Graphene Saturable Absorber Mirror for Mode-Locked Orange Pulse Laser

Journal of Russian Laser Research - We demonstrate a passively-mode-locked Pr3+: LuLiF4 laser operated at the 604 nm orange wave-length, using monolayer graphene as a saturable absorber. The...     

Flotation-spectrophotometric determination of trace of germanium with isochromatic dye ion-pairs formed by rhodamine 6G and tetrabromofluorescein

A flotation spectrophotometric method for the determination of germanium with isochromatic dye ion-pairs is described. The molar ratio of germanium to rhodamine 6G to tetrabromofluorescein is 1:5:5. The apparent molar absorptivity is 5.8 x 10(5) l mol(-1) cm(-1) at 531 nm. Beer's law is obeyed over the concentration range of 5.0 x 10(-8)-1.25 x 10(-6) mol l(-1). The proposed method is sensitive and accuracy and can be applied satisfactorily to the determination of germanium in vegetables.     

A Triply Negatively Charged Nanographene Bilayer with Spin Frustration

We report on the largest open-shell graphenic bilayer and also the first example of triply negatively charged radical π-dimer. Upon three-electron reduction, bilayer nanographene fragment molecule (C₉₆H₂₄Ar₆)₂ (Ar=2,6-dimethylphenyl) ( 1 ₂) was transformed to a triply negatively charged species 1 ₂^3.−, which has been characterized by single-crystal X-ray diffraction, electron paramagnetic resonance (EPR) spectroscopy and magnetic properties on a superconducting quantum interference device (SQUID). 1 ₂^3.− features a 96-center-3-electron (96c/3e) pancake bond with a doublet ground state, which can be thermally excited to a quartet state. It consists of 34 π-fused rings with 96 conjugated sp² carbon atoms. Spin frustration is observed with the frustration parameter f>31.8 at low temperatures in 1 ₂^3.−, which indicates graphene upon reduction doping may behave as a quantum spin liquid.     

Interaction between longitudinal vortices and flat plate boundary layer

The interaction between longitudinal vortices and flat plate boundary layer has been studied numerically for both laminar and turbulent flow situations. The vortices are assumed to be placed in an otherwise two-dimensional boundary layer flow. The flow is assumed to be incompressible and steady. Considering the fact that the velocity, vorticity and temperature gradients in the transverse directions are much larger than the longitudinal (streamwise) gradients for these flows, the original Navier Stokes equations are parabolized in the streamwise direction. A simple model, based on Boussinesq hypothesis, is used for turbulent flow. The discretized equations are then solved step by step in the streamwise direction, using an iterative procedure at each station. Numerical solutions have been obtained for different parameters, such as the Reynolds number, the circulation and the initial position of the vortices. The computed flow patterns and the skin friction coefficient and Stanton number are found to be qualitatively consistent with available experimental results. It is shown that the interaction between the vortices and the boundary layer may severely disturb the boundary layer flow field and thus considerably increase the local skin friction and heat transfer rate on surface of an aircraft.     

A stable triplet diradical emitter

Molecules with luminescence have been extensively investigated, but the luminescence of a stable molecule with a triplet ground state has not been observed. Synthesis of boron-containing radicals has attracted lots of interest because of their unique electronic structures and potential applications in organic semiconductors. Though some boron-based diradicals have been reported, neutral boron-containing diradicals with triplet ground states are rare. Herein two borocyclic diradicals with different substituents (3 and 4) have been isolated. Their electronic structures were investigated by EPR and UV spectroscopy, and SQUID magnetometry, in conjunction with DFT calculations. Both experiment and calculation suggest that 3 is an open shell singlet diradical while 4 is a triplet ground state diradical with a large singlet–triplet gap (0.25 kcal mol⁻¹). Both diradicals show multi fluorescence peaks (3: 414, 431, and 470 nm; 4: 420, 433, and 495 nm). 3 displays multiple redox steps and is a potential material towards the design of high-density memory devices. 4 represents the first example of a neutral triplet boron-containing diradical with a strong ferromagnetic interaction, and also is the first stable triplet diradical emitter.

Stable borocyclic diradical emitters with a tunable ground state.     

