全文获取类型
收费全文 | 94篇 |
免费 | 0篇 |
专业分类
化学 | 64篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 1篇 |
物理学 | 26篇 |
出版年
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2017年 | 4篇 |
2016年 | 4篇 |
2014年 | 1篇 |
2013年 | 1篇 |
2012年 | 7篇 |
2011年 | 4篇 |
2010年 | 3篇 |
2009年 | 6篇 |
2008年 | 5篇 |
2007年 | 4篇 |
2006年 | 9篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 6篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有94条查询结果,搜索用时 15 毫秒
1.
Yu. N. Zakharov S. I. Raevskaya V. Z. Borodin V. G. Kuznetsov I. P. Raevskiĭ 《Physics of the Solid State》2006,48(6):1077-1078
The magnitudes of the temperature hysteresis and diffuse dielectric anomaly corresponding to the transition from the antiferroelectric phase to the ferroelectric phase in PbZr1 ? x TixO3 (0.03 ≤ x ≤ 0.05) ceramics can be reversibly changed by varying the temperatures of heating and cooling in the course of thermocycling. The results obtained indicate that the antiferroelectric-ferroelectric transition in the PbZr1 ? x TixO3 ceramics materials is a smeared first-order phase transition. 相似文献
2.
A. I. Burkhanov P. V. Bondarenko S. I. Raevskaya A. V. Shil’nikov I. P. Raevskiĭ 《Physics of the Solid State》2006,48(6):1114-1116
The dielectric properties of a ceramic and a single crystal of the same composition 0.9NaNbO3-0.1Gd1/3NbO3 (NNG10) with different prehistories of the material are investigated in the low-and infralow-frequency ranges. It is revealed that the dielectric aging of the material based on the NaNbO3 antiferroelectric with a smeared phase transition differs in character from similar phenomena observed in relaxor ferroelectrics. 相似文献
3.
A. E. Raevskaya A. L. Stroyuk S. Ya. Kuchmii Yu. M. Azhnyuk V. M. Dzhagan M. Ya. Valakh 《Theoretical and Experimental Chemistry》2006,42(3):162-168
The optical characteristics of CdSe nanoparticles, produced in aqueous solutions and polymer films in the reaction of cadmium
chloride and sodium selenosulfate, were studied. The main parameters that make it possible to vary the forbidden band width
were identified. The absorption, photoluminescence, Raman, and nonstationary decolorization spectra of CdSe nanoparticles
of various sizes were analyzed. It was demonstrated that under the conditions of pulsed irradiation the CdSe nanoparticles
are capable of accumulating excess electrons and inducing redox transformations in components of the solution (oxygen, methylviologen,
and sulfite ions).
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 3, pp. 150–155, May–June, 2006. 相似文献
4.
L. N. Raevskaya N. I. Il’chenko Yu. I. Pyatnitskii N. V. Pavlenko 《Theoretical and Experimental Chemistry》1997,33(2):78-81
The catalytic transformation of methane into higher hydrocarbons was studied under unsteady conditions on oxides of various
metals (Pb, Fe, Nb, Ti, Cd, Mo, Mg, Zn, Zr, Bi, Mn), and also on Sr-, La-, Y-, and Mn-containing oxides of perovskite structure.
It is shown that the effectiveness of the catalysts not only depends on their chemical composition, but also is determined
to a considerable degree by the specific surface of the oxides.
L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of Ukraine, 252039 Kiev, Prosp. Nauki, 31, Ukraine.
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 33, No. 2, pp. 91–95, March–April, 1997. 相似文献
5.
