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1.
The energy balance in the fission of 234U has been investigated on the basis of experimental results from the 233U(d, pf) reaction. Taking into account the neutron evaporation we have deduced the total kinetic energy and excitation energy distributions of the primary fragments as functions of the excitation energy of the fissioning nucleus. The neutron evaporation temperatures have been adjusted so as to reproduce the average value and width of the measured kinetic energy distributions for each fragmentation. Excitation energy distributions of the fragments have been deduced. The data are discussed in the framework of the liquid-drop model with shell corrections. Evidence for energy dissipation in the fission of 234U, involving drastic changes in the scission configuration, is shown for some fragmentation modes. 相似文献
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The tris(2-fluoro-6-pyridylmethyl)amine ligand, F3TPA, can easily be prepared by reaction of 2-fluoro-6-bromomethylpyridine with NH4Cl in the presence of NaOH. Complexation to FeCl2 affords the high-spin F3TPAFe(II)Cl2 complex, the X-ray structure of which is reported. The three fluorine substituents provide enough steric hindrance to force the tripod to coordinate in the tridentate mode, affording a trigonal bipyramidal iron center. This complex is thermally stable, and it reacts instantaneously with molecular dioxygen to afford the unsymmetrical micro-oxo dimer F3TPAFe(III)ClOFe(III)Cl3 as the major product, together with small amounts of the mixed salt [F3TPAFe(II)Cl]2, [Fe(III)2OCl6]. These two complexes have been isolated and characterized by X-ray diffraction analysis. A mechanism by which they are obtained is suggested and seems to parallel the well-known process of autoxidation of ferrous porphyrins. 相似文献
3.
Souad Chaouche Rachid Ouarsal Brahim El Bali Mohammed Lachkar Michael Bolte Michal Dusek 《Journal of chemical crystallography》2010,40(6):526-530
Abstract
Crystal structure of Li2HPO3,H2O was determined by single-crystal X-Ray diffraction analysis at 173(2) K. It crystallizes in the monoclinic system (P21/c) with the parameters: a = 5.0322(9) ?, b = 8.9795(17) ?, c = 17.088(4) ?, β = 92.672(16)° and Z = 8. The structure was refined to R = 0.0237 and ωR = 0.0650 for 1449 reflexions. The framework of Li2HPO3, H2O can be described as layers perpendicular to the crystallographic c axis. The structure contains two types of Li-tetrahedrons. In one kind each O atom belongs to one HPO3 group, while in the second kind one apex is an O from water. A network of hydrogen bonds interactions insures the connection between the layers. 相似文献4.
Souad Chaouche Rachid Ouarsal Mohammed Lachkar Francesco Capitelli Brahim El Bali 《Journal of chemical crystallography》2010,40(6):486-490
Abstract
A new hybrid phosphate, (C6H5NH3)[ZnCl(HPO3)], has been synthesized and its structure characterized from single-crystal X-ray diffraction. The title compound crystallizes in the orthorhombic space group Pbca (n. 61) with the unit-cell parameters: a = 9.8635(2) ?, b = 9.4516(10) ?, c = 22.2430(4) ?, Z = 8 and V = 2,073.62(6) ?3. The final R factors were R/ωR = 0.0361/0.0924. Its framework might be described as a layered structure with two (010)-parallel cationic and anionic layers. The IR spectrum of this phase shows characteristic bands of phosphite and anilinium groups. 相似文献5.
Le Gac S Najjari B Motreff N Remaud-Le Saec P Faivre-Chauvet A Dimanche-Boitrel MT Morgenstern A Bruchertseifer F Lachkar M Boitrel B 《Chemical communications (Cambridge, England)》2011,47(30):8554-8556
For the first time, α-emitter radioisotope (213)Bi has been incorporated into porphyrin chelates, with rates matching with the short period of the radionuclide. An in situ transmetalation mechanism involving the daughter isotope (209)Pb is expected to boost the (213)Bi radiolabeling process. 相似文献
6.
Hanane El Hajaji Nadya Lachkar Katim Alaoui Yahya Cherrah Abdellah Farah Abdesslam Ennabili Brahim El Bali Mohammed Lachkar 《Arabian Journal of Chemistry》2011,4(3):321-324
We evaluated the in vitro antioxidant property and phytochemical constituents of the crude ethyl acetate and methanol extract of the three genders of carob tree barks (spontaneous male, spontaneous female, and grafted female). The scavenging activity on DPPH (1,1-diphenyl-2-picrylhydrazyl) was determined, as well as the phenolic contents (Folin–Ciocalteu method) of both the extracts. The highest antioxidant activity and the higher amounts of total phenols were shown in methanol crude bark extract for the three genders. Variety significantly affected the phenol content and the antioxidant activity, with the spontaneous male variety globally showed a higher polyphenol concentration and antioxidant activity than the grafted female and spontaneous female. 相似文献
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A new route to 15-hydroxydehydroabietic acid derivatives from abietic acid (11), via abieta-8,13(15)-dien-18-oic acid (12), is reported. Utilizing this, the first synthesis of bioactive terpenes 3, 6, 9 and 10, as well as natural diol 4 and lactones 7-8 was achieved. 相似文献
9.
El Antri A Messouri I Bouktaib M El Alami R Bolte M El Bali B Lachkar M 《Molecules (Basel, Switzerland)》2004,9(8):650-657
Two tetrahydroisoquinoline alkaloids were extracted from the alkaloid fraction of a methanol extract of the seeds of Calycotome Villosa Subsp. intermedia. Their structures were established as (R)-1-hydroxymethyl-7-8-dimethoxy-1,2,3,4-tetrahydro- isoquinoline (1) and (S)-7-hydroxymethyl-2-3-dimethoxy-7,8,9,10-tetrahydroisoquinoline chloride (2) by spectroscopic techniques and X-ray diffraction analysis. 相似文献
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