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The conformational and dynamic properties of the 7-membered cyclic sulfites 1 and 2 were investigated by 1H and 13CDNMR as well as by IR spectroscopy. Compound 1 showed two spectral modifications at low temperature for both 1H (100 MHz) and 13C (22.6 MHz) spectra while for compound 2 a single 1H spectral change has been observed and resolved at 300MHz. Analysis of the low temperature NMR spectra together with the IR frequencies for the stretching vibration of the SO bond indicate that 1 exists as a 1:1 mixture of C-a and TB conformations in CHF2Cl. Less polar solvents increase the proportion of the C-a form.In contrast, compound 2 is found to exist very predominantly as the TB form in CHF2Cl at ?160°, whereas in the less polar CCl4 solvent a small amount of C-a form is found to be present at room temperature from the IR data. The conformational and dynamic properties determined for 1 and 2 are discussed in light of current theories relating to n→σ* stereoelectronic lone pair donation and dipole-dipole interactions. Furthermore the results for 1 and 2 are used as the basis for a new conformational interpretation of published IR data for dimethyl sulfite. Finally, the differences in properties of 1 and 2 are discussed. 相似文献
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