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1.
Sanchez-sanz M; Blyth MG 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(2):125-138
Unsteady, axisymmetric stagnation flow about a circular cylinderis examined when the far-field flow is a periodic function oftime with a fixed time average and an oscillatory part of prescribedamplitude and frequency. Solutions are computed for arbitraryvalues of the Reynolds number, quantifying the effects of surfacecurvature, and a frequency parameter based on the period ofthe far-field flow. It is found that solutions remain regularand periodic provided that the far-field amplitude lies belowa critical value. Above this value, solutions terminate in afinite-time singularity. The blow-up time is delayed by increasingthe curvature of the surface. These results are corroboratedby asymptotic predictions valid in the limits of small and largeamplitude and frequency. For large Reynolds number, the problemreduces to the two-dimensional stagnation-point flow againsta plane wall studied by previous authors. 相似文献
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A theoretical and experimental study is made on light diffraction from holographic diffraction gratings, recorded in cubic photorefractive crystals Bi12SiO20 with (110) cut, for two orientation of the grating wave vector,K [001] andK [110], when an external electric field is applied. 相似文献
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This paper presents a detailed analysis of the electro-optic behavior of suspensions of noninteracting monodisperse beta-FeOOH particles. The electro-optic parameters are determined for aqueous suspensions of the oxide particles and the influences of surface charge and Debye layer thickness are verified. Since the conventional method of frequency analysis is inconsistent in the low-frequency range, new electro-optic parameters are introduced to define the frequency variation of the effects. Electric polarizability is determined with precision to a constant, and its relative variations are followed. As reported for other oxides, electric polarizability correlates with charge variations in the diffuse part of the particle surface electric layer, and its relaxation frequency increases with surface charge density, indicating a Maxwell-Wagner type of surface polarization. The alternating component of the responses yields particle relaxation frequency and the phase shift of the responses at this frequency. For all studied samples the phase shift at particle relaxation frequency is 45 degrees. The relative changes in the steady component of the responses in the low-frequency range are followed by field intensity curves at characteristic frequencies of the samples. Electrophoretic rotation is the process consistent with our data for the low-frequency effect. The results show that it is enhanced by the combined actions of low or slowly relaxing polarizability and significant electrophoretic mobility. 相似文献
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We demonstrate reversible photoinduced in situ reorientation of low molecular mass liquid crystals (LCs) by means of photoaddressable polymers (PAPs). These polymers contain mesogenic azobenzene side chains optimized to reorient cooperatively and effectively upon illumination with polarized light. Various low molecular mass LCs were introduced between two PAP layers and these sandwich devices were tested with respect to stability and reversibility of photoinduced orientation. Dissolution of the PAP layer by the low molecular mass LC was observed for several material combinations and systematically investigated. Different anisotropic dyes were added as fluorescence markers in order to monitor the photoinduced LC orientation. With an optimized material combination, more than 10 reversible reorientation processes could be realized with polarized light of either 514 or 405 nm wavelength, without any reduction in alignment quality. Further, microscopic polarized fluorescence patterns could be produced and erased within short exposure times. 相似文献
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S -nitrosothiols have many biological activities and may act as nitric oxide (NO) carriers and donors, prolonging NO half-life in vivo. In spite of their great potential as therapeutic agents, most S -nitrosothiols are too unstable to isolate. We have shown that the S -nitroso adduct of N -acetylcysteine (SNAC) can be synthesized directly in aqueous and polyethylene glycol (PEG) 400 matrix by using a reactive gaseous (NO/O2 ) mixture. Spectral monitoring of the S–N bond cleavage showed that SNAC, synthesized by this method, is relatively stable in nonbuf-fered aqueous solution at 25°C in the dark and that its stability is greatly increased in PEG matrix, resulting in a 28-fold decrease in its initial rate of thermal decomposition. Irradiation with UV light (λ= 333 nm) accelerated the rate of decomposition of SNAC to NO in both matrices, indicating that SNAC may find use for the photogeneration of NO. The quantum yield for SNAC decomposition decreased from 0.65 ± 0.15 in aqueous solution to 0.047 ± 0.005 in PEG 400 matrix. This increased stability in PEG matrix was assigned to a cage effect promoted by the PEG microenvironment that increases the rate of geminated radical pair recombination in the homolytic S–N bond cleavage process. This effect allowed for the storage of SNAC in PEG at −20°C in the dark for more than 10 weeks with negligible decomposition. Such stabilization may represent a viable option for the synthesis, storage and handling of S -nitrosothiol solutions for biomedical applications. 相似文献
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L. S. Uspenskaya T. Nurgaliev B. Blagoev T. Donchev S. Miteva 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(4):540-542
The change in the magnetic domain structure due to the proximity of a superconductor has been experimentally investigated for the first time. The complex character of magnetization reversal at temperatures below critical, caused by the mutual long-range effect of a superconductor and a magnet, has been shown. In particular, it is found that even magnetization reversal of the heterostructure by an in-plane field leads to the formation of Abrikosov vortices in the superconductor, carrying a flux perpendicularly to the film plane. It is shown that this is a consequence of the transformation of narrow domain walls into wide stripes due to the interaction with scattering fields from the superconductor. In turn, after penetration of the magnetic flux into the superconductor at some depth, the scattering fields cause backward magnetization reversal of the external film edge, as a result of which vortices with oppositely directed fluxes enter the crystal and propagate in the superconductor bulk in the form of chains along twins, as in the case of magnetization by a perpendicular magnetic field. Thus, at longitudinal magnetization, the flux enters the superconducting film in the form of wide stripes with alternating perpendicular induction, which is explained by the long-range interaction of the scattering fields of the superconductor with the manganite magnetization. 相似文献
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Heinz‐Georg Nothofer Andreas Meisel Tzenka Miteva Dieter Neher Michael Forster Masao Oda Günter Lieser Dessislava Sainova Akio Yasuda Donald Lupo Wolfgang Knoll Ullrich Scherf 《Macromolecular Symposia》2000,154(1):139-148
A series of 9,9‐dialkyl‐poly(fluorene‐2,7‐diyl)s containing linear and branched alkyl substituents with a Mn of up to 200000 g/mol has been synthesized. Moreover, some of the polymers were end capped with a suitable hole transport functionality, such as a triphenylamine derivative, to improve their charge transport properties and to control the molecular weight. The thermal alignment of these novel polymers on a rubbed polyimide layer led to highly anisotropic film formation with dichroic ratios (absorption parallel and perpendicular to the rubbing direction) of up to 26 in absorption and 21 in emission. 相似文献
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David Lagorce Tania Pencheva Bruno O Villoutreix Maria A Miteva 《BMC chemical biology》2009,9(1):6-10