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1.
Lopez-Martens A Hannachi F Dossing T Schück C Collatz R Gueorguieva E Vieu C Leoni S Herskind B Khoo TL Lauritsen T Ahmad I Blumenthal DJ Carpenter MP Gassmann D Janssens RV Nisius D Korichi A Bourgeois C Astier A Ducroux L Le Coz Y Meyer M Redon N Sharpey-Schafer JF Wilson AN Korten W Bracco A Lucas R 《Physical review letters》1996,77(9):1707-1710
2.
The catalytic constants for the -butylaminolysis of sultones in aprotic-apolar solvents are linearly correlated with a combination of the hydrogen-bonding parameter and the polarity parameter of the catalyst. 相似文献
3.
The use of Tenax GC for the extraction of organic micro-pollutants such as pesticides and polynuclear aromatic hydrocarbons from water has been studied. In the absence of other contaminants and under conditions standardized at the time as optimal, the recovery of such substances is, on average, over 90%, both for the organochlorine and organophosphorus pesticides and for polynuclear aromatic hydrocarbons. Research into the effectiveness of extraction with Tenax from natural waters and water artificially contaminated with surfactants, fats and oils etc., in the laboratory is now being carried out. 相似文献
4.
V. Leoni A. M. Caricchia C. Cremisini S. Chiavarini L. Fabiani R. Morabito 《International journal of environmental analytical chemistry》2013,93(1-4):411-422
Abstract Total Diet Studies on pesticide residues in foods carried out in Italy in the last two decades are briefly summarized and data are discussed. Health risk assessment is expressed by the ratio total intake/ADI (%ADI ingested) for each compound and by the sum of the percentages of ADI for each compound within the same class of pesticides. The total dietary intake of chlorinated pesticides, that was almost 100% of ADI in the years 1970-74, decreased down to 10% in the period 1978-84. This trend was confirmed for DDT in recent years, while data on Lindane and Heptachlor seem to be constant. As regards the organophosphorus pesticides the sum of the percentages of ADI ingested for each compound, extrapolated from recent data (1990-1991) is about 20% and can be regarded as reasonably acceptable because the study included practically all the mainly used compounds. Only few data are available for some pesticides like dithiocarbamates, especially EBDCs and their derivatives (e.g. ETU), other carbamates (e.g. aldicarb), paraquat etc. Moreover, analytical methods for these compounds should be improved. The need for a considerable improvement in the number and organization of monitoring structures, in the use of standardized analytical procedures, in good laboratory practice standards and in the realibility of “monitoring protocols” and their homogeneity is evidenced. 相似文献
5.
Renato D’Angelo Cristy Leonor Azanza Ricardo Alberto Mittiga Paolo Scardi Matteo Leoni 《Journal of Sol-Gel Science and Technology》2014,72(3):490-495
Zinc-rich/copper-poor Cu2-xZn1+xSnS4 (x = 0.2, CZTS) has been successfully produced in film and powder form using two non-aqueous solutions (of metal salts and thiourea) without the need for sulfurization during the annealing phase. A reaction route is proposed and the choices of the solvents (water, ethyleneglycol, ethanol, methanol) and of the tin source (tin chloride pentahydrate or anhydrous) discussed and justified. A pure and coarse-grained material is obtained with a mix of metal salts in methanol and thiourea in ethylene glycol. The tin pentahydrate salt seems a better alternative to the commonly used anhydrous chloride. 相似文献
6.
Jae Won Chang Mohammed Bhuiyan Hsiu‐Ming Tsai Hannah J. Zhang Gang Li Shaghayegh Fathi David C. McCutcheon Lara Leoni Richard Freifelder Chin‐Tu Chen Raymond E. Moellering 《Angewandte Chemie (International ed. in English)》2020,59(35):15161-15165
Herein, we report the development of an 18F‐labeled, activity‐based small‐molecule probe targeting the cancer‐associated serine hydrolase NCEH1. We undertook a focused medicinal chemistry campaign to simultaneously preserve potent and specific NCEH1 labeling in live cells and animals, while permitting facile 18F radionuclide incorporation required for PET imaging. The resulting molecule, [18F]JW199, labels active NCEH1 in live cells at nanomolar concentrations and greater than 1000‐fold selectivity relative to other serine hydrolases. [18F]JW199 displays rapid, NCEH1‐dependent accumulation in mouse tissues. Finally, we demonstrate that [18F]JW199 labels aggressive cancer tumor cells in vivo, which uncovered localized NCEH1 activity at the leading edge of triple‐negative breast cancer tumors, suggesting roles for NCEH1 in tumor aggressiveness and metastasis. 相似文献
7.
F. Mattioli M. Ortolani S. Lupi O. Limaj R. Leoni 《Applied Physics A: Materials Science & Processing》2011,103(3):627-630
We report on the fabrication and optical properties of thin metal films periodically patterned with square hole arrays of
2 micron pitch, which behave as substrateless plasmonic devices at mid-infrared frequencies. Large (3×3 mm2) meshes were fabricated by metallizing a patterned silicon nitride membrane. The mid-infrared spectra display resonant absorption
lines with a Q-factor up to 22 in both transmission and reflection, due to the interaction of the radiation with surface plasmon
modes on both faces of the film, allowed by substrate removal. The devices can be used to fabricate surface plasmon-based
chemical sensors employing mid-infrared radiation. 相似文献
8.
A. Casaburi M. Ejrnaes F. Mattioli A. Gaggero R. Leoni N. Martucciello S. Pagano M. Ohkubo R. Cristiano 《Journal of nanoparticle research》2011,13(11):6121-6131
The recent progress in the nanofabrication of superconducting films opens the road toward detectors with highly improved performances.
This is the case for superconducting nano-striplines where the thickness and the width are pushed down to the extreme limits
to realize detectors with unprecedented sensitivity and ultra fast response time. In this way quantum detectors for single
photons at telecommunication wavelengths and for macromolecules such as proteins can be realized. As is often the case in
applied nanotechnology, it is a challenge to make devices with the necessary macroscopic dimensions that are needed to interface
present technologies, while maintaining the performance improvements. For nano-stripline detectors, both the fast temporal
response and the device sensitivity is generally degraded when the area is increased. Here, we present how such detectors
can be scaled up to macroscopic dimensions without losing the performance of the nano-structured active elements by using
an innovative configuration. In order to realize ultrathin superconducting film the nano-layer is growth with a careful setup
of the deposition technique which guarantees high quality and thickness uniformity at the nano-scale size. The active nano-strips
are defined with the state-of-the-art electron beam nanolithography to achieve a highly uniform linewidth. We present working
detectors based on nano-strips with thicknesses 9–40 nm and widths of 100–1000 nm which exhibit unprecedented speed and area
coverage (40 × 40 μm2 for single photon detectors and 1 × 1 mm2 for single molecule detectors) based on niobium nitride thus enabling practical use of this nanotechnology. 相似文献
9.
10.
We present a general theory to study optimal regularity for a large class of nonlinear elliptic systems satisfying general boundary conditions and in the presence of a geometric transmission condition on the free boundary. As an application we give a full positive answer to a conjecture of De Giorgi on the analyticity of local minimizers of the Mumford‐Shah functional. © 2004 Wiley Periodicals, Inc. 相似文献