Y2O3和CeO2复合掺杂ZrO2纳米晶的制备与表征

以ZrOCl2.8H2O,Y2O3,Ce（NO3）3.5.5H2O为原料,NH3.H2O作沉淀剂,少量表面活性剂PE作分散剂,采用反向共沉淀-喷雾干燥法,结合物理、化学分散技术,成功地制备了Y2O3,CeO2复合掺杂ZrO2纳米粉末。通过DSC-TG,XRD,XPS,BET和SEM等方法对所制得粉末进行了表征。结果表明：以Ce0.1Y0.1Zr0.8O1.95化学计量比制备的多元氢氧化物胶体经过喷雾干燥处理后,在500℃基本完成水合氧化物的分解,577℃附近完成由非晶相向立方相的转变;经过580-1000℃煅烧后,CeO2和Y2O3已经完全固溶到ZrO2中,形成类质同相体,该粉末系列均属于立方相萤石结构;掺杂进入ZrO2晶格中的Ce呈＋4价形式存在;比表面积由22.0 m^2.g^-1（580℃煅烧）减至4.97 m^2.g^-1（1000℃煅烧）;SEM结果显示800℃煅烧的该粉末颗粒尺寸分布均匀,多呈类球状,且粒径在50-80 nm。     

考虑上部结构的桩筏基础非线性共同作用分析

当前虽然已有考虑桩筏非线性的设计,但仍无人在此基础上,考虑上部结构。因此考虑上部结构,进一步认识其与桩筏基础非线性共同作用机理,优化桩筏基础设计,具有重要的现实意义。本文以子结构法凝聚上部结构的荷载及刚度,以平面壳体单元模拟筏板,按有限层法模拟桩土之间的弹性相互作用,用广义剪切位移法模拟桩的非线性工作性状,建立了一种考虑上部结构共同作用的桩筏基础非线性分析方法,并编制了分析程序。通过实例分析,探讨了上部结构与桩筏基础非线性共同作用的机理,研究了合理布桩方式,探讨了以差异沉降为目标的优化设计的可能途径。     

HL—1装置汤姆逊散射测量空间两点电子温度

本文叙述用激光汤姆逊散射方法测量HL-1装置在不同放电条件下空间两点的电子温度。简要介绍了测量条件,空间两点测量的实验安排及数据获取系统等。对实验结果进行了初步分析。在适当改变等离子体边缘径向电场分布时,电子温度有明显增加。     

Stereospecific Nucleophilic Substitution with Arylboronic Acids as Nucleophiles in the Presence of a CONH Group

Stereospecific nucleophilic substitution was achieved for the first time with arylboronic acids as nucleophiles. This transition‐metal‐free coupling between chiral α‐aryl‐α‐mesylated acetamides and arylboronic acids provided access to a series of chiral α,α‐diaryl acetamides with excellent enantioselectivity and moderate to good yields. The CONH functionality proved to be crucial for bridging the reactants and promoting the reaction. Efficient syntheses of a cannabinoid CB₁ receptor ligand, the antidepressant (S)‐diclofensine, and a key chiral building block of the inhibitor implitapide were successfully accomplished by using this method.     

Stereoelectronic Effects in Ligand Design: Enantioselective Rhodium‐Catalyzed Hydrogenation of Aliphatic Cyclic Tetrasubstituted Enamides and Concise Synthesis of (R)‐Tofacitinib

We herein report the development of a conformationally defined, electron‐rich, C₂‐symmetric, P‐chiral bisphosphorus ligand, ArcPhos, by taking advantage of stereoelectronic effects in ligand design. With the Rh‐ArcPhos catalyst, excellent enantioselectivities and unprecedentedly high turnovers (TON up to 10 000) were achieved in the asymmetric hydrogenation of aliphatic carbocyclic and heterocyclic tetrasubstituted enamides, to generate a series of chiral cis‐2‐alkyl‐substituted carbocyclic and heterocyclic amine derivatives in excellent enantiomeric ratios. This method also enabled an efficient and practical synthesis of the Janus kinase inhibitor (R)‐tofacitinib.     

共沉淀-喷雾干燥法制备Sm2O3掺杂CeO2纳米粉体

以Sm（NO3）3.6H2O和Ce（NO3）3.6H2O为原料,用共沉淀-喷雾干燥法制备了Sm2O3掺杂CeO2（SDC）粉体。通过沉降实验、TG-DSC、XRD、BET、SEM和粒度分布对前驱体的分散性、稳定性及制得的SDC粉体性能进行表征,研究了洗涤方法、分散剂对前驱体及SDC粉体的影响。结果表明：无机陶瓷膜洗涤后前驱体分散性好,经500℃以上温度焙烧后的粉体为立方萤石型结构。加入分散剂后前驱体的分散性明显提高,制得的SDC粉体比表面积显著增加,最终获得了晶粒平均粒径为12.51 nm、团聚态颗粒为球形的SDC纳米粉体。     

Study on Polarization of BEPC Beam and a Polarimeter

The necessity and feasibility of beam polarizaion on Beijing Electron-Positron Collider (BEPC)and the principes and methods of measurements for beam polarization are briefly introduced in this paper.The design of a Compton polarimeter used for measurements of beam polarization of BEPC beam by using a synchrotron radiation pipe-line and the experiments under way are presented.     

HL—1M装置等离子体电子温度测量

在ＨＬ－１Ｍ装置上用红宝石激光９０ｏ汤姆逊散射对等离子体电子温度进行了测量,建立了激光测量等离子体电子温度的数学模型。开发了用于数据采集和处理的程序,并对实验结果进行了初步讨论和误差分析。     

Construction of Various Bridged Polycyclic Skeletons by Palladium‐Catalyzed Dearomatization

A powerful palladium‐catalyzed dearomative cyclization was developed that provides facile access to eight types of bridged tetracyclic skeletons bearing various ring sizes and heterocycles. With this method, several skeletons or analogues of natural products, including tubingensin B and dracaenones, were synthesized. Asymmetric dearomative cyclization enables the construction of various enantiomerically enriched bridged polycyclic systems with up to 99 % ee by employing a chiral palladium catalyst.     

重组实验数据处理与经验证据评估新架构的探索——《新概念基础物理实验讲义》前4章的特点介绍

随机误差的随机性与未定系统误差的近似随机性,是宏观测量数据分析中应用统计学非公理化体系适用的基础．本书剖析了实际实验与测量中有关不确定度来源及其影响的8个主从关系,提出在实验和测量中需要重视的10个命题,以此作为重建实验数据处理与经验证据评估架构的基础．在此架构中,重新审视误差严格正态分布的普遍性,新导出了统计允许限因子的高准确度计算式,构建了正态分布前提下用统计允许限的新判据;对比分析已有的3种常见的不确定度评定架构,创建了不确定度分量合成的综合技术法,阐述并实例化该方法在实验数据分析中的具体应用．