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1.
Grindstone Chemistry--a greatly evolved version of Toda’s method of grinding solids together for solvent-free chemical reactions--has been described and its usefulness illustrated by the successful application of this technique to a simplified process for conducting the multi-component Biginelli reaction for the synthesis of physiologically active tetrahydropyrimidinones. 相似文献
2.
Ajay K. Bose Maghar S. Manhas Suhas Pednekar Subhendu N. Ganguly Hoang Dang William He Arun Mandadi 《Tetrahedron letters》2005,46(11):1901-1903
An important stage in process development is kilo scale preparation of the target compound. For this reason, a procedure involving water-based biphasic reaction media has been developed for conducting some exothermic reactions on a large scale. This protocol is illustrated by the energy-efficient and rapid preparation of dihydropyrimidinones by a solvent-free, green chemistry procedure applied to the Biginelli reaction using p-toluenesulfonic acid as catalyst. 相似文献
3.
Joseph P. Kennedy Tung-Ping Liao Suhas Guhaniyogi Victor S. C. Chang 《Journal of polymer science. Part A, Polymer chemistry》1982,20(11):3219-3227
β-Pinene was polymerized with H2O/BCl3 (protic) and p-dicumyl chloride and sym-tricumyl chloride (nonprotic) inifer systems in CH2Cl2 or CH2Cl2/n-C6H14 solvents from ?10 to ?70°C. The effect of solvent polarity, temperature, and monomer and inifer concentration on conversions and molecular weights was investigated. Low conversions and molecular weights, M?n = 1300–2500, obtained under these conditions suggest rapid termination. 相似文献
4.
Deshpande Deepti Gadmale Dinesh Bakre Suhas Srivastava Ashwini Kumar 《平面色谱法杂志一现代薄层色谱法》2016,29(6):429-434
JPC – Journal of Planar Chromatography – Modern TLC - In an attempt to determine chlorpyrifos insecticide and its metabolite 3,5,6-trichloropyridinol in visceral samples, a rapid... 相似文献
5.
We consider the nonanalytic temperature dependences of the specific heat coefficient, C(T)/T, and spin susceptibility, chi(s)(T), of 2D interacting fermions beyond the weak-coupling limit. We demonstrate within the Luttinger-Ward formalism that the leading temperature dependences of C(T)/T and chi(s)(T) are linear in T, and are described by the Fermi liquid theory. We show that these temperature dependences are universally determined by the states near the Fermi level and, for a generic interaction, are expressed via the spin and charge components of the exact backscattering amplitude of quasiparticles. We compare our theory to recent experiments on monolayers of He3. 相似文献
6.
Babasaheb P. Bandgar Suhas P. Kasture 《Monatshefte für Chemie / Chemical Monthly》2001,132(9):1101-1104
Summary. Trimethylsilylation of alcohols and phenols is carried out using hexamethyldisilazane and LiClO4 under microwave irradiation and neutral conditions. The deprotection of silyl ethers is carried out similarly using natural
kaolinitic clay and a few drops of water.
Received March 1, 2001. Accepted (revised) April 17, 2001 相似文献
7.
We show that one-dimensional electron systems in the proximity of a superconductor that support Majorana edge states are extremely susceptible to electron-electron interactions. Strong interactions generically destroy the induced superconducting gap that stabilizes the Majorana edge states. For weak interactions, the renormalization of the gap is nonuniversal and allows for a regime in which the Majorana edge states persist. We present strategies of how this regime can be reached. 相似文献
8.
Coherent diffraction imaging (CDI) and ptychography techniques bypass the difficulty of having high-quality optics in X-ray microscopy by using a numerical reconstruction of the image that is obtained by inverting the diffracted intensity recorded by a charge-coupled device array. However, the reconstruction of the image from the intensity data obtained from a weakly diffracting specimen is known to be difficult because of the obvious reduction in signal-to-noise ratio (SNR). In this case, the specimen only slightly modifies the probe diffraction pattern, resulting in difficulty in the identification of the detailed structure of the specimen from the reconstructed image because of the poor contrast and sharpness of the image. To address this situation, a modification in the image retrieval algorithms used in the iterative reconstruction of the image is suggested. This modification should double the presence of high spatial frequencies in the diffraction pattern to enhance the contrast and edge detection in existing imaging techniques. 相似文献
9.
In Hee Shin Seongmin Ju Suhas Poyyil Veetil Won-Taek Han Dug Young Kim 《Optics Communications》2008,281(9):2504-2508
We have measured residual stress in a commercial single mode optical fiber and observed its relaxation in an annealing process with a polariscopic stress measurement method. After annealing the fiber for an hour at various high temperatures in a specially made image furnace we have measured the temperature dependent relaxation of frozen-in viscoelastic stress in the fiber. We have proposed a simple physical model to explain recently observed relaxation of frozen-in viscoelastic stress in optical fibers based on the Kelvin-Voigt model of viscoelastic materials. The experimental results are explained with our model of frozen-in viscoelastic stress by introducing simplified four-step procedures for fiber drawing. 相似文献
10.
We investigate interactions between spins of strongly correlated electrons subject to the spin-orbit interaction. Our main finding is that of a novel, spin-orbit mediated anisotropic spin-spin coupling of the van der Waals type. Unlike the standard exchange, this interaction does not require the wave functions to overlap. We argue that this ferromagnetic interaction is important in the Wigner crystal state where the exchange processes are severely suppressed. We also comment on the anisotropy of the exchange between spins mediated by the spin-orbital coupling. 相似文献