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1.
Tzanetos NP Dracopoulos V Kallitsis JK Deimede VA 《Langmuir : the ACS journal of surfaces and colloids》2005,21(20):9339-9345
A detailed study of the self-assembly ability of triblock coil-rod-coil copolymers containing a rigid di(styryl)-anthracene segment covalently linked to oxadiazole-based blocks and their binary blends with oxadiazole-based homopolymers is presented here. The self-organized microdomains seem to pack into a fascinating ordered hexagonal structure obtained at a critical concentration without any significant influence of the sample preparation method, based on evidence obtained by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and fluorescence microscopy studies. The compatibilization efficiency of these coil-rod-coil copolymers in polymer blends composed of an electron-accepting polyoxadiazole and a luminescent polyanthracene-based pair was studied by atomic force microscopy (AFM). The common feature of all observed morphologies is the compatibilizing function of the rod-coil molecule, which intercalates between the incompatible domains to prevent the formation of well-defined phase separated nanostructured surfaces. 相似文献
2.
Boudalis AK Lalioti N Spyroulias GA Raptopoulou CP Terzis A Bousseksou A Tangoulis V Tuchagues JP Perlepes SP 《Inorganic chemistry》2002,41(24):6474-6487
The preparations, X-ray structures, and detailed physical characterizations are presented for three new tetranuclear Fe(III)/RCO(2)(-)/phen complexes, where phen = 1,10-phenanthroline: [Fe(4)(OHO)(OH)(2)(O(2)CMe)(4)(phen)(4)](ClO(4))(3).4.4MeCN.H(2)O (1.4.4MeCN.H(2)O); [Fe(4)O(2)(O(2)CPh)(7)(phen)(2)](ClO(4)).2MeCN (2.2MeCN); [Fe(4)O(2)(O(2)CPh)(8)(phen)(2)].2H(2)O (3.2H(2)O). Complex 1.4.4MeCN.H(2)O crystallizes in space group P2(1)/n, with a = 18.162(9) A, b = 39.016(19) A, c = 13.054(7) A, beta = 104.29(2) degrees, Z = 4, and V = 8963.7 A(3). Complex 2.2MeCN crystallizes in space group P2(1)/n, with a = 18.532(2) A, b = 35.908(3) A, c = 11.591(1) A, beta = 96.42(1) degrees, Z = 4, and V = 7665(1) A(3). Complex 3.2H(2)O crystallizes in space group I2/a, with a = 18.79(1) A, b = 22.80(1) A, c = 20.74(1) A, beta = 113.21(2) degrees, Z = 4, and V = 8166(1) A(3). The cation of 1 contains the novel [Fe(4)(mu(4)-OHO)(mu-OH)(2)](7+) core. The core structure of 2 and 3 consists of a tetranuclear bis(mu(3)-O) cluster disposed in a "butterfly" arrangement. Magnetic susceptibility data were collected on 1-3 in the 2-300 K range. For the rectangular complex 1, fitting the data to the appropriate theoretical chi(M) vs T expression gave J(1) = -75.4 cm(-1), J(2) = -21.4 cm(-1), and g = 2.0(1), where J(1) and J(2) refer to the Fe(III)O(O(2)CMe)(2)Fe(III) and Fe(III)(OH)Fe(III) pairwise exchange interactions, respectively. The S = 0 ground state of 1 was confirmed by 2 K magnetization data. The data for 2 and 3 reveal a diamagnetic ground state with antiferromagnetic exchange interactions among the four high-spin Fe(III) ions. The exchange coupling constant J(bb) ("body-body" interaction) is indeterminate due to prevailing spin frustration, but the "wing-body" antiferromagnetic interaction (J(wb)) was evaluated to be -77.6 and -65.7 cm(-1) for 2 and 3, respectively, using the appropriate spin Hamiltonian approach. M?ssbauer spectra of 1-3 are consistent with high-spin Fe(III) ions. The data indicated asymmetry of the Fe(4) core of 1 at 80 K, which is not detected at room temperature due to thermal motion of the core. The spectra of 2 and 3 analyze as two quadrupole-split doublets which were assigned to the body and wing-tip pairs of metal ions. (1)H NMR spectra are reported for 1-3 with assignment of the main resonances. 相似文献
3.
George V. Rekatas Vassilis J. Demopoulos Panos N. Kourounakis 《Journal of heterocyclic chemistry》1996,33(3):989-990
In this work, the synthesis of 1-(pyridine-3-carbonyl)pyrrolidin-2-one ( 1a ) and 1-(2-propyl-1-pentanoyl)pyrrolidin-2-one ( 1b ) by cyclization of the corresponding GABA derivatives, is reported. Two different methods are developed. For the synthesis of 1a , the parent molecule 4-[(pyridine-3-carbonyl)-amino]butanoic acid ( 2a ) is treated first with thionyl chloride and then with triethylamine. The second derivative, 1b , is produced by an intramolecular dehydration of 4-(2-propylpentanoylamino)butanoic acid ( 2b ) using an acid catalyst. 相似文献
4.
5.
The synthetic investigation of the CuII/maleamate(−1) ion (HL−)/N,N′,N′′-chelate general reaction system has allowed access to compounds [Cu2(HL)2(bppy)2](ClO4)2·H2O (1·H2O), [Cu(HL)(bppy)(ClO4)] (2) and [Cu(HL)(terpy)(H2O)](ClO4) (4) (bppy = 2,6-bis(pyrazol-1-yl)pyridine, terpy = 2,2′;6′,2′′-terpyridine). In the absence of externally added hydroxides, compound [Cu2(L′)2(bppy)2](ClO4)2 (3) was obtained from MeOH solutions; L′− is the monomethyl maleate(−1) ligand which is formed in situ via the CuII-assisted HL− → L′− transformation. In the case of tptz-containing (tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine) reaction systems, the CuII-assisted hydrolysis of tptz to pyridine-2-carboxamide (L1) afforded complex [Cu(L1)2(NO3)2] (5). The crystal structures of 1–5 are stabilized by intermolecular hydrogen bonding and π–π stacking interactions. Characteristic IR bands of the complexes are discussed in terms of the known structures and the coordination modes of the ligands. 相似文献
6.
