2Cl2/n-C6H14 solvents from ?10 to ?70°C. The effect of solvent polarity, temperature, and monomer and inifer concentration on conversions and molecular weights was investigated. Low conversions and molecular weights, M?n = 1300–2500, obtained under these conditions suggest rapid termination. 相似文献
4.
Manoj K. Kolel‐Veetil Kenan P. Fears Syed B. Qadri Christopher A. Klug Teddy M. Keller 《Journal of polymer science. Part A, Polymer chemistry》2012,50(15):3158-3170
A semicrystalline inorganic–organic hybrid crosslinked network containing polyhedral oligomeric silsesquioxane (POSS) cores was constructed by the unusual hydrosilylation of the terminal vinyl groups of an internal acetylene‐containing silane linker by a POSS monomer. Products from the thermal treatments of this network in either argon or air at 250, 550, and 1000 °C, respectively, were characterized by Fourier transform infrared, Solid‐state 13C and 29Si magic angle spinning NMR, X‐ray diffraction and XPS analyses. The highly symmetrically functionalized POSS silica clusters, in the fluorite silica phase, in the network were found to remain unchanged on thermal treatment possibly due to the shielding of the silica core by the functionalities and a cancellation of thermal stresses on the silica core. Stabilization of the metastable α‐cristobalite phase, which is typically formed on cooling by a β‐ to α‐transition of the β‐cristobalite phase formed above 1400 °C, was observed in the amorphous regions in the network sample treated only to 1000 °C in air. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
5.
Manoj K. Kolel‐Veetil Dawn D. Dominguez Christopher A. Klug Kenan P. Fears Syed B. Qadri Daniel Fragiadakis Teddy M. Keller 《Journal of polymer science. Part A, Polymer chemistry》2013,51(12):2638-2650
Structural isomers of thermo‐oxidatively stable poly(carborane‐siloxane‐arylacetylene) (PCSAA), namely, m‐PCSAA and p‐PCSAA, were synthesized by the reaction of the dimagnesium salts of m‐diethynylbenzene or p‐diethynylbenzene with 1,7‐bis(chlorotetramethyldisiloxyl)‐m‐carborane. The developed polymers have exceptional thermo‐oxidative properties similar to their diacetylene counterpart poly(carborane‐siloxane‐acetylene), PCSA. Thermal treatment of either of the PCSAAs results in a fully crosslinked thermoset by 500 °C resulting from the cycloaddition reactions involving the acetylene and aryl functionalities and subsequent formation of bridging disilylmethylene entities as discerned from Fourier transform infrared, 13C and 29Si solid‐state NMR, and XPS studies. X‐ray diffraction analysis revealed that the thermosets obtained from p‐PCSAA possess enhanced crystallinity when compared to that obtained from m‐PCSAA possibly due to more efficient packing interactions of the p‐diethynylbenzene groups during thermoset formation. The presence of the aryl groups in the backbone of the PCSAAs' chains appeared to have enhanced the storage and bulk moduli of their thermosets when compared to the thermoset of PCSA. Dielectric studies of m‐PCSAA and p‐PCSAA revealed segmental relaxation peaks, α, above their glass transition temperatures with p‐PCSAA exhibiting a broader peak with a slower relaxation rate than m‐PCSAA. © 2013 Wiley Periodicals, Inc.? J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2638–2650 相似文献
6.
Vartika Srivastava Manukonda Suresh Kumar Puthiya Veetil Nidheesh Carlos A. Martínez-Huitle 《Current Opinion in Electrochemistry》2021
Use of robust and safe water disinfection technologies which are inexpensive and energy-efficient are need of the hour to combat the problem of inadequate access of safe and clean drinking water. Energy and chemically intensive water treatment technologies warrant the need for a safe and environmentally sound treatment technology. Electrochemical disinfection or electrodisinfection (ED) is experiencing a great resurgence among the scientific communities owing to its novel use of electrode materials and electric current in an inexpensive and energy-efficient way for achieving the inactivation of microorganisms. Among the various electrodes used in the ED, boron-doped diamonds emerge as a sustainable alternate for their ability to electro generate strong potent oxidants which result in effective pathogen control in drinking water. ED for disinfecting waters occurs via generation of the reactive species which act in the bacterial inactivation mechanisms. In this mini-review, a critical discussion on the fundamentals and applications of promising electrochemical methods using boron-doped diamond anodes (namely electrochemical oxidation), evidencing their advantages for the remediation of drinking water infected with waterborne agents, is given. 相似文献
7.
Deshpande Deepti Gadmale Dinesh Bakre Suhas Srivastava Ashwini Kumar 《平面色谱法杂志一现代薄层色谱法》2016,29(6):429-434
JPC – Journal of Planar Chromatography – Modern TLC - In an attempt to determine chlorpyrifos insecticide and its metabolite 3,5,6-trichloropyridinol in visceral samples, a rapid... 相似文献
8.
We consider the nonanalytic temperature dependences of the specific heat coefficient, C(T)/T, and spin susceptibility, chi(s)(T), of 2D interacting fermions beyond the weak-coupling limit. We demonstrate within the Luttinger-Ward formalism that the leading temperature dependences of C(T)/T and chi(s)(T) are linear in T, and are described by the Fermi liquid theory. We show that these temperature dependences are universally determined by the states near the Fermi level and, for a generic interaction, are expressed via the spin and charge components of the exact backscattering amplitude of quasiparticles. We compare our theory to recent experiments on monolayers of He3. 相似文献
9.
Babasaheb P. Bandgar Suhas P. Kasture 《Monatshefte für Chemie / Chemical Monthly》2001,132(9):1101-1104
Summary. Trimethylsilylation of alcohols and phenols is carried out using hexamethyldisilazane and LiClO4 under microwave irradiation and neutral conditions. The deprotection of silyl ethers is carried out similarly using natural
kaolinitic clay and a few drops of water.
Received March 1, 2001. Accepted (revised) April 17, 2001 相似文献
10.
We show that one-dimensional electron systems in the proximity of a superconductor that support Majorana edge states are extremely susceptible to electron-electron interactions. Strong interactions generically destroy the induced superconducting gap that stabilizes the Majorana edge states. For weak interactions, the renormalization of the gap is nonuniversal and allows for a regime in which the Majorana edge states persist. We present strategies of how this regime can be reached. 相似文献