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1.
Lomonova E. E. Agarkov D. A. Borik M. A. Eliseeva G. M. Kulebyakin A. V. Kuritsyna I. E. Milovich F. O. Myzina V. A. Osiko V. V. Chislov A. S. Tabachkova N. Yu. 《Russian Journal of Electrochemistry》2020,56(2):118-123
Russian Journal of Electrochemistry - The effects of the Y2O3 and Yb2O3 co-doping impurities on the transport characteristics and stabilization of the cubic phase in solid solutions based on... 相似文献
2.
M. A. Borik V. T. Bublik M. A. Vishnyakova E. E. Lomonova V. A. Myzina N. Yu. Tabachkova A. A. Timofeev 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2011,5(1):166-171
Zirconia single crystals doped with 2.8, 3.2, 3.7, and 4.0 mol % of Y2O3 have been studied. The phase composition and structure have been studied by X-ray diffraction analysis and transmission electron
microscopy. It has been established that all investigated samples has two ZrO2 tetragonal phases with tetragonality c/a = 1.006–1.007 and c/a = 1.014–1.015 independent of the stabilizing impurity content. The former phase is not transformed, whereas the latter is
transformed into a monoclinic one. In all cases the samples have a developed twin structure. Twinning hierarchy is observed:
there are first-, second-, third-order, etc., twins, each of them containing the next-order twins inside them. Elastic stress
relaxation occurs by twinning rather than by generation of dislocations. The stabilizing impurity content affects the structure
nonmonotonically; the minimum dimensions of the twin lamellas refer to the Y2O3 concentration of 3.2 mol %. 相似文献
3.
M. Hartmanov F. Kubel V. Buríkov E.E. Lomonova J.P. Holgado V. Navrtil K. Navrtil F. Kundracik 《Journal of Physics and Chemistry of Solids》2008,69(4):805-814
The paper represents a detailed insight into the correlation between changes of the phase composition of crystalline YbxZr1−xO2−x/2 solid solutions and their structural, electrical, mechanical and optical properties. Particularly, the effect of the crystal growth conditions and stabilizer amount in the range of 1.5–13.8 mol% of Yb2O3 are studied in terms of Rietveld analysis of powder X-ray diffraction data, electrical conductivity measured by impedance spectroscopy, absorption coefficient and refractive index measurements, Vickers microhardness (classical technique) as well as the plastic microhardness and effective elastic modulus (DSI—depth-sensing indentation technique). Potential applications of the investigated systems are discussed in view of the results obtained. 相似文献
4.
Agarkov D. A. Borik M. A. Korableva G. M. Kulebyakin A. V. Kuritsyna I. E. Lomonova E. E. Milovich F. O. Myzina V. A. Popov P. A. Ryabochkina P. A. Tabachkova N. Yu. 《Physics of the Solid State》2020,62(12):2357-2364
Physics of the Solid State - The effect of heat treatment at 1000°C for 400 h on the thermal conductivity of zirconium dioxide crystals stabilized with scandium oxide... 相似文献
5.
Perevalov T. V. Kruchinin V. N. Rykhlitskii S. V. Gritsenko V. A. Eliseev A. P. Lomonova E. E. 《Optics and Spectroscopy》2020,128(12):1963-1969
Optics and Spectroscopy - The luminescent and optical properties of materials based on zirconium(IV) oxide grown by crystallization of ZrO2 melts with 0, 2.0, 2.5, 2.8, and 3.7 mol % of Y2O3 are... 相似文献
6.
Borik M. A. Volkova T. V. Kuritzyna I. E. Larina N. A. Lomonova E. E. Myzina V. A. Ryabochkina P. A. Tabachkova N. Yu. 《Optics and Spectroscopy》2018,125(6):898-902
Optics and Spectroscopy - The specific features of the local structure of ZrO2–Sc2O3–Y2O3 and ZrO2–Sc2O3–Yb2O3 crystals are revealed by optical spectroscopy using the Eu3+... 相似文献
7.
M. A. Borik T. V. Volkova E. E. Lomonova V. A. Myzina P. A. Ryabochkina N. Yu. Tabachkova A. N. Chabushkin 《Optics and Spectroscopy》2017,122(4):580-587
The structure of the optical centers of Eu3+ ions in tetragonal (ZrO2)1–x–y (Y2O3) x (Eu2O3) y (х = 2.7–3.6; y = 0.1) and cubic (ZrO2)1–x–y (Y2O3) x (Eu2O3) y (х = 8–38; y = 0.1–0.5) crystals of solid solutions on the basis of zirconium dioxide is studied using the methods of optical and Raman-scattering spectroscopy. Characteristic optical centers of Eu3+ ions with different crystalline environments are revealed in the above compounds. 相似文献
8.
D. A. Agarkov M. A. Borik S. I. Bredikhin A. V. Kulebyakin I. E. Kuritsyna E. E. Lomonova F. O. Milovich V. A. Myzina V. V. Osiko E. A. Agarkova N. Yu. Tabachkova 《Russian Journal of Electrochemistry》2018,54(6):459-463
The crystals of (ZrO2)1–x(Sc2O3) x (СeO2)0.01 solid solutions (x = 0.08–0.10) were obtained by directional crystallization. The crystals of the grown composites were semitransparent, opalescent, and without cracks and had varying microstructure in the bulk. In the range of compositions under study, it was impossible to obtain optically homogeneous, fully transparent crystals. The crystals grown at a growth rate of 10 mm/h had a nonuniform distribution of ceria along the length of the ingot. The introduction of ceria in an amount of 1 mol % increased the conductivity of the crystals, but the increase in the specific electric conductivity depended on the Sc2O3 content and the phase composition of the crystals. The highest conductivity was inherent in the (ZrO2)0.89(Sc2O3)0.10(CeO2)0.01 crystals. 相似文献
9.
S. V. Belov M. A. Borik M. A. Vishnyakova Yu. K. Danileiko A. V. Kulebyakin E. E. Lomonova F. O. Milovich V. A. Myzina V. V. Osiko V. A. Salyuk N. Yu. Tabachkova 《Doklady Physics》2013,58(5):161-164
To optimize the chemical composition of the crystals of nanostructured partially stabilized zirconium dioxide for fabricating cutting parts of an electrosurgical tool, the structural and strength properties of these crystals were investigated in dependence on the stabilizing impurity (Y2O3) content and the effect of additional dopants on the critical properties of the material was studied. It was established that in all the investigated crystals without additional doping, regardless of the stabilizing impurity content, there are two phases of zirconium dioxide tetragonal modification with different tetragonality factors, c/a = 1.006–1.007 and 1.014–1.015, the first being nontransformable and the second being transformable to a monoclinic phase. All the synthesized crystals are characterized by a pronounced twin domain structure, which forms upon cooling the single crystal during the transition of the cubic structure to the tetragonal one. It was established that the Y2O3 concentration in the range from 2.5 to 3.0 mol % is optimal for ensuring high values of the strength characteristics and fracture toughness of the material. Doping of the crystals with the rare-earth elements notice-ably affects their strength characteristics. One of the most promising materials for fabricating cutting blades of the electrosurgical tool is the crystals of partially stabilized zirconium dioxide doped with Ce2O3+Nd2O3, which are characterized by high fracture toughness and enhanced bending strength. 相似文献
10.
Popov P. A. Solomennik V. D. Lomonova E. E. Borik M. A. Myzina V. A. 《Physics of the Solid State》2012,54(3):658-661
The thermal conductivity of ZrO2−x
Y2O3 single crystals (x = 0.5, 1.5, 2.0, 2.5, 3.0, 8.0 mol %) has been studied experimentally in the temperature range 50–300 K. The influence of
high-temperature annealings on the thermal conductivity has been analyzed. 相似文献