全文获取类型
收费全文 | 281篇 |
免费 | 27篇 |
国内免费 | 4篇 |
专业分类
化学 | 227篇 |
力学 | 7篇 |
数学 | 23篇 |
物理学 | 55篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 13篇 |
2019年 | 5篇 |
2018年 | 24篇 |
2017年 | 18篇 |
2016年 | 20篇 |
2015年 | 16篇 |
2014年 | 15篇 |
2013年 | 22篇 |
2012年 | 25篇 |
2011年 | 34篇 |
2010年 | 26篇 |
2009年 | 10篇 |
2008年 | 15篇 |
2007年 | 14篇 |
2006年 | 11篇 |
2005年 | 11篇 |
2004年 | 7篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1993年 | 1篇 |
1982年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有312条查询结果,搜索用时 15 毫秒
1.
Valiollah Mirkhani Shahram TangestaninejadBahram Yadollahi Ladan Alipanah 《Tetrahedron》2003,59(41):8213-8218
Epoxides can be cleaved in a regio- and stereoselective manner under neutral conditions with alcohols and acetic acid in the presence of catalytic amounts of decatungstocerate(IV) ion, ([CeW10O36]8−), affording the corresponding β-alkoxy and β-acetoxy alcohols in high yields. In water, ring opening of epoxides occurs with this catalyst to produce the corresponding diols in good yields. 相似文献
2.
Molecular Diversity - In this research, QSAR modeling was carried out through SMILES of compounds and on the basis of the Monte Carlo method to predict the antioxidant activity of 79 derivatives of... 相似文献
3.
4.
Soltanolkottabi Fariba Talaie M R Aghamiri Seyedfoad Tangestaninejad Shahram 《Journal of the Iranian Chemical Society》2020,17(1):17-24
Journal of the Iranian Chemical Society - The primary objective of the present work was to investigate the effect of fluid movement on synthesized chromium-benzenedicarboxylate, MIL-101(Cr),... 相似文献
5.
Niloufar Afzali Reihaneh Kardanpour Farnaz Zadehahmadi Shahram Tangestaninejad Majid Moghadam Valiollah Mirkhani Adam Mechler Iraj Mohammadpoor‐Baltork Mehrnaz Bahadori 《应用有机金属化学》2019,33(11)
A novel heterogeneous nanocatalyst was established by supporting molybdenum (VI) on Zr6 nodes in the structure of the well‐known UiO‐66 metal–organic framework (MOF). The structure of the UiO‐66 before and after Mo (VI) immobilization was confirmed with XRD, DR‐FTIR and UV–vis spectroscopy, and the presence and amount of Mo (VI) was identified by X‐ray photoelectron spectroscopy and inductively coupled plasma atomic emission spectroscopy. TEM imaging confirmed the absence of Mo clusters on the MOF surface, while SEM confirmed that the appearance of the MOF has not changed upon immobilizing the Mo (VI) catalyst. BET adsorption measurements were used to confirm the porosity of the catalyst. The catalytic activity of this heterogeneous catalyst was investigated in oxidation of sulfides with H2O2 in acetonitrile and oxidative desulfurization of dibenzothiophene. Easy work up, convenient and steady reuse and high activity and selectivity are prominent properties of this new hybrid material. 相似文献
6.
Mehdi Shafiee Ahmad R. Khosropour Iraj Mohammadpoor-Baltork Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani 《Tetrahedron letters》2012,53(24):3086-3090
A novel, diastereoselective, one-pot synthesis of new bis-Betti bases via condensation of dihydroxynaphthalene, two equivalents of aryl aldehydes, and two equivalents of 3-amino-5-methylisoxazole is reported. Conversion into the adducts was almost quantitative without the use of solvent or catalyst. The reaction conditions are very simple and enable easy isolation of the product. 相似文献
7.
Morteza Moradi Shahram Seidi Mahnaz Ghambarian Ali Esrafili 《International journal of environmental analytical chemistry》2013,93(2):199-212
An ultrasound-assisted emulsification microextraction (USAEME) based on low-density solvents was successfully applied for the extraction and pre-concentration of four toxic nitrophenols in water samples. The extracted analytes were analyzed by high-performance liquid chromatography-UV detection. The important parameters influencing the extraction efficiency were studied and optimized utilizing two different optimization methods: one variable at a time (OVAT) and central composite design (CCD). The results showed that the emulsification process can be completed in a few seconds using low-density solvents, but almost 10–20?min is necessary for high-density solvents. Under the optimum conditions (extraction solvent, 1-octanol; extraction solvent volume, 40?µL; sample pH, 3.0; salt concentration, 20% (w/v) NaCl; extraction temperature, 40 (±3)°C), limits of detection of the method were in the range of 0.25 to 1?µg?L?1 and the repeatability and reproducibility of the proposed method, expressed as relative deviation, varied in the range of 2.2–4.2% and 4.7–6.9%, respectively. Linearity was found to be in the range of 1 to 200?µg?L?1 and the preconcentration factors (PFs) were between 77 and 175. The relative recoveries of the four nitrophenols from water samples at spiking level of 10.0?µg?L?1 were in the range of 92.0 to 115.0%. 相似文献
8.
Structural Chemistry - The measured densities and viscosities of the binary mixtures of the isobutanol and 2-methylcyclohexanol were reported experimentally in a certain range of concentrations at... 相似文献
9.
Reihaneh Hajiaghabozorgy Ali Reza Zarei Shahram Ghanbari Pakdehi 《Journal of Analytical Chemistry》2014,69(8):805-811
A simple and highly sensitive method developed for preconcentration and spectrophotometric determination of ultra trace amounts of azide ion (N 3 ? ) in water and biological samples using dispersive liquid-liquid microextraction (DLLME) technique. The method is based on ion association formation of azide ion with malachite green and extraction of the ion pairing product using DLLME technique. Some important parameters, such as reaction conditions and the kind and volume of extraction solvent and disperser solvent were studied and optimized. The calibration curve was linear in the range of 0.5–50 μg/L of azide ion. Also, the enrichment factor and extraction recovery obtained were 24.7 and 98.7%, respectively. The method was applied to the determination of azide ion in water and biological samples. 相似文献
10.
The synthesis and characterization of two new aluminate(Ⅲ) complexes with general formula K[AlCl3X] are reported. These compounds derived from aluminate trichloride and related salts. Potassium trichlorothiocyanoaluminate, PCTA, and potassium trichlorocyanatoalu-minate, PCCA, are two new ionic aluminate complexes. They can be easily synthesized in a nearly quantitative yield by using the direct reaction of AlCl3 and KX. The complexes were characterized by physico-chemical and spectroscopic methods. Theoretical calculations have been used for the extraction of structural and spectroscopic data of these new synthesized complexes. The antibacterial activities of such compounds were studied against the Staphylococcus aureus, Escherichia coli, Staphylococcus Epidermidis, Estreptococo B and Shigella. 相似文献