S-alkyl dithioformates as 1,3-dipolarophiles. Generation of C(2)-unsubstituted penems

S-Alkyl dithioformates, generated by a cycloreversion process, react as 1,3-dipolarophiles with beta-lactam-based azomethine ylids to provide, after (net) elimination of MeSH, C(2)-unsubstituted penems. The overall cycloreversion/cycloaddition sequence was accelerated by microwave irradiation. [reaction: see text]     

A study of methods for moving particles in RF processing plasmas

Methods for moving charged particles in RF processing plasmas are investigated. These methods include varying RF power, varying chamber pressure, attraction and repulsion by an electrostatic probe, and movement with magnetic fields. Varying RF power changes the depth of the potential wells where particles are trapped. The RF power affects shape and location of the traps and the bulk plasma potential. Increasing the chamber pressure moves the sheath edge closer to the wafer being processed. Since particle traps are found at the plasma sheath edge increasing the chamber pressure will move the particle traps (and any trapped particles) closer to the wafer being processed. The Langmuir probe can repel particles when under negative bias and attract them when positively biased. This probe can also distort the sheath edge when the tip resides within the sheath. Applying a magnetic field can change the characteristics of the particle traps and produce a force on the charged dust particles     

Simple Zeros of the Riemann Zeta-Function

Assuming the Riemann Hypothesis, Montgomery showed by meansof his pair correlation method that at least two-thirds of thezeros of Riemann's zeta-function are simple. Later he and Taylorimproved this to 67.25 percent and, more recently, Cheer andGoldston increased the percentage to 67.2753. Here we proveby a new method that if the Riemann and Generalized LindelöofHypotheses hold, then at least 70.3704 percent of the zerosare simple and at least 84.5679 percent are distinct. Our methoduses mean value estimates for various functions defined by Dirichletseries sampled at the zeros of the Riemann zeta-function. 1991Mathematics Subject Classification: 11M26.     

Quantum Zeno and anti-Zeno paradoxes

Continuous observation of a time independent projection operator is known to prevent change of state (the quantum Zeno paradox). We discuss the recent result that generic continuous measurement of time dependent projection operators will in fact ensure change of state: an anti-Zeno paradox.     

The effects of electrostatic, molecular drag and gravitationalforces on the behavior of particle clouds in an RF discharge

A Gaseous Electronics Conference (GEC) Reference Cell was used to investigate the behavior of graphite particles sputtered in an argon plasma. By configuring the reactor in a normal (wafer facing upward) and in an inverted (wafer facing downward) configuration, and by varying the direction and flow of the argon, the relative importance of gravity, molecular drag and electrostatic trapping could be observed. It was observed that particle clouds in specific locations adjacent to the wafer (referred to as particle traps) were identical in both configurations. Drag forces from the showerhead grounded electrode were sufficient to prevent particles from accumulating in the traps over the wafer. Drag forces from flow parallel to the wafer (⩾25 cm/s) easily emptied the traps. Gas flow from a ring source mounted above a downward facing driven electrode were observed to affect the manner in which particles were removed from the ring-shaped trap surrounding the cathode. In that case, particles were observed to flow down eight fluid streamlines toward the eight openings through which the gas flowed from the reaction chamber to the pump. Comparison of results for the normal and inverted configurations also permitted estimates of the number of electrons attached to each particle     

粉粒体两相流的电容层析成象测量

粉粒体系统中的固相浓度分布的在线测量是十分困难的问题．电容层析成象技术是一种近年来发展起来的非侵入式快速浓度场测量技术．它不干扰流场，不受流动中颗粒浓度、加速度、不透明等因素的制约．本文讨论其测量原理、应用、近期进展、存在的主要问题及其解决的对策．     

ac Conductivity of mixed spinel NiAl0.7Cr0.7Fe0.6O4

ac Conductivity measurements are carried out across the metal to insulator transition in NiAl_0.7Cr_0.7Fe_0.6O₄. The low frequency data is analyzed using Summerfield scaling theory for hopping conductivity. The exponent of the scaling behavior has significantly different values in the conducting and insulating regimes. The hopping frequency and the zero frequency conductivity are found to increase with temperature, slowly in the metallic regime and rapidly in the insulating regime.