全文获取类型
收费全文 | 28806篇 |
免费 | 4975篇 |
国内免费 | 4311篇 |
专业分类
化学 | 21700篇 |
晶体学 | 392篇 |
力学 | 1552篇 |
综合类 | 288篇 |
数学 | 3112篇 |
物理学 | 11048篇 |
出版年
2024年 | 96篇 |
2023年 | 575篇 |
2022年 | 1092篇 |
2021年 | 1147篇 |
2020年 | 1176篇 |
2019年 | 1149篇 |
2018年 | 1041篇 |
2017年 | 1041篇 |
2016年 | 1402篇 |
2015年 | 1525篇 |
2014年 | 1829篇 |
2013年 | 2345篇 |
2012年 | 2756篇 |
2011年 | 2801篇 |
2010年 | 2030篇 |
2009年 | 1860篇 |
2008年 | 2030篇 |
2007年 | 1856篇 |
2006年 | 1671篇 |
2005年 | 1297篇 |
2004年 | 939篇 |
2003年 | 757篇 |
2002年 | 775篇 |
2001年 | 695篇 |
2000年 | 524篇 |
1999年 | 555篇 |
1998年 | 424篇 |
1997年 | 330篇 |
1996年 | 311篇 |
1995年 | 305篇 |
1994年 | 252篇 |
1993年 | 239篇 |
1992年 | 184篇 |
1991年 | 185篇 |
1990年 | 168篇 |
1989年 | 145篇 |
1988年 | 109篇 |
1987年 | 103篇 |
1986年 | 82篇 |
1985年 | 75篇 |
1984年 | 33篇 |
1983年 | 37篇 |
1982年 | 30篇 |
1981年 | 23篇 |
1980年 | 15篇 |
1979年 | 11篇 |
1978年 | 8篇 |
1977年 | 10篇 |
1974年 | 7篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
Analysis and pharmacokinetic study of polyphyllin H in beagle dog plasma after oral administration of Rhizoma Paridis Extracts by LC‐MS/MS 下载免费PDF全文
2.
Jing Zhihong Ling Baoping Yu Yang Qi Wei Zhang Shufang 《Journal of Sol-Gel Science and Technology》2015,73(1):112-117
Journal of Sol-Gel Science and Technology - A novel gas sensing material, La–Y co-doped TiO2 nanoparticles, was synthesized by sol–gel method and applied to detect organic pollutants... 相似文献
3.
Mass concentration and isotopic values δ13C and 14C are presented for the water-insoluble refractory carbon(WIRC) component of total suspended particulates(TSP),collected weekly during 2003,as well as from October 2005 to May 2006 at the WMO-GAW Mt.Waliguan(WLG) site.The overall average WIRC mass concentration was(1183±120)ng/m3(n = 79),while seasonal averages were 2081 ±1707(spring),454±205(summer),650±411(autumn),and 1019±703(winter) ng/m3.Seasonal variations in WIRC mass concentrations were consistent with black carbon measurements from an aethalometer,although WIRC concentrations were typically higher,especially in winter and spring.The δ13C PDB value(-25.3 ± 0.8)%.determined for WIRC suggests that its sources are C3 biomass or fossil fuel combustion.No seasonal change in δ13C PDB was evident.The average percent Modern Carbon(pMC) for 14C in WIRC for winter and spring was(67.2 ± 7.7)%(n = 29).Lower pMC values were associated with air masses transported from the area east of WLG,while higher pMC values were associated with air masses from the Tibetan Plateau,southwest of WLG.Elevated pMC values with abnormally high mass concentrations of TSP and WIRC were measured during a dust storm event. 相似文献
4.
JPC – Journal of Planar Chromatography – Modern TLC - A new high-performance thin-layer chromatographic (HPTLC) method has been developed for the simultaneous estimation of... 相似文献
5.
