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1.
ABSTRACTBayfol (PC-PBT blend ?lm) is a class of polymeric solid-state nuclear track detector which has a lot of applications in several radiation detection ?elds. It is a bisphenol-A polycarbonate PC blended with polybutylene terephthalate PBT. Bayfol/Palladium (PC-PBT/Pd) nanocomposite films have been deposited using the molding technique. It is worth mentioning that this report is almost the first one dealing with the topic of the changes of physical properties of Bayfol/Pd nanocomposite due to laser exposure. Samples from PC-PBT/Pd (5?wt%) nanocomposite were exposed to IR-pulsed laser of 5-W power, capable of producing 2000 pulses per second with pulse duration of 200?ns at 904?nm. The laser fluences were in the range 2–25?J/cm2. The resultant modi?cations in the exposed nanocomposite samples have been studied as a function of fluence using different characterization techniques such as X-ray diffraction (XRD), UV spectroscopy and color difference studies. The results indicate the proper dispersion of Pd nanoparticles in the PC-PBT matrix that causes a strong intermolecular interaction between Pd and PC-PBT, resulted in an increase in refractive index and the amorphous phase. Also, it is found that the laser exposure reduces the optical energy gap that could be attributed to the increase in structural disorder of the exposed PC-PBT/Pd nanocomposites due to crosslinking. Further, the color intensity ΔE, which is the color difference between the exposed samples and the non-exposed one, was increased with increasing the laser fluence, convoyed by a significant increase in the green and yellow color components. 相似文献
2.
Bulk superconducting samples of type Tl0.5Pb0.5Sr1.6Ba0.4CaCu2−x
Ru
x
O7−δ, (Tl, Pb)/Sr-1212, with 0.0 ≤ x ≤ 0.525 were prepared by the conventional one-step solid-state reaction technique. The prepared samples were investigated
using X-ray powder diffraction, electrical resistivity and electron paramagnetic resonance (EPR) measurements. Enhancement
of the phase formation, superconducting transition temperature T
c and hole carriers concentration P was observed up to x = 0.075. For x > 0.075, a reverse trend was observed. EPR spectra were measured at different temperatures (120–290 K) for all prepared samples.
The number of spins N participating in the resonance and the paramagnetic susceptibility χ were calculated as a function of both Ru-content and
temperature. N and χ increased as the Ru-content increased. A linear relationship between logN and 1/T was established, from which the activation energy E
a was calculated as a function of the Ru-content. The temperature dependence of χ was fitted according to Curie–Weiss type
of magnetic behavior. Curie constant C, Curie temperature θ, the effective magnetic moment μ and the electronic specific heat γ were estimated as a function of the Ru-content. 相似文献
3.
An exact expression for the functional derivative of the distribution function of a -nucleon pair in nuclear matter is derived. An approximate expression is also derived by means of the Kirkwood superposition approximation. The latter expression is subsequently used to obtain the Euler equation for the correlation functionf(r1) of a -nucleon pair in nuclear matter. 相似文献
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M.E. Grypeos 《Physics letters. [Part B]》1973,45(1):30-34
It is shown that an approximate expression in closed form can be obtained for the Jastrow trial energy per particle in nuclear matter. The undesirable truncation of the cluster expansion may thus be avoided. 相似文献
7.
The dependence of the harmonic oscillator (HO) energy level spacing ?ω on the particle number N is studied analytically for atomic (metal) clusters on the basis of their electronic densities, parametrizing Ekardt's results (for sodium clusters) by means of a Fermi distribution. An interesting feature of such an approach is that it leads, under the assumptions made, to “kinks,” that is, to “marked discontinuities in the slope” of ?ω at the closed shells. These discontinuities diminish as N increases. For large N, ?ω becomes simply: ?ω?c1N?1/3+c2N?1. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001 相似文献
8.
M. E. Grypeos G. A. Lalazissis S. E. Massen C. P. Panos 《Zeitschrift für Physik A Hadrons and Nuclei》1989,332(4):391-395
The relative contribution of the recoilless and quasifreeΛ-production in the (K?,π?) strangeness exchange reaction in nuclei is estimated by using the nuclear Debye-Waller factor. The expressions for theΛ-oscillator spacing ?ωΛ needed for such an estimate are derived by means of procedures which lead to quite simple formulae for ?ωΛ as function of the mass number and are useful in obtaining improved results. 相似文献
9.
G. A. Lalazissis C. P. Panos M. E. Grypeos Y. K. Gambhir 《Zeitschrift für Physik A Hadrons and Nuclei》1997,357(4):429-432
The simple algebraic form for the nuclear densities designed to incorporate correctly, the two physical requirements, namely, the asymptotic behaviour and the behaviour near the centre, is used to calculate the neutron distributions in several nuclei. Sample neutron densities for 58,64 Ni, 116Sn and 208Pb are presented. The calculation reveals an excellent agreement with the experiment as well as with the relativistic and nonrelativistic microscopic mean field calculations. The use of this algebraic form of the densities in the analytic studies is strongly advocated. 相似文献
10.
Salah E. M. Eltom Ahmed A. H. Abdellatif Hamzah Maswadeh Mohsen S. Al-Omar Atef A. Abdel-Hafez Hamdoon A. Mohammed Eiman ME. Agabein Ibrahim Alqasoomi Salem A. Alrashidi Mohammed S. M. Sajid Mugahid A. Mobark 《Molecules (Basel, Switzerland)》2021,26(12)
The ostrich oil of Struthio camelus (Ratite) found uses in folk medicine as an anti-inflammatory in eczema and contact dermatitis. The anti-inflammatory effect of a γ-lactone (5-hexyl-3H-furan-2-one) isolated from ostrich oil and its formulated nano-emulsion in formalin-induced paw edema was investigated in this study. Ostrich oil was saponified using a standard procedure; the aqueous residue was fractionated, purified, and characterized as γ-lactone (5-hexyl-3H-furan-2-one) through the interpretation of IR, NMR, and MS analyses. The γ-lactone was formulated as nano-emulsion using methylcellulose (MC) for oral solubilized form. The γ-lactone methylcellulose nanoparticles (γ-lactone-MC-NPs) were characterized for their size, shape, and encapsulation efficiency with a uniform size of 300 nm and 59.9% drug content. The γ-lactone was applied topically, while the formulated nanoparticles (NPs) were administered orally to rats. A non-steroidal anti-inflammatory drug (diclofenac gel) was used as a reference drug for topical use and ibuprofen suspension for oral administration. Edema was measured using the plethysmograph method. Both γ-lactone and γ-lactone-MC-NPs showed reduction of formalin-induced paw edema in rats and proved to be better than the reference drugs; diclofenac gel and ibuprofen emulsion. Histological examination of the skin tissue revealed increased skin thickness with subepidermal edema and mixed inflammatory cellular infiltration, which were significantly reduced by the γ-lactone compared to the positive control (p-value = 0.00013). Diuretic and toxicity studies of oral γ-lactone-MC-NPs were performed. No diuretic activity was observed. However, lethargy, drowsiness, and refusal to feeding observed may limit its oral administration. 相似文献