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排序方式: 共有121条查询结果,搜索用时 15 毫秒
1.
Beverly MB Voorhees KJ Hadfield TL 《Rapid communications in mass spectrometry : RCM》1999,13(23):2320-2326
Spores from the Bacillus species, B. cereus, B. anthracis, B. thuringensis, B. lichenformis, B. globigi, and B. subtilis, were examined by direct probe mass spectrometry using electron ionization (EI) and positive and negative chemical ionization (CI). Molecular ions from free fatty acids and nucleic acids were observed in the 70eV spectra as were fragments from glycerides. Spectra obtained with isobutane positive chemical ionization (CI(+)) were dominated by ions associated with pyranose compounds such as N-acetylglucosamine (NAG). Unlike the positive ion spectra, the negative ion spectra of the spores were very simple and contained few peaks. The M(-.) ion from dipicolinic acid (DPA) was the base peak in the negative ion spectra of all spore species except those from B. lichenformis. The negative ion of DPA produced such a strong signal that 10(8) colony forming units (CFUs) of B. cereus spores could be detected directly in 0.5 g of ground rice. Principal component analysis (PCA) of the spectra revealed that only CI(+) spectra contained differences that could be used to identify the spectra by species. Differentiation of the CI(+) spectra by PCA was attributed to variances in the peaks associated with the bacterial polymer poly(3-hydroxybutyrate) (PHB) and NAG. Similar differences in PHB and NAG peaks were detected in the CI(+) spectra of a suite of vegetative Bacillus stains grown with various media. 相似文献
2.
Harry A. Frank Roya Farhoosh Mila L. Aldema Beverly DeCoster Ronald L. Christensen Ronald Gebhard Johan Lugtenburg 《Photochemistry and photobiology》1993,57(1):49-55
Four carotenoids, 3,4,7,8-tetrahydrospheroidene, 3,4,5,6-tetrahydrospheroidene, 3,4-dihydrospheroidene and spheroidene, have been incorporated into the B850 light-harvesting complex of the carotenoidless mutant, photosynthetic bacterium, Rhodobacter sphaeroides R-26.1. The extent of π-electron conjugation in these molecules increases from 7 to 10 carbon-carbon double bonds. Carotenoid-to-bacteriochlorophyll singlet state energy transfer efficiencies were measured using steady-state fluorescence excitation spectroscopy to be 54 ± 2%, 66 ± 4%, 71 ± 6% and 56 ± 3% for the carotenoid series. These results are discussed with respect to the position of the energy levels and the magnitude of spectral overlap between the S, (2′AJ state emission from the isolated carotenoids and the bacteriochlorophyll absorption of the native complex. These studies provide a systematic approach to exploring the effect of excited state energies, spectral overlap and excited state lifetimes on the efficiencies of carotenoid-to-bacteriochlorophyll singlet energy transfer in photosynthetic systems. 相似文献
3.
William A. Feld Lucia Serico Beverly G. Genez Linda L. Friar 《Journal of polymer science. Part A, Polymer chemistry》1983,21(3):883-890
The synthesis of two phenylated bifunctional monomers, dimethyl 4-(4-(p-aminophenoxy)phenyl)-3,5,6-triphenylphthalate and dimethyl 4-(4-(4-(p-aminophenoxy)phenoxy)phenyl)-3,5,6-triphenylphthlate, was accomplished. Polymerization in solution or by a bulk polymerization procedure yielded a series of low molecular weight phenylated polyimides. The polymers were soluble in chlorinated hydrocarbons and exhibited thermal stabilities comparable to other polyimide systems. 相似文献
4.
R. E. Beverly III 《Applied physics. B, Lasers and optics》1991,53(3):187-193
Discharge behavior of large-aperture (10–70 cm) CO2 lasers is computed using a coupled particle kinetics-equivalent circuit model. Pulsed power systems that produce a single excitation pulse are only able to satisfy the preionization, ignition, and impedance matching conditions for interelectrode gaps 40–50 cm. Double-pulse systems are required for larger gaps, not only to optimize electrical efficiency, but to avoid oscillatory behavior which can lead to arc formation during the second cycle. 相似文献
5.
6.
R. E. Beverly III 《Optical and Quantum Electronics》1982,14(6):501-513
Onset of the dissociative-attachment instability requires that the rate coefficient for electron detachment (k
d) from negative ions be below a critical value. The predominant negative and positive ions in a CO2N2He gas-discharge plasma are known to change with time. As secondary by-products form and the predominant negative-ion species changes from CO
3
–
to NO
2
–
, a decrease ink
d occurs destabilizing the discharge. Since NO
2
–
and NO
3
–
are largely unreactive with respect to associative detachment,k
d depends in a sensitive fashion on the concentration of certain minority negative ions (O–, O
2
–
) and neutrals (CO, O, N). The sufficient conditions for the dissociative-attachment instability are much less sensitive to changes in the electron-ion and ion-ion recombination rate coefficients resulting from the ion aging process. 相似文献
7.
Dipolar 1:1 Adducts from the Reaction of 3-Amino-2H-azirines with 1,3,4-Oxadiazol- and 1,3,4-Thiadiazol-2(3H)-ones 3-Amino-2H-azirines 1 react with 5-(trifluoromethyl)-1,3,4-oxadiazol-2(3H)-one ( 2 ) as well as with different 5-substituted 1,3,4-thiadiazol-2(3H)-ones ( 5a–e ) in 2-propanol at room temperature to give dipolar 1:1 adducts of type 3 and 6 , respectively, in reasonable-to-good yields (Schemes 3 and 6, Tab. 1 and 2). The structure of two of these dipolar adducts, 6a and 6e , which are formally donor-acceptor-stabilized azomethin imines, have been elucidated by X-ray crystallography (Figs. 1-4). In the reaction of 2 and sterically crowded 3-amino-2H-azirines 1c–e with a 2-propyl and 2-propenyl substituent, respectively, at C(2), a 4,5-dihydro-1,2,4-triazin-3(2H)-one of type 4 is formed as minor product (Scheme 3 and Table 1). Independent syntheses of these products proved the structure of 4 . Several reaction mechanisms for the formation of compounds 3 and 4 are discussed, the most likely ones are described in Scheme 4: reaction of 2 as an NH-acidic compound leads, via a bicyclic zwitterion of type A , to 3 as well as to 4 . In the latter reaction, a ring-expanded intermediate B is most probable. 相似文献
8.
Beverly Brooks Hinojosa 《Journal of solid state chemistry》2010,183(1):262-4974
To clarify the role of A2O′ and B2O6 networks on cation displacement observed in Bi2Ti2O′O6, we used density functional theory calculations to examine the effect of sulfur substitution on the O′ and O sites on lone pair formation and resulting atomic displacement observed in Bi2Ti2O′O6. Cation displacement in bismuth titanate is suppressed only when S is substituted on the O′ site. Analysis of the electronic structure shows that S substitution on the O′ site suppresses the formation of the asymmetric p-type lone pair by modifying the Bi-anion hybridization. Lone pair formation is favored in Bi2Ti2O′S6 and the atomic displacement is larger than that observed in Bi2Ti2O′O6. This enhanced displacement is due to weaker Bi-S versus Bi-O interactions leading to significantly stronger hybridization between the Bi and O′ states in Bi2Ti2O′S6. We also induced lone pair formation in a metallic bismuth pyrochlore oxide (Bi2Ru2O′O6) by modifying the Bi-O interactions through S substitution on the B2O6 network, indicating atomic displacement on the A2O′ network may be achieved by modifying the B2O6 network. 相似文献
9.
In this paper we extend the plane blow-up results of Grundy& McLaughlin (1997) to the three-dimensional Navier-Stokes equations.Using a solution structure originally due to Lin we first providenumerical evidence for the existence of blow-up solutions on- < x, z < , 0 y 1 with boundary conditions on y = 0and y = 1 involving derivatives of the velocity components.The formulation enables us to consider plane and radial flowas special cases. Various features of the computations are isolatedand are used to construct a formal asymptotic solution closeto blow-up. We show that the numerical and asymptotic analysesprovide a mutually consistent global picture which supportsthe conclusion that, for the family of problems we considerhere, blow-up in fact can take place in three dimensions butat an inverse linear rate rather than the faster inverse squareof the plane case. 相似文献
10.
Beverly K Berger 《Annals of Physics》1984,156(1):155-193
The Gowdy T3 Cosmology is an exact solution to the vacuum Einstein equations interpreted to be a single polarization of gravitational waves propagating in an anisotropic, spatially inhomogeneous background. The classical behavior is reviewed and related to standard cosmological parameters. Canonical quantization of the dynamical degrees of freedom is reviewed. An adiabatic vacuum state is constructed. Adiabatic regularization is used to obtain non-divergent stress-energy tensor vacuum expectation values. Casimir energy terms due to T3 imposed discrete modes are evaluated. The vacuum expectation values are analyzed in early and late time limits and evaluated numerically. The regularized expectation value is used as a source for the classical background spacetime in the spirit of semi-classical gravity. An entirely vacuum expectation value source term produces essentially the time reverse of the classical evolution. Classical stress-energy added to the source restores the classical behavior at late times only. The combined system collapses from infinite to small but non-zero volume and reexpands. The classical singularity is replaced by a symmetric bounce. 相似文献