壁面传质扰动有纵向速度的流动问题

研究壁面有周期性定向抽吸－引射且在壁面上形成纵向速度的二维渠道流动,壁面上的纵向平均速度为〈uω〉．数值结果表明,抽吸－引射的传质倾角θ对流场的性质和壁面上的切应力等有重要的影响．与速度为〈uω〉的运动壁无扰动流动相比,它的阻力偏低,这种阻力偏低与流场的扰动特性有关,即与扰动速度分量的二重相关积分I成正比．阻力在θ＞-24°的范围内有减阻效果;能量在θ＞8°时有净能量减小的效果．     

Validity of thermodynamic laws and weak cosmic censorship for AdS black holes and black holes in a cavity

By throwing a test charged particle into a Reissner-Nordstrom (RN) black hole, we test the validity of the first and second laws of thermodynamics and the weak cosmic censorship conjecture (WCCC) with two types of boundary conditions: the asymptotically anti-de Sitter (AdS) space and a Dirichlet cavity wall placed in an asymptotically flat space. For the RN-AdS black hole, the second law of thermodynamics is satisfied, and the WCCC is violated for both extremal and near-extremal black holes. For the RN black hole in a cavity, the entropy can either increase or decrease depending on the change in the charge, and the WCCC is satisfied/violated for the extremal/near-extremal black hole. Our results indicate that there may be a connection between the black hole thermodynamics and the boundary condition imposed on the black hole.     

SPE then RP-LC for Simultaneous Analysis of Cyromazine and its Metabolite Melamine in Liquid Milk and Egg

Solid-phase extraction (SPE) and reversed-phase liquid chromatography (RP-LC) have been used for simple, sensitive simultaneous analysis of cyromazine and melamine residues in liquid milk and eggs. The conditions used for SPE and LC were investigated and optimized. A combined cation-exchange–reversed-phase cartridge was used for clean-up, and an ODS (C₁₈) column (150 mm × 4.6 mm i.d., 5-μm particles) with 62:38 (v/v) 5 mm sodium lauryl sulfate (pH 3.4)–acetonitrile as mobile phase was used for RP-LC. Under the optimum conditions the method limit of detection (LOD) for both cyromazine and melamine was 6.2 μg kg⁻¹ for liquid milk samples, and 11.5 μg kg⁻¹ for egg samples. Average recovery of cyromazine and melamine from milk samples was 90.3%, RSD 4.6–5.6%, and 99.6%, RSD 3.2–4.7%, respectively. Average recovery of cyromazine and melamine from egg samples was 85.3%, RSD 1.0–4.7%, and 89.6%, RSD 3.1–5.0%, respectively. The method enables detection of melamine and cyromazine at levels as low as 20.7 μg kg⁻¹ in liquid milk and 38.3 μg kg⁻¹ in egg.

     

Tricoordinate Nontrigonal Pnictogen‐Centered Radical Anions: Isolation,Characterization, and Reactivity

The search for main‐group element‐based radicals is one of the main research topics in contemporary chemistry because of their fascinating chemical and physical properties. The Group 15 element‐centered radicals mainly feature a V‐shaped two coordinate structure, with a couple of radical cations featuring trigonal tricoordinated geometry. Now, nontrigonal compounds R₃E (E=P, As, Sb) were successfully synthesized by introducing a new rigid tris‐amide ligand. The selective one‐electron reduction of R₃E afforded the first stable tricoordinate pnictogen‐centered radical anion salts; the pnictogen atoms retain planar T‐shaped structures. EPR spectroscopy and calculations reveal that the spin density mainly resides at the p orbitals of the pnictogen atoms, which is perpendicular to the N₃E planes.     

胶束溶液增溶过程的高分辩NMR研究

本文用高分辨~1H-NMR谱, 研究了十二烷基硫酸钠(SDS)胶束水溶液对m-二甲苯和苯甲醇的增溶作用。结果表明, 增溶物浓度很低时, m-二甲苯和苯甲醇均吸附在胶束-水“界面”。随着浓度增加m-二甲苯增溶在胶束的“栅栏”层和内核中, 并沿SDS的烃链均匀分布。当浓度约为0.34摩尔分数时, 它沿烃链的增溶达到“饱和”, 开始进入胶束内核中心。苯甲醇主要增溶在“栅栏”层中, 其羟基靠近胶束-水“界面”, 苯基深入到与α-CH_2基相邻的五个亚甲基的位置。