Simultaneous quantitative determination of 20 active components in the traditional Chinese medicine formula Zhi‐Zi‐Da‐Huang decoction by liquid chromatography coupled with mass spectrometry: application to study the chemical composition variations in different combinations 下载免费PDF全文
Zheng Tang Ran Yin Kaishun Bi Heyun Zhu Fei Han Kelin Chen Fenrong Wang 《Biomedical chromatography : BMC》2015,29(9):1406-1414
6.
Dekun Wu Dr. Qing Xu Dr. Jing Qian Prof. Xiaopeng Li Prof. Yuhan Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):3105-3111
Covalent organic frameworks (COFs) are a new class of crystalline porous polymers comprised mainly of carbon atoms, and are versatile for the integration of heteroatoms such as B, O, and N into the skeletons. The designable structure and abundant composition render COFs useful as precursors for heteroatom-doped porous carbons for energy storage and conversion. Herein, we describe a multifunctional electrochemical catalyst obtained through pyrolysis of a bimetallic COF. The catalyst possesses hierarchical pores and abundant iron and cobalt nanoparticles embedded with standing carbon layers. By integrating these features, the catalyst exhibits excellent electrochemical catalytic activity in the oxygen reduction reaction (ORR), with a 50 mV positive half-wave potential, a higher limited diffusion current density, and a much smaller Tafel slope than a Pt-C catalyst. Moreover, the catalyst displays superior electrochemical performance toward the hydrogen evolution reaction (HER), with overpotentials of −0.26 V and −0.33 V in acidic and alkaline aqueous solution, respectively, at a current density of 10 mA cm−2. The overpotential in the catalysis of the oxygen evolution reaction (OER) was 1.59 V at the same current density. 相似文献
7.
8.
Naphthalimide‐phthalimide derivative based photoinitiating systems for polymerization reactions under blue lights 下载免费PDF全文
Pu Xiao Frédéric Dumur Jing Zhang Bernadette Graff Didier Gigmes Jean Pierre Fouassier Jacques Lalevée 《Journal of polymer science. Part A, Polymer chemistry》2015,53(5):665-674
Naphthalimide‐phthalimide derivatives (NDPDs) have been synthesized and combined with an iodonium salt, N‐vinylcarbazole, amine or 2,4,6‐tris(trichloromethyl)‐1,3,5‐triazine to produce reactive species (i.e., radicals and cations). These generated reactive species are capable of initiating the cationic polymerization of epoxides and/or the radical polymerization of acrylates upon exposure to very soft polychromatic visible lights or blue lights. Compared with the well‐known camphorquinone based systems used as references, the novel NDPD based combinations employed here demonstrate clearly higher efficiencies for the cationic polymerization of epoxides under air as well as the radical polymerization of acrylates. Remarkably, one of the NDPDs (i.e., NDPD2) based systems is characterized by an outstanding reactivity. The structure/reactivity/efficiency relationships of the investigated NDPDs were studied by fluorescence, cyclic voltammetry, laser flash photolysis, electron spin resonance spin trapping, and steady state photolysis techniques. The key parameters for their reactivity are provided. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 665–674 相似文献
9.
A rapid method had been used for comparative study on Artemisia halodendron Turcz. and its two related plants by gas phase-mass spectrometry (GC-MS). The comparison of the volatile oils obtained in three plants by GC-MS were similar in 20 compositions. However, n-Hexadecanoic acid (10.40%), Biphenyl (7.867%) and 9,12-Octadecadienoic acid (7.25%) were the predominant in the volatile oils of A. halodendron Turcz., whereas these constituents did not exist in the other two plants. And the study investigated the effect of three plants against CCl4-induced hepatotoxicity in mice. 70% ethanol extracts of A. halodendron Turcz. showed weaker protective effect than the other two plants. It suggested that they provide a basis for the identification of the A. halodendron Turcz. from the other two plants and the ethanol extract from three plants exerted a protecting effect against hepatotoxicity. 相似文献
10.