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1.
We examine the optical near-field interaction between different types of scanning tips and single oriented fluorescent molecules.
We demonstrate the influence of a tip on the excitation intensity as well as on the integrated fluorescence signal, the excited
state lifetime, and the angular emission of single molecules. By using a standard model describing the radiation of an oscillating
dipole close to a nanosphere or a flat interface, we interpret our observations and describe some central criteria for obtaining
fluorescence enhancement or quenching.
PACS 33.80.-b; 07.79.Fc; 78.90.+t 相似文献
2.
Vahid Karimipour 《Letters in Mathematical Physics》1994,30(2):87-98
Quantum de Rham complexes on the quantum plane and the quantum group itself are constructed for the nonstandard deformation of Fun(SL(2)). It is shown that in contrast to the standardq-deformation of SL(2), the above complexes are unique for SL
h
(2). Also, as a byproduct, a new deformation of the two-dimensional Heisenberg algebra is obtained which can be used to construct models ofh-deformed quantum mechanics. 相似文献
3.
4.
Michael P. Doyle Robert L. Dow Vahid Bagheri William J. Patrie 《Tetrahedron letters》1980,21(29):2794-2798
Oxidations of 2,2-disubstituted-1,4-butanediols by the combination of nickel(II) bromide and benzoyl peroxide and by trityl tetrafluoroborate produce β,β-disubstituted-γ-butyrolactones with exceptional selectivity. 相似文献
5.
The reaction of an ethanolic solution 2,6‐pyridinedicarboxylic acid ( 1 , LH2) with TlNO3 in the presence of triethylamine led to the coordination polymer [Tl(LH)]n ( 2 ). The complex was characterized by elemental analysis, IR spectroscopy and single‐crystal X‐ray diffraction. Crystal data for 2 at –80 °C: monoclinic, space group I2/a, a = 696.1(1), b = 1190.6(2), c = 931.0(2) pm, β = 103.28(1)°, Z = 4, R1 = 0.0256. 相似文献
6.
The reaction of 2,6‐pyridinedicarboxylic acid ( 1 , LH2) with CeCl3·7H2O and Sm(NO3)3·6H2O in the presence of triethylamine led to the coordination polymer complexes [M(L)(LH)(H2O)2]·4H2O [M = Ce ( 2 ) and Sm ( 3 )]. Both complexes were characterized by elemental analyses, IR spectroscopy and the crystal structures of 2 and 3 . Crystal data for 2 at ?80 °C: monoclinic, space group P21/c, a = 1404.6(1), b = 1122.1(1), c = 1296.1(1) pm, β = 102.09(1)°, Z = 4, R1 = 0.0217 and for 3 at ?80 °C: monoclinic, space group P21/c, a = 1395.1(1), b = 1120.1(1), c = 1282.8(1) pm, β = 102.71(1)°, Z = 4, R1 = 0.019. 相似文献
7.
8.
Marie-Pierre Girard Vahid Karimzadegan Marianne Hneault Francis Cloutier Gervais Brub Lionel Berthoux Natacha Mrindol Isabel Desgagn-Penix 《Molecules (Basel, Switzerland)》2022,27(17)
Amaryllidaceae alkaloids (AAs) are a structurally diverse family of alkaloids recognized for their many therapeutic properties, such as antiviral, anti-cholinesterase, and anticancer properties. Norbelladine and its derivatives, whose biological properties are poorly studied, are key intermediates required for the biosynthesis of all ~650 reported AAs. To gain insight into their therapeutic potential, we synthesized a series of O-methylated norbelladine-type alkaloids and evaluated their cytotoxic effects on two types of cancer cell lines, their antiviral effects against the dengue virus (DENV) and the human immunodeficiency virus 1 (HIV-1), and their anti-Alzheimer’s disease (anti-cholinesterase and -prolyl oligopeptidase) properties. In monocytic leukemia cells, norcraugsodine was highly cytotoxic (CC50 = 27.0 μM), while norbelladine was the most cytotoxic to hepatocarcinoma cells (CC50 = 72.6 μM). HIV-1 infection was impaired only at cytotoxic concentrations of the compounds. The 3,4-dihydroxybenzaldehyde (selectivity index (SI) = 7.2), 3′,4′-O-dimethylnorbelladine (SI = 4.8), 4′-O-methylnorbelladine (SI > 4.9), 3′-O-methylnorbelladine (SI > 4.5), and norcraugsodine (SI = 3.2) reduced the number of DENV-infected cells with EC50 values ranging from 24.1 to 44.9 μM. The O-methylation of norcraugsodine abolished its anti-DENV potential. Norbelladine and its O-methylated forms also displayed butyrylcholinesterase-inhibition properties (IC50 values ranging from 26.1 to 91.6 μM). Altogether, the results provided hints of the structure–activity relationship of norbelladine-type alkaloids, which is important knowledge for the development of new inhibitors of DENV and butyrylcholinesterase. 相似文献
9.
10.
The linear 3D piezoelasticity theory in conjunction with the versatile transfer matrix approach and the wave equation for the internal acoustic domain are employed for active non-stationary vibroacoustic response control of an arbitrarily thick, tri-laminate, fluid-filled, simply supported, piezocomposite cylindrical tank, excited by arbitrary (non-axisymmetric) time-dependent on-surface mechanical loads. The smart structure is composed of a supporting core layer of functionally graded orthotropic material perfectly bonded to inner and outer spatially distributed radially polarized functionally graded piezoceramic sensor and uniform force actuator (FGPM) layers. Active vibration damping is implemented by transferring the accumulated voltage on the sensor layer to the piezoelectric actuator layer in context of proportional and derivative control laws. Durbin's numerical inverse Laplace transform scheme is utilized to calculate the time response histories of the relevant interface displacement/stress components, center-point acoustic pressure, and actuator voltage, for selected loading configurations (i.e., concentrated step, impulse, and moving external loads). Numerical simulations demonstrate the effectiveness of the adopted distributed sensing/actuation configuration together with the active damping control strategy in suppressing the vibroacoustic response of a three-layered (Ba2NaNb5O15/Al/PZT4) water-filled piezoelastic cylindrical tank. Limiting cases are considered and the validity of results is established by comparison with the available data as well as with the aid of a commercial finite element package. 相似文献