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J.C. Selover Marianne Marsi David W. Parker J.A. Gladysz 《Journal of organometallic chemistry》1981,206(3):317-329
A series of kinetically unstable mononuclear anionic formyl complexes have been prepared by the action of Li(C2H5)3BH on neutral metal carbonyl precursors. One of these, Li+[(CO)4Mn(COC6H5)(CHO)]?, is shown to decompose by a hydride transfer disproportionation mechanism involving the by-product (C2H5)3B. 相似文献
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The reaction of dimethyl ketals with (CO)5MnSi(CH3)3 ( at 50 °C in CH3CN affords methyl enol ethers, generally in 75–95% yields. 相似文献
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Estimation of kinetic parameters in oxidative dehydrogenation of n-butenes over SnO2?Sb2O4 catalysts
K. Varga I. Marsi J. Halász K. Hernádi P. Fejes 《Reaction Kinetics and Catalysis Letters》1991,44(1):127-132
Kinetic curves measured in the oxidation of n-butenes over a SnSb=31 mixed oxide catalyst were fitted by the kinetic model put forward in a previous paper. The goodness of fitting shows that the kinetic behavior of this complex reaction system can be described by a mechanism involving acidic and redox sites on the catalyst surface.
- SnSb=31 , . , , - .相似文献
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