The dependence of ultrasound contrast agents backscatter on acoustic pressure: theory versus experiment 总被引:2,自引:0,他引:2
Experimental investigations have not fully explored the interaction between ultrasound beams and microbubble contrast agents. Moreover theoretical investigations have not solved the problem of the microbubble oscillation. A simple in-vitro system based on a commercial scanner (ATL UM9) was used to insonate (3 MHz transmission) diluted contrast suspensions of Definity and Quantison at different acoustic pressures (0.27-1.52 MPa). The experimental data were referred to a blood mimicking fluid in order to extract an estimate of their scattering cross-section. The results were compared with the solutions of the three main bubble oscillatidn models, Rayleigh-Plesset, Herring and Gilmore. Non-linear solutions of the above models were produced numerically using the Mathematica Package Software. The experiments showed that both agents provided a linear increase in scattering cross-section with increasing acoustic pressure. The thick shelled Quantison provided an increasing number of scatterers with increasing acoustic pressure, which proved that free bubbles leaked out of the shell. At high acoustic pressures both Quantison and Definity scattering cross-sections were almost identical, and were probably that of a free bubble. The Rayleigh-Plesset model provided a scattering cross-section almost independent of acoustic pressure. On the contrary the scattering cross-sections calculated by the Herring and Gilmore models solutions displayed a definite dependence on acoustic pressure of an order higher than one, which is slightly higher than the order of dependence exhibited by the experimental data. However, the increase of the experimentally measured scattering cross-section with acoustic pressure was sharper than the calculated one by the above two models. This is most probably due to the fact that the models simulated damped and not free bubble oscillations. In conclusion the Rayleigh-Plesset model was inadequate in describing the bubble oscillations even at small diagnostic acoustic pressures. The Herring and Gilmore models could simulate the dependence of the scattering cross-section of encapsulated microbubbles on acoustic pressure. However the contribution of free bubble oscillations has still to be modelled. 相似文献
7.
Vassilis Kanellopoulos 《Proceedings of the American Mathematical Society》2004,132(11):3231-3242
W. T. Gowers' theorem asserts that for every Lipschitz function and 0$">, there exists an infinite-dimensional subspace of such that the oscillation of on is at most . The proof of this theorem has been reduced by W. T. Gowers to the proof of a new Ramsey type theorem. Our aim is to present a proof of the last result.
8.
Vassilis S. Kouikoglou 《Annals of Operations Research》2000,93(1-4):245-264
The analysis of finitebuffered, unreliable production lines is often based on the method of decomposition, where the original system is decomposed into a series of twostage subsystems that can be modeled as quasi birthdeath processes. In this paper, we present methods for computing the gradients of the equilibrium distribution vector for such processes. Then we consider a specific production line with finite buffers and machine breakdowns and develop an algorithm that incorporates gradient estimation into the framework of Gershwin's approximate decomposition. The algorithm is applied to the problem of workforce allocation to the machines of a production line to maximize throughput. It is shown that this problem is equivalent to a convex mathematical programming problem and, therefore, a globally optimal solution can be obtained. 相似文献
9.
Georgopoulou AN Adam R Raptopoulou CP Psycharis V Ballesteros R Abarca B Boudalis AK 《Dalton transactions (Cambridge, England : 2003)》2010,39(20):5020-5027
Complexes [M(II)Gd(III){pyCO(OEt)pyC(OH)(OEt)py}?](ClO?)?·EtOH [M(II) = Cu(II) (1), Mn(II) (2), Ni(II) (3), Co(II) (4) and Zn(II) (5)] crystallize in the monoclinic Cc space group and contain one hexacoordinate M(II) ion and one enneacoordinate Gd(III) ion, bridged by three {pyCO(OEt)pyC(OH)(OEt)py}? ligands. Magnetic susceptibility measurements indicate a ferromagnetic interaction for 1 and antiferromagnetic interactions for 2-4. Using the ? = -J?(Gd(III))?(M(II)) spin Hamiltonian formalism, fits to the magnetic susceptibility data yielded J values of +0.32 cm?1 for 1, -1.7 cm?1 for 2, and -0.22 cm?1 for 3. In complex 4, the orbital contributions of Co(II) precluded the determination of the magnetic coupling. The complex follows the Curie-Weiss law with θ = -2.07 K (-1.44 cm?1). 相似文献
10.
A tree T is said to be homogeneous if it is uniquely rooted and there exists an integer b ≥ 2, called the branching number of T, such that every t ∈ T has exactly b immediate successors. A vector homogeneous tree T is a finite sequence (T 1,...,T d ) of homogeneous trees and its level product ?T is the subset of the Cartesian product T 1×...×T d consisting of all finite sequences (t 1,...,t d ) of nodes having common length. We study the behavior of measurable events in probability spaces indexed by the level product ?T of a vector homogeneous tree T. We show that, by refining the index set to the level product ?S of a vector strong subtree S of T, such families of events become highly correlated. An analogue of Lebesgue’s density Theorem is also established which can be considered as the “probabilistic” version of the density Halpern-Läuchli Theorem. 相似文献