Nuclear pears: Recent developments and future prospects

We report studies of examples of reflection-asymmetric nuclei which are difficult to access using compound nucleus reactions. The octupole radium isotopes withN>132 and radon isotopes are not accessible by reactions employing stable targets and beams; we have shown that multinucleon transfer reactions can populate these nuclei with sufficient yield for their structure to be determined. We report high-spin studies in^{218, 220, 222}Rn and^{222, 224, 226, 228, 230}Ra: these show that the Ra isotopes withA<228 have the characteristics of octupole deformed nuclei whereas the Rn isotopes behave like octupole vibrators. Measurements of theB(E1)/B(E2) ratios indicate that the electric dipole moment in these nuclei is constant with spin. The most octupole deformed nuclei are predicted to be uranium isotopes withN≈132; measurements of the very fissile nucleus²²⁶U suggest that it is octupole deformed and has a large intrinsic electric dipole moment. Finally, we speculate that the best examples of pear shapes are the hyperdeformed minima predicted to lie low in uranium isotopes withN≈140; their signature of high-multiplicity low-energyE1 photon cascades should be detectable using present-day high-efficiency germanium arrays.     

Homopolar- and Heteropolar Bond Dissociation Energies and Heats of Formation of Radicals and Ions in the Gas Phase. I. Data on organic molecules

The literature data on heteropolar and homopolar 2-center bond dissociation energies in organic molecules in the gas phase and the corresponding heats of formation of radicals and ions have been critically evaluated. Data for more than 500 bonds are represented in tabular form together with the pertinent literature references. Selected electron affinities and π-bond dissociation energies have also been incorporated. The follow-up paper will discuss some empirical general aspects of these data particularly regarding the effect of structure on the bond dissociation energies.     

Extension of the Linear Matching Method to frame structures made from a material that exhibits softening

This paper considers the problem of evaluating the maximum load that an elastic–plastic frame structure can withstand when material or element softening is present. Here we propose an extension of the Linear Matching Method to take into account material softening. The technique has two major steps: reduction of the total potential energy to obtain the solution of a linear problem and scaling of the resulting mechanism of deformation to maximize the load. Two procedures are evaluated for the second of these steps; a direct approach which simply examines how the solution evolves along a radial path in degree of freedom space, and an incremental method which takes into account how the solution might evolve along paths away from this radial line. It is demonstrated that the incremental approach is more robust and provides stable solutions for high and low levels of softening, but numerical instabilities in the procedure can occur for intermediate degrees of softening.     

In-beam spectroscopy of 253, 254No

In-beam conversion electron spectroscopy experiments have been performed on the transfermium nuclei ^{253, 254}No using the conversion electron spectrometer SACRED in nearly collinear geometry in conjunction with the gas-filled separator RITU at the University of Jyv?skyl?. The experimental setup is discussed and the spectra are compared to Monte Carlo simulations. The implications for the ground-state configuration of ²⁵³No are discussed. Received: 21 March 2002 / Accepted: 16 May 2002 / Published online: 31 October 2002 RID="a" ID="a"e-mail: rdh@ns.ph.liv.ac.uk RID="b" ID="b"Present address: GANIL, F-14021 Caen, France. RID="c" ID="c"Permanent address: IReS Strasbourg, IN2P3-CNRS, F-67037-Strasbourg, France. RID="d" ID="d"Present address: CEA/DIF DCRE/SDE/LDN F-91680 Bruyeres-le-Chatel. RID="e" ID="e"Present address: Daresbury Laboratory, Daresbury WA4 4AD, UK. RID="f" ID="f"Permanent address: IPN Lyon, IN2P3-CNRS, F-69037 Lyon, France.     

Untersuchung von Fetten

Ohne Zusammenfassung     

High-spin study of Xe

High-spin states have been populated in ₅₄¹¹⁹Xe via the ⁹⁶Mo(²⁷Al,p3n) reaction at 133 MeV, using the γ-ray spectrometer to record triple γ-ray coincidences. The known level scheme has been significantly extended and several band crossings identified. In particular, the νh_11/2 yrast band has been extended to I^π = (83/2⁻) and shows features which are consistent with those of smooth band termination at high spin. Theoretical results for ¹¹⁹Xe at high spin are discussed within the framework of cranked Nilsson-Strutinsky calculations, together with results for ¹¹⁷Xe.     

Electronic absorption and emission spectra of mixed-ligand ruthenium(II) complexes [Ru(2,2'-bipyridine)n {2-(2-pyridyl)quinoline}3−n]2+(n = 0,1,2 or 3)

Room-temperature electronic absorption spectra, and emission spectra at room temperature and 77 K, have been measured for the mixed ligand 2,2'-bipyndine-2-(2-pyridyl)quuioline complexes of ruthemum (II). The charge-transfer states initially populated by absorption of visible light are essentially localised on individual ligands, and there is little coupling of these ligand states. Emissions, however, occur from a single state possessing the characteristics of the pyridylquinoline ligand alone.     

Neighbouring group participation in phosphate esters. Fragmentation of {2-arylethyl} phosphorochloridates

(β-Arylethyl)phosphorochloridates decompose easily yielding 1-chloro-2-arylethanes and/or arylethylenes, presumably via the concerted P-Cl fission and the expulsion of metaphosphate-like species.