CONTROLLING THE 3D NANOSCALE ORGANIZATION OF BULK HETEROJUNCTION POLYMER SOLAR CELLS

In this study,the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography.After annealing treatment,either at elevated temperature or during slow solvent evaporation,nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer.Such a tailored morphology acco...     

Models for capacitated lot-sizing problem with backlogging,setup carryover and crossover

Setup operations are significant in some production environments. It is mandatory that their production plans consider some features, as setup state conservation across periods through setup carryover and crossover. The modelling of setup crossover allows more flexible decisions and is essential for problems with long setup times. This paper proposes two models for the capacitated lot-sizing problem with backlogging and setup carryover and crossover. The first is in line with other models from the literature, whereas the second considers a disaggregated setup variable, which tracks the starting and completion times of the setup operation. This innovative approach permits a more compact formulation. Computational results show that the proposed models have outperformed other state-of-the-art formulation.     

Monoamine Oxidase (MAO) as a Potential Target for Anticancer Drug Design and Development

Monoamine oxidases (MAOs) are oxidative enzymes that catalyze the conversion of biogenic amines into their corresponding aldehydes and ketones through oxidative deamination. Owing to the crucial role of MAOs in maintaining functional levels of neurotransmitters, the implications of its distorted activity have been associated with numerous neurological diseases. Recently, an unanticipated role of MAOs in tumor progression and metastasis has been reported. The chemical inhibition of MAOs might be a valuable therapeutic approach for cancer treatment. In this review, we reported computational approaches exploited in the design and development of selective MAO inhibitors accompanied by their biological activities. Additionally, we generated a pharmacophore model for MAO-A active inhibitors to identify the structural motifs to invoke an activity.     

Computational model for simultaneous Q switching and mode-locking in a solid state laser with a saturable absorber

A numerical model of rate equations for a four-level solid state laser with Cr⁴⁺:YAG saturable absorber including excited state absorption ESA is presented. The cavity is divided into a large number of disks and the model is solved for each disk and its local corresponding photon flux. The flux array is shifted for each recurrence simulating the movement of photons inside the cavity during the round trip. This simulator can describe the mode-locking phenomenon and can be used to simulate simultaneous mode locking and Q switching with a saturable absorber.     

Analysis of laser-diode end-pumped intracavity frequency-doubled,passively Q-switched and mode-locked Nd:YVO<Subscript>4</Subscript> laser

Simultaneous Q-switching and mode locking in a laser-diode end-pumped intracavity frequency-doubled Nd:YVO₄/KTP green laser using a Cr⁴⁺:YAG saturable absorber with 81% initial transmission is experimentally demonstrated. At an incident pump power of 6 W, 300 mW of average green power was obtained, which is around four times higher than the cw green power obtained without the Cr⁴⁺:YAG crystal. The repetition rate of the mode-locked green pulses was 400 MHz and the individual mode-locked pulse width was measured to be 500 ps. The repetition rate of the Q-sw itched envelope of the mode-locked pulses was 15 kHz at 6 W of incident pump power. The energy of the mode-locked pulse at the peak of the Q-sw itched envelope was estimated to be 1 J and the peak power was estimated to be 2.4 kW. The measured width and the total energy of the Q-sw itched envelope of the mode-locked pulses was 47 ns and 21 J, respectively, at the maximum incident pump power. An analysis of the system by incorporating a nonlinear loss term due to the intracavity second-harmonic generation to the general recurrence relation for the mode-locked pulses under the Q-sw itched envelope at the fundamental wavelength has been presented. Using a hyperbolic secant square function to model the mode-locked pulse, the temporal shape of a single Q-sw itched pulse at the second-harmonic wavelength has been reconstructed. The theoretical calculations of the pulse parameters like pulse energy, peak power, pulse width and pulse-symmetry factor have shown fairly good agreement with the experimental results. PACS 42.55.Rz; 42.55.Xi; 42.60.By     

Preparation, structural analysis and dielectric properties of Bi x La1−x FeO3 perovskite

Rare earth element substituted bismuth ferrites (BiFeO₃) are of enormous importance as magnetoelectric materials. The polycrystalline samples of Bi _x La_1−x FeO₃ (x=0, 0.2, 0.4, 0.6, 0.8) were prepared by solid-state reaction using standard ceramic method. The single-phase formation of these compounds was confirmed by X-ray diffraction (XRD) studies. The samples with x=0, 0.2, 0.4, 0.6 are found to be orthorhombic while the sample with x=0.8 is triclinic. The dielectric constant (ε′) and dissipation factor (tan δ) were measured in the frequency range 100 Hz to 1 MHz at room temperature and as a function of temperature at certain fixed frequencies (1 kHz, 10 kHz, 100 kHz, 1 MHz). All the samples showed dielectric dispersion. The dielectric constant with temperature shows a broad peak; the peak temperature shifts with frequency which reflects the relaxor-type behavior. The peak above 600 K in the measured temperature range corresponds to antiferromagnetic ordering temperature (Néel temperature). The broadness of the peak changes with composition. The ac conductivity as well as ε′ are found to be maximum for the sample x=0.2 at room temperature.     

Magnetoelectric effect in cobalt ferrite-barium titanate composites and their electrical properties

CoFe₂O₄-BaTiO₃ composites were prepared using conventional ceramic double sintering process with various compositions. Presence of two phases in the composites was confirmed using X-ray diffraction. The dc resistivity and thermoemf as a function of temperature in the temperature range 300 K to 600 K were measured. Variation of dielectric constant (ɛ′) with frequency in the range 100 Hz to 1 MHz and also with temperature at a fixed frequency of 1 kHz was studied. The ac conductivity was derived from dielectric constant (ɛ′) and loss tangent (tan δ). The nature of conduction is discussed on the basis of small polaron hopping model. The static value of magnetoelectric conversion factor has been studied as a function of magnetic field.