A. I. Bostan Yu. I. Pyatnitskii L. N. Raevskaya V. G. Pryanikova S. A. Nedil’ko A. G. Dzyaz’ko E. G. Zen’kovich 《Theoretical and Experimental Chemistry》2005,41(1):32-36
The oxidative coupling of methane (OCM) in a periodic regime over the SrMnO3 and its derivatives has been investigated. It has been established that partial replacement of the strontium ion by alkali metal ions leads to an increase in both catalytic activity and in selectivity with respect to higher hydrocarbons. Comparison of the results obtained in the present work with those obtained earlier for catalysts based on SrCoO3 led to the conclusion that the Co-containing catalysts were preferable to the Mn-containing catalysts for carrying out oxidative coupling of methane in a periodic regime.__________Translated from Teoreticheskaya i Éksperimentalnaya Khimiya, Vol. 41, No. 1, pp. 30–34, January–February, 2005. 相似文献
6.
A. E. Raevskaya A. L. Stroyuk S. Ya. Kuchmii 《Theoretical and Experimental Chemistry》2005,41(3):181-186
We have shown that CdSe/CdS nanocomposites can be obtained in a photocatalytic reaction with participation of CdS nanoparticles from sodium selenosulfate. We have studied the kinetic characteristics of this process in detail and have shown that its most likely mechanism includes a step involving reaction between SeSO3/2− anions and electrons generated in the conduction band of the CdS nanoparticles during irradiation and stabilized in traps on the semiconductor surface.__________Translated from Teoreticheskaya i Eksperimental’naya Khimiya, Vol. 41, No. 3, pp. 171–175, May–June, 2005. 相似文献
7.
K. M. Gitis G. E. Neumoeva N. I. Raevskaya G. A. Arutyunyants G. V. Isagulyants 《Russian Chemical Bulletin》1992,41(4):728-734
The synthesis of C-alkylimidazoles from 1,2-diamines and carboxylic acids over bifunctional platinum—alumina catalysts has been studied. It has been shown that this method is effective for the synthesis of 2-alkyl and 2,4-dialkylimidazoles including imidazoles with long-chain alkyls. The effect of the reaction temperature, space velocity of the flow of the raw materials, and dilution by hydrogen on the yield of product has been examined for the example of the synthesis of 2-methylimidazole from ethylenediamine and acetic acid, and the stability of the catalyst in continuous reaction cycles with intermediate oxidative regeneration has been studied. The composition of the accompanying products has been established and a mechanism proposed for their formation.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 4, pp. 932–940, April, 1992. 相似文献
8.
9.
I. V. Kumpanenko A. V. Roshchin V. V. Usin E. G. Raevskaya A. V. Bloshenko N. A. Sakharova 《Russian Journal of Physical Chemistry B, Focus on Physics》2012,6(5):671-676
A system for automatic control of a three-step process of water purification is developed. The system includes the online monitoring of the concentrations of pollutants in water at points of the flow diagram corresponding to the primary, fine, and final treatment steps, and consists of a UV-fluorimeter for determining the concentrations of pollutants, solenoid valves for controlling the flow of water in the treatment installation and a computerized central control unit operating according to a preset algorithm of water treatment control. 相似文献
10.
M. P. Ivliev S. I. Raevskaya I. P. Raevskiĭ V. A. Shuvaeva I. V. Pirog 《Physics of the Solid State》2007,49(4):769-779
The Curie-Weiss temperatures T CW of NaNbO3 and AgNbO3 are determined for the first time by extrapolating the temperature dependence of the reciprocal permittivity from the cubic phase. It is established that the values of T CW of ANbO3 perovskites (A = Na, Ag, K) are practically equal, i.e., that the cubic phases of all the compounds are potentially unstable to an almost equal extent with respect to polarization. From an analysis of the EXAFS spectra of the NaNbO3 and KNbO3 cubic phases, it follows that the potential-energy surfaces of the Nb cation in both compounds are similar and exhibit eight minima shifted by 0.16 and 0.19 Å, respectively, from the oxygen-octahedron center along the [111]-type directions. Based on these facts, it is inferred that the ANbO3 instability with respect to the occurrence of polarization is due to the tendency of the Nb cations to be ordered over the eight minima and that the phase transitions induced by this instability are of the order-disorder type. A statistical model capable of describing the sequence of ferroelectric phase transitions occurring in KNbO3 and in (Ba, Sr)TiO3 is proposed and studied. 相似文献