Two-nucleon transfer reactions in deformed nuclei using very heavy ions

Semiclassical methods found to be highly accurate for inelastic scattering are applied to the calculation of rotational population signatures in heavy-ion two-neutron transfer reactions involving highly deformed targets. Basic features to be expected for such reactions are predicted, and are shown to have straightforward semiclassical interpretations. The rotational population signatures for 2-neutron transfer are shown to be quite different from those expected for the analogous inelastic scattering case. Several calculations are shown for Xe projectiles on rare-earth targets, and it is demonstrated that such reactions can provide a unique probe of nuclear structure in high angular momentum states. The extension of the general ideas employed here to 1-nucleon transfer in deformed nuclei and to several other examples of transfer to highly collective states in deformed and vibrational nuclei using very heavy ions is briefly considered. Experimental possibilities are discussed, and it is concluded that relevant experiments in this virtually unexplored area are possible using sophisticated particle-γ spectroscopic techniques.     

Generalizing the Cooper-pair instability to doped Mott insulators

Copper oxides become superconductors rapidly upon doping with electron holes, suggesting a fundamental pairing instability. The Cooper mechanism explains normal superconductivity as an instability of a fermi-liquid state, but high-temperature superconductors derive from a Mott-insulator normal state, not a fermi liquid. We show that precocity to pair condensation with doping is a natural property of competing antiferromagnetism and d-wave superconductivity on a singly-occupied lattice, thus generalizing the Cooper instability to doped Mott insulators, with significant implications for the high-temperature superconducting mechanism.     

Comparison of flow and batch polymerization processes for production of vinyl ether terpolymers for use in the delivery of siRNA

Synthetic polymers represent a modifiable class of materials that can serve as adjuvants to address challenges in numerous biomedical and medicinal chemistry applications including the delivery of siRNA. Polymer‐based therapeutics offer unique challenges in both synthesis and characterization as compared to small molecule therapeutics. The ability to control the structure of the polymer is critical in creating a therapeutic. Reported herein, are batch and flow polymerization processes to produce amphiphilic terpolymers through a Lewis acid BF₃OEt₂‐catalyzed polymerization. These processes focus on controlling reaction variables, which affect polymer structure in this rapid, exothermic, nonliving cationic polymerization. In addition to analytical characterization of the polymers, the in vivo activity of the polymer‐siRNA conjugates is also highlighted—demonstrating that the method of synthesis does affect the in vivo activity of the resulting polymer conjugate. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1119–1129     

Algebraic stabilization of explicit numerical integration for extremely stiff reaction networks

In contrast to the prevailing view in the literature, it is shown that even extremely stiff sets of ordinary differential equations may be solved efficiently by explicit methods if limiting algebraic solutions are used to stabilize the numerical integration. The stabilizing algebra differs essentially for systems well-removed from equilibrium and those near equilibrium. Explicit asymptotic and quasi-steady-state methods that are appropriate when the system is only weakly equilibrated are examined first. These methods are then extended to the case of close approach to equilibrium through a new implementation of partial equilibrium approximations. Using stringent tests with astrophysical thermonuclear networks, evidence is provided that these methods can deal with the stiffest networks, even in the approach to equilibrium, with accuracy and integration timestepping comparable to that of implicit methods. Because explicit methods can execute a timestep faster and scale more favorably with network size than implicit algorithms, our results suggest that algebraically-stabilized explicit methods might enable integration of larger reaction networks coupled to fluid dynamics than has been feasible previously for a variety of disciplines.     

Selective Homogeneous Palladium(0)-Catalyzed Hydrogenation of Alkynes to (Z)-Alkenes

Zero-valent palladium precatalysts containing rigid bidentate bis(arylimino)acenaphthene ligands (shown schematically) facilitate the highly stereoselective homogeneous catalytic hydrogenation of alkynes to (Z)-alkenes. Internal, terminal, aryl-substituted, and cyclic alkynes are suitable substrates, as are some enynes, which are chemoselectively hydrogenated to dienes. E=CO(2)Me; R(1), R(2)=4-OCH(3), 4-CH(3), 2,6-(CH(3))(2).     

A critical investigation of the effects of the radio frequency potential on the trapping of externally injected ions in ion trap mass spectrometry

The sensitivity of all ion trap mass spectrometry (ITMS) methods is dependent on the trapping efficiency of the instrument. For ITMS instruments utilizing external ion sources, such as laser desorption, trapping efficiency is known to depend on the phase and amplitude of the radio frequency (RF) potential applied to the ring electrode at the time of ion introduction. It is remarkable that, in a considerable body of literature, no consensus exists regarding the effects of these parameters on the efficacy of trapping externally generated ions. In this paper, a summary of the literature is presented in order to highlight significant discrepancies. New laser desorption ion trap mass spectrometry (LD-ITMS) data are also presented, from which conclusions are drawn in our effort to clarify some of the confusion. Copyright 1999 John Wiley & Sons, Ltd.     

Multichannel time-reversal processing for acoustic communications in a highly reverberant environment

The development of time-reversal (T/R) communication systems is a recent signal processing research area dominated by applying T/R techniques to communicate in hostile environments. The fundamental concept is based on time-reversing the impulse response or Green's function characterizing the uncertain communications channel to mitigate deleterious dispersion and multipath effects. In this paper, we extend point-to-point to array-to-point communications by first establishing the basic theory to define and solve the underlying multichannel communications problem and then developing various realizations of the resulting T/R receivers. We show that not only do these receivers perform well in a hostile environment, but they also can be implemented with a "1 bit" analog-to-digital converter design structure. We validate these results by performing proof-of-principle acoustic communications experiments in air. It is shown that the resulting T/R receivers are capable of extracting the transmitted coded sequence from noisy microphone array measurements with zero-bit error.     

MNDO calculations for compounds containing aluminum and boron

Parametrization of MNDO for aluminum and comparisons of calculated molecular properties with experimental values indicate the general usefulness of MNDO to study aluminum-containing compounds. Although results are not as good as for molecules containing only C, H, N, and O, they are nevertheless accurate enough to be useful, especially when predictive biases noted in this article are considered. Inclusion of the d orbital in the MNDO scheme may improve the aluminum results. Results for boron-containing molecules not previously reported are also reported in this article.