全文获取类型
收费全文 | 69篇 |
免费 | 0篇 |
专业分类
化学 | 18篇 |
数学 | 3篇 |
物理学 | 48篇 |
出版年
2019年 | 1篇 |
2014年 | 2篇 |
2013年 | 2篇 |
2012年 | 1篇 |
2011年 | 1篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2007年 | 1篇 |
2006年 | 1篇 |
2005年 | 2篇 |
2004年 | 1篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 5篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1939年 | 1篇 |
排序方式: 共有69条查询结果,搜索用时 640 毫秒
1.
Arunee Tabtiang Noree Phochalam Richard Venables 《Journal of Polymer Science.Polymer Physics》2004,42(6):965-973
The effects of the copolymer microstructure on the morphology evolution in polyethylene/poly(ethylene‐co‐α‐olefin) blends were investigated. Microscopy revealed that the melt‐phase morphology, inferred from the solid‐state morphologies of annealed and quenched samples, was strongly affected by the copolymer structure, that is, the branch content and branch length. Higher molecular weight α‐olefin comonomer residues and residue contents in the copolymers led to faster coarsening of the morphology. The molecular weight of the polyethylene and the copolymers affected the coarsening rates of the morphology, principally through its influence on the melt viscosity. The effects of the molecular weight were largely explained by the normalization of the coarsening rate data with respect to the thermal energy and zero‐shear‐rate viscosity. Thus, the effect of the molecular weight on the compatibility of the blends was much smaller than the effects of the branch length and branch number. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 965–973, 2004 相似文献
2.
3.
4.
5.
An experimental study of the thermal decomposition of a β‐hydroxy alkene, 3‐methyl‐3‐buten‐1‐ol, in m‐xylene solution, has been carried out at five different temperatures in the range of 513.15–563.15 K. The temperature dependence of the rate constants for the decomposition of this compound in the corresponding Arrhenius equation is given by ln k (s?1) = (25.65 ± 1.52) ? (17,944 ± 814) (kJ·mol?1)·T?1. A computational study has been carried out at the M05–2X/6–31+G(d,p) level of theory to calculate the rate constants and the activation parameters by the classical transition state theory. There is a good agreement between the experimental and calculated rate constants and activation Gibbs energies. The bonding characteristics of reactant, transition state, and products have been investigated by the natural bond orbital analysis, which provides the natural atomic charges and the Wiberg bond indices. Based on the results obtained, the mechanism proposed is a one‐step process proceeding through a six‐membered cyclic transition state, being a concerted and slightly asynchronous process. The results have been compared with those obtained previously by us (Struct Chem 2013, 24, 1811–1816) for the thermal decomposition of 3‐buten‐1‐ol, in m‐xylene solution. We can conclude that in the compound studied in this work, 3‐methyl‐3‐buten‐1‐ol, the effect of substitution at position 3 by a weakly activating CH3 group is the stabilization of the transition state formed in the reaction and therefore a small increase in the rate of thermal decomposition. 相似文献
6.
Abstract Due to the wide use of polymers in medicine, researchers are required to solve a very important problem–to understand the interaction between materials of nonphysiological origin and the surrounding biological liquids, and tissues, particularly blood. 相似文献
7.
A new apparatus is described which allows transmission electron microscope observations to be made of the growth of condensed gas films on clean surfaces at low temperatures. Observations on the mode of growth of xenon growing on a graphite (0001) surface are reported. It is shown that, once the surface is cleaned by heating, layer-by-layer growth is observed. The observation of island growth of rare gas crystals on graphite in previous experiments is shown to have been caused by surface contamination. 相似文献
8.
9.
Z.M. Babar Wan Mohd Azizi Solachuddin JA Ichwan Qamar Uddin Ahmed Abul Kalam Azad Imranul Mawa 《Natural product research》2019,33(15):2266-2270
The current study provides a way of extraction for both active NSO and WSE from Nigella sativa seeds using 98% methanol. About 1?kg of ground seeds was macerated by 1:2.5 w/v (g/mL) for 72?hours. After rotary evaporation and 7 days of continuous drying and chilling at 50 and 4?°C, NSO and WSE were obtained at the same instant. Solubility tests of 24 solvents and 11 thin layer chromatographic analyses while 2, 2-diphenyl-1-picrylhydrazyl free radical scavenging assay of NSO (73.66) , WSE (33.32) and NSO?+?WSE (78.22) against ascorbic acid (IC50?=?4.28?mg/mL) was performed. WSE was found to be highly soluble in water and 5% NaOH exhibiting the same Rf value of 0.95 for EtOH:DMSO (9:1) against the honey. WSE has revealed more than twofold higher anti-oxidant activity than others. Formulation of WSE with Tualang honey may provide better targeted hydrophilic drug delivery systems. 相似文献
10.