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1.
Prashanth Jaikumar 《Pramana》2006,67(5):937-949
We investigate the impact of magnetic fields on the electron distribution of the electrosphere of quark stars. For moderately
strong magnetic fields of B ∼ 1013 G, quantization effects are generally weak due to the large number density of electrons at surface, but can nevertheless
affect the photon emission properties of quark stars. We outline the main observational characteristics of quark stars as
determined by their surface emission, and briefly discuss their formation in explosive events termed as quark-novae, which
may be connected to the r-process. 相似文献
2.
UV curable epoxy acrylates were reinforced with two different organically modified montmorillonites (MMTs) and an unmodified MMT. Conversion and rate of polymerization was monitored by real time infrared spectroscopy (RTIR) and photo-DSC. Microstructures were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and optical clarity. Optical clarity of the films containing clay was quite good as only a slight decrease was observed. Physical properties of the reinforced films were examined by differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), hardness and tensile testing. Enhancements in glass transition temperature (Tg), thermal stability and mechanical properties were observed. The films reinforced with the unmodified MMT exhibit the most significant enhancements in properties. 相似文献
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M. S. Raghu K. Basavaiah Sameer A. M. Abdulrahaman K. N. Prashanth K. B. Vinay 《Journal of Analytical Chemistry》2013,68(11):969-976
Two simple, selective and sensitive spectrophotometric methods are described for the determination of pheniramine maleate (PAM) in pure and dosage forms. The method is based on the reaction of PAM with hypochlorite in the presence of Kolthoff buffer (phosphate-borate) of pH 7.0 to form the chloro derivative of PAM, destruction of the excess hypochlorite by nitrite ion (the chloro derivative of drug is unaffected under the optimized conditions) followed by the oxidation of iodide with the chloro derivative of PAM to iodine (I 3 ? which is either measured directly at 355 (method A) or reacted with starch to form a blue chromogen measurable at 590 nm (method B). The optimum conditions that affect the reaction were ascertained, and under these conditions linear relationship was obtained in the concentration ranges of 2–50 and 1–25 μg/mL PAM in methods A and B, respectively. The calculated molar absorptivity values are 7.26 × 103 and 1.28 × 104 L/(mol cm) for method A and method B, respectively. Sandell’s sensitivity values, limits of detection (LOD) and quantification (LOQ) are calculated as per ICH guidelines. The proposed methods were applied successfully to the determination of PAM in tablets and injection with good accuracy and precision and without interferences from common additives. The results obtained by the proposed methods were compared favourably with those of the reference method. The accuracy and reliability of the proposed methods were further checked by recovery studies via standard addition procedure. 相似文献
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Let N ≥ 5 and \({{\mathcal{D}}^{2,2} (\mathbb{R}^N)}\) denote the closure of \({C_0^\infty (\mathbb{R}^N)}\) in the norm \({\|u\|_{{\mathcal{D}}^{2,2} (\mathbb{R}^N)}^2 := \int\nolimits_{\mathbb{R}^N} |\Delta u|^2.}\) Let \({K \in C^2 (\mathbb{R}^N).}\) We consider the following problem for ? ≥ 0: $$(P_\varepsilon) \left\{\begin{array}{llll}{\rm Find} \, u \in {\mathcal{D}}^{2, 2} (\mathbb{R}^N) \, \, {\rm solving} :\\ \left.\begin{array}{lll}\Delta^2 u = (1+ \varepsilon K (x)) u^{\frac{N+4}{N-4}}\\ u > 0 \end{array}\right\}{\rm in} \, \mathbb{R}^N.\end{array}\right.$$ We show an exact multiplicity result for (P ? ) for all small ? > 0. 相似文献
7.
Biswarup Chakraborty Shweta Kalra Rodrigo Beltrn‐Suito Chittaranjan Das Tim Hellmann Prashanth W. Menezes Matthias Driess 《化学:亚洲杂志》2020,15(6):852-859
In the urge of designing noble metal‐free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2CuI(PyHS)}2](OTf)2 ( 1 ), and utilized as an anode material in electrocatalytic OER for the first time. A hot injection of 1 yielded a pure phase and highly crystalline Cu9S5, which was then electrophoretically deposited (EPD) on a highly conducting nickel foam (NF) substrate. When assessed as an electrode for OER, the Cu9S5/NF displayed an overpotential of merely 298±3 mV at a current density of 10 mA cm?2 in alkaline media. The overpotential recorded here supersedes the value obtained for the best reported Cu‐based as well as the benchmark precious‐metal‐based RuO2 and IrO2 electrocatalysts. In addition, the choronoamperometric OER indicated the superior stability of Cu9S5/NF, rendering its suitability as the sustainable anode material for practical feasibility. The excellent catalytic activity of Cu9S5 can be attributed to the formation of a crystalline CuO overlayer on the conductive Cu9S5 that behaves as active species to facilitate OER. This study delivers a distinct molecular precursor approach to produce highly active copper‐based catalysts that could be used as an efficient and durable OER electro(pre)catalysts relying on non‐precious metals. 相似文献
8.
M. S. Raghu K. Basavaiah K. N. Prashanth K. B. Vinay 《Moscow University Chemistry Bulletin》2013,68(1):67-73
Four simple, selective and sensitive methods are described for the determination of levocetirizine dihydrochloride (LCT) in bulk drug and in tablets. The methods exploit the well-known analytical reaction between iodide and iodate in the presence of acid solution. Iodide present is oxidized by iodate in an amount equivalent to the HCl present in LCT to iodine and the liberated iodine is determined by four different procedures which inturn quantify LCT at varying detection range and sensitiveness. Two direct titrimetric procedures involve titration of iodine by thiosulphate either towards starch end point (method A) or potentiometrically (method B). Both the methods have a reaction stiochiometry of 1: 1 (LCT: liberated iodine) and have quantification ranges of 2–20 mg LCT for method A and method B. The liberated iodine is also measured spectrophotometrically at 350 nm (method C) or the iodine-starch complex measured at 570 nm (method D). In both the methods, the absorbance is found to be linearly dependent on the concentration of iodine which in turn is related to LCT concentration. The calibration curves are linear over 5–40 and 1.25–12.5 mg mL?1 LCT for method C and method D, respectively. The calculated molar absorptivity and Sandel sensitivity values are 1.0 × 104 L mol?1 cm?1 and 0.0435 mg cm?2, respectively for method C, and their respective values for method D are 2.9 × 104 L mol?1 cm?1 and 0.0156 mg cm?2. The intra-day and inter-day accuracy and precision studies were carried according to the ICH guidelines. The method was successfully applied to the analysis of two brands of tablets LCT. The accuracy was also checked by placebo blank and synthetic mixture analyses besides recovery study via standard addition procedure. 相似文献
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Prashanth Thodupunuri Marumamula Hanumaiah Shobanbabu Bommagani Gangavaram V. M. Sharma 《Journal of carbohydrate chemistry》2017,36(2-3):100-110
An efficient and short stereoselective synthesis of C11–C19 fragment of Macrolactin 3 was achieved. The vic-triol moiety (C15–C17) was derived from the C2–C4 chiral centers of D-mannose. The C-1 of D-mannose was utilized for the Wittig-olefination followed by hydroxylation using hydroboration reaction to introduce C11–C13 carbon chain in the C11–C19 fragment, whereas C5–C6 carbon chain of mannose was converted into C18–C19 of the target by dehydration reactions. Thus, the main strategy was (a) two consecutive Wittig-olefination reactions on C1 carbon of mannose, (b) inversion of C4 stereocenter, and (c) dehydration of C5–C6 vic-diol to olefin to result in the C11–C19 fragment. 相似文献
10.
A Molecular Approach to Self‐Supported Cobalt‐Substituted ZnO Materials as Remarkably Stable Electrocatalysts for Water Oxidation 下载免费PDF全文
Johannes Pfrommer Dr. Michael Lublow Anahita Azarpira Dr. Caren Göbel Marcel Lücke Dr. Alexander Steigert Martin Pogrzeba Dr. Prashanth W. Menezes Dr. Anna Fischer Dr. Thomas Schedel‐Niedrig Prof. Dr. Matthias Driess 《Angewandte Chemie (International ed. in English)》2014,53(20):5183-5187
In regard to earth‐abundant cobalt water oxidation catalysts, very recent findings show the reorganization of the materials to amorphous active phases under catalytic conditions. To further understand this concept, a unique cobalt‐substituted crystalline zinc oxide (Co:ZnO) precatalyst has been synthesized by low‐temperature solvolysis of molecular heterobimetallic Co4?xZnxO4 (x=1–3) precursors in benzylamine. Its electrophoretic deposition onto fluorinated tin oxide electrodes leads after oxidative conditioning to an amorphous self‐supported water‐oxidation electrocatalyst, which was observed by HR‐TEM on FIB lamellas of the EPD layers. The Co‐rich hydroxide‐oxidic electrocatalyst performs at very low overpotentials (512 mV at pH 7; 330 mV at pH 12), while chronoamperometry shows a stable catalytic current over several hours. 